氧化硅纳米多孔材料表面的水蒸气吸附动力学研究

张虎 1; 谷伟 1; 李增耀 1; 陶文铨 1; 胡子君 2

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氧化硅纳米多孔材料表面的水蒸气吸附动力学研究

更新时间：2025-07-09

- 氧化硅纳米多孔材料表面的水蒸气吸附动力学研究
- Experimental Study on Kinetics of Water-Vapor Sorption on Surface of Silica Nano-Porous Materials
- 西安交通大学学报 2012年46卷第3期页码：1-8
- 作者机构：
  
  西安交通大学能源与动力工程学院,西安,710049
- 作者简介：
- 基金信息：
  
  : 2011-06-18. 作者简介: 张虎(1987-),男,博士生;陶文铨(通信作者),男,教授,博士生导师,中国科学院院士. 基金项目: 国家自然科学基金重点资助项目(51136004)
- DOI：
  中图分类号： TB383;O647.32
- 网络首发：2012-03-10，
  
  纸质出版：2012
- 稿件说明：
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张虎 1, 谷伟 1, 李增耀 1, 等. 氧化硅纳米多孔材料表面的水蒸气吸附动力学研究[J]. 西安交通大学学报, 2012,46(3):1-8.

Experimental Study on Kinetics of Water-Vapor Sorption on Surface of Silica Nano-Porous Materials[J]. 2012, 46(3): 1-8.
张虎 1, 谷伟 1, 李增耀 1, 等. 氧化硅纳米多孔材料表面的水蒸气吸附动力学研究[J]. 西安交通大学学报, 2012,46(3):1-8. DOI：

Experimental Study on Kinetics of Water-Vapor Sorption on Surface of Silica Nano-Porous Materials[J]. 2012, 46(3): 1-8. DOI：

摘要

采用称重法对氧化硅纳米多孔材料在温湿环境中的水蒸气吸附规律进行了实验研究.在25 ℃分别测定了不同孔隙率的材料在水蒸气相对蒸汽压为0.3～0.9范围内的吸附动力学曲线.分别采用不同的多层吸附等温式对材料的吸附等温线进行拟合

提出了一种双指数衰减动力学吸附模型方程

并和准一/二级动力学吸附模型一起对实验结果进行了拟合.结果表明:Redlich-Peterson、Fritz-Schlünder吸附等温式和BET多层吸附模型的拟合相关系数较大; BET多层吸附模型的拟合参数可给出单层饱和吸附量和吸附层数

吸附等温线由单层到多层存在临界点

具有明显的物理意义; 氧化硅纳米多孔材料对湿空气中水蒸气的动态吸附过程可由双指数衰减模型来描述

与实验数据的相关系数在0.99以上

在整个吸附过程中均与实验数据拟合良好.

Abstract

The thermal gravimetrical method was adopted to measure the water-vapor sorption of silica nano-porous materials in the thermal and moisture environment. The water-vapor sorption kinetics was experimentally investigated at environmental temperature 25 ℃ and different relative pressure of vapor from 0.3 to 0.9. The sorption equilibrium data were fitted with different equations. An exponential decay-2 model was proposed based on the experimental data and was compared with the pseudo-first-order and the pseudo-second-order equations. The results show that the correlation coefficients of the Redlich-Peterson equation

the Fritz-Schlünder equation and the BET finite layer equation are higher than those of the other models; the BET model is more reasonable because it can present the monolayer saturation sorption capacity and the sorption layer number

and the sorption equilibrium curve of materials exists an inflection point from monolayer sorption to multilayer sorption. In addition

the kinetics of water-vapor sorption on the surface of silica nano-porous materials can be described by the decay-2 model with correlation coefficients above 0.99

and the decay-2 model fits well with the experimental values in the whole sorption process.

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