面向电氢耦合能源系统的可逆固体氧化物电池研究进展

周峻; 孙跃跃; 李儒欢; 冀承泽; 付磊; 吴锴; 成永红

doi:10.7652/xjtuxb202604006

您当前的位置：

首页 >

文章列表页 >

面向电氢耦合能源系统的可逆固体氧化物电池研究进展

专题西安交通大学自然科学优秀成果 | 更新时间：2026-04-10

- 面向电氢耦合能源系统的可逆固体氧化物电池研究进展
- Progress of Reversible Solid Oxide Cells for the Electric-Hydrogen Energy Systems
- 西安交通大学学报 2026年60卷第4期页码：72-83
- 作者机构：
  
  西安交通大学电工材料电气绝缘全国重点实验室，710049，西安
  西安交通大学电气工程学院，710049，西安
- 作者简介：
  
  作者简介：周峻（1985—），男，教授，博士生导师。
- 基金信息：
  
  国家自然科学基金资助项目(52377212;51877173);陕西省重点研发计划资助项目。(2023-YBGY-057)
- DOI：10.7652/xjtuxb202604006
  中图分类号： TM911.4
- 收稿：2025-09-26，
  
  网络首发：2025-11-11，
  
  纸质出版：2026-04-10
- 稿件说明：
移动端阅览
周峻, 孙跃跃, 李儒欢, 等. 面向电氢耦合能源系统的可逆固体氧化物电池研究进展[J]. 西安交通大学学报, 2026,60(4):72-83.

ZHOU Jun, SUN Yueyue, LI Ruhuan, et al. Progress of Reversible Solid Oxide Cells for the Electric-Hydrogen Energy Systems[J]. Journal of Xi'an Jiaotong University, 2026, 60(4): 72-83.
周峻, 孙跃跃, 李儒欢, 等. 面向电氢耦合能源系统的可逆固体氧化物电池研究进展[J]. 西安交通大学学报, 2026,60(4):72-83. DOI： 10.7652/xjtuxb202604006.

ZHOU Jun, SUN Yueyue, LI Ruhuan, et al. Progress of Reversible Solid Oxide Cells for the Electric-Hydrogen Energy Systems[J]. Journal of Xi'an Jiaotong University, 2026, 60(4): 72-83. DOI： 10.7652/xjtuxb202604006.

摘要

可逆固体氧化物电池（RSOC）是一种能够灵活、高效地实现电能与燃料气化学能双向转换的关键技术，在可再生能源整合和能源存储领域具有巨大潜力，被视为构建电氢耦合能源系统的关键。西安交通大学电工材料电气绝缘全国重点实验室研究团队长期聚焦于RSOC电氢耦合技术，开展了一系列贯穿材料、电堆与系统层面的系统性研究。在材料层面，针对钙钛矿电极材料发展了原位出溶、熵工程、表面缺陷工程等创新设计方法，结合实验与计算探究了快速电荷转移、缺陷降低出溶势垒等电化学性能提升机制，实验结果表明，可逆固体氧化物单电池的电转氢效率超过90%；在电堆层面，探究了模式切换过程中反应物比例、温度、压强等因素对RSOC动态性能的影响机理，改善反应物分布、引入模糊控制器等优化措施将电流超调抑制99%以上，有效减轻模式切换动态过程的功率波动并提升长期运行稳定性；在系统层面，整合电能、热能、化学能等多重能源，构建了以RSOC为核心的电氢耦合能源系统，使用分段线性化方法优化RSOC的输入输出模型显著降低了计算复杂度，引入RSOC的热备用与停机状态使系统运行成本降低24%。未来，该技术有望在可再生能源消纳、电网调峰、储能等领域得到广泛应用，推动构建清洁低碳、安全高效的能源体系。

Abstract

Reversible solid oxide cells（RSOC）represent a key technology capable of flexibly and efficiently achieving the bidirectional conversion between electrical energy and the chemical energy of fuel gases.They show great potential in renewable energy integration and energy storage，and are regarded as critical components for building electric-hydrogen coupled energy systems.The research team from the state key laboratory of electrical insulation and power equipment at Xi'an Jiaotong University has long been focused on RSOC electric-hydrogen coupling technology，conducting a series of systematic investigations spanning materials，stacks，and systems.At the material level，innovative design methods for perovskite electrode materials have been developed，including in-situ exsolution，entropy engineering，and surface defect engineering.Combined with experimental and computational studies，mechanisms for enhancing electrochemical performancesuch as rapid charge transfer and lowered exsolution barriers via defect engineering-have been elucidated.Experimental results show that the electricity-to-hydrogen conversion efficiency of reversible solid oxide single cells exceeds 90%.At the stack level，the influence mechanisms of factors including reactant ratio，temperature，and pressure on the dynamic performance of RSOC during mode switching have been explored.Optimization measures such as improved reactant distribution and the introduction of fuzzy controllers have been implemented，suppressing current overshoot by over 99% and effectively mitigating power fluctuations during the dynamic modeswitching process，thereby enhancing long-term operational stability.At the system level，multiple energy forms including electrical，thermal，and chemical energy have been integrated to construct RSOC-centered electric-hydrogen coupled energy systems.The input-output model of RSOC has been optimized using a piece-wise linearization method，significantly reducing computational complexity.The introduction of hot-standby and shutdown states for RSOC has lowered system operating costs by 24%.In the future，RSOC technology is expected to be widely applied in areas such as renewable energy accommodation，grid peaking，and energy storage，promoting the construction of a clean，low-carbon，safe，and efficient energy system.

关键词

Keywords

references

RISCO-BRAVO A，VARELA C，BARTELS J，et al. From green hydrogen to electricity：a review on recent advances，challenges，and opportunities on power-tohydrogen-to-power systems [J].Renewable and Sustainable Energy Reviews，2024，189（Part A）：113930.

BANASIAK D，GALLAUN M，RINNHOFER C，et al. Integration of a rSOC-system to industrial processes [J]. Energy Conversion and Management：X，2023，20：100425.

VENKATARAMAN V，PÉREZ-FORTES M，WANG Ligang，et al.Reversible solid oxide systems for energy and chemical applications-review & perspectives [J]. Journal of Energy Storage，2019，24：100782.

KHAN M S，XU X，KNIBBE R，et al.Air electrodes and related degradation mechanisms in solid oxide electrolysis and reversible solid oxide cells [J].Renewable and Sustainable Energy Reviews，2021，143：110918.

HE Shuai，ZOU Yuanfeng，CHEN Kongfa，et al.A critical review of key materials and issues in solid oxide cells [J].Interdisciplinary Materials，2023，2（1）：111-136.

ASSIREY E A R.Perovskite synthesis，properties and their related biochemical and industrial application [J]. Saudi Pharmaceutical Journal，2019，27（6）：817-829.

LIU Zuoqing，TANG Zhengjie，SONG Yufei，et al. High-Entropy perovskite oxide：a new opportunity for developing highly active and durable air electrode for reversible protonic ceramic electrochemical cells [J]. Nano-Micro Letters，2022，14（1）：217.

LI Yihang，LI Yanpu，ZHANG Shaowei，et al.Mutual conversion of CO-CO 2 on a perovskite fuel electrode with endogenous alloy nanoparticles for reversible solid oxide cells [J ] .ACS Applied Materials & Interfaces，2022，14（7）：9138-9150.

KANG S，AHN K Y.Dynamic modeling of solid oxide fuel cell and engine hybrid system for distributed power generation [J].Applied Energy，2017，195：1086-1099.

NERATM. Modeling and analysis of short-period transient response of a single，planar，anode supported，solid oxide fuel cell during load variations [J]. Energy，2017，138：728-738.

MCVAY D，ZHAO Li，BROUWER J.Dynamic subthermoneutral voltage operation of solid oxide electrolysis with alternative heat addition [J].ECS Transactions，2017，78（1）：2975-2985.

JIN Xinfang，XUE Xingjian.Mathematical modeling analysis of regenerative solid oxide fuel cells in switching mode conditions [J].Journal of Power Sources，2010，195（19）：6652-6658.

PREININGER M，SUBOTIC V，STOECKL B，et al. Electrochemical characterization of a CFY-stack with planar electrolyte-supported solid oxide cells in rSOC operation [J].International Journal of Hydrogen Energy，2018，43（27）：12398-12412.

SAARINEN V，PENNANEN J，KOTISAARI M，et al.Design，manufacturing，and operation of movable 2 × 10 kW size rSOC system [J].Fuel Cells，2021，21（5）：477-487.

BALDINELLI A，BARELLI L，BIDINI G.Sustainable water-energy innovations for higher comfort of living in remote and rural areas from developing coun tries：from seawater to hydrogen through reversible solid oxide cells [J].Journal of Cleaner Production，2021，321：128846.

YANG Yiping，LEI Jinyong，HUANG Xurui，et al. Recent development in reversible solid oxide fuel cells：theory，integration and prospective [J].ChemElectro-Chem，2024，11（6）：e202300593.

CALIFANO M，SORRENTINO M，PIANESE C. Energy management control strategies addressing the rSOC degradation phenomena in a polygeneration microgrid [J].International Journal of Hydrogen Energy，2024，95：1137-1150.

WANG Chen，LI Zheng，ZHU Meng，et al.Improving the performance and economics of reversible solid oxide cell-based hydrogen energy storage systems through the utilization of renewable alternative fuels [J].Fuel，2024，375：132484.

李欣，王昌胜，李新宇，等.含可逆固体氧化物电池的综合能源系统低碳运行优化[J].电力建设，2025，46（1）：58-71.

LI Xin，WANG Changsheng，LI Xinyu，et al.Low carbon operation optimization of integrated energy system with reversible solid oxide cell[J].Electric Power Construction，2025，46（1）：58-71 .

王秋杰，刘国安，谭洪，等.考虑电氢耦合的虚拟电厂鲁棒可行域模型与求解[J].电网技术，2025，49（3）：889-898.

WANG Qiujie，LIU Guoan，TAN Hong，et al.Models and solutions of robust feasible region for virtual power plants with electric hydrogen coupling [J]. Power System Technology，2025，49（3）：889-898.

SHI Huangang，SU Chao，RAN Ran，et al.Electrolyte materials for intermediate-temperature solid oxide fuel cells [J].Progress in Natural Science：Materials International，2020，30（6）：764-774.

GÓMEZ S Y，HOTZA D.Current developments in reversible solid oxide fuel cells [J].Renewable and Sustainable Energy Reviews，2016，61：155-174.

YANG Jiaming，ZHOU Jun，LIU Zhengrong，et al. Exploring heterogeneous phases in highly A-site-deficient titanate with Ni exsolution [J].Journal of Power Sources，2023，580：233369.

MOGENSEN M B.Materials for reversible solid oxide cells [J].Current Opinion in Electrochemistry，2020，21：265-273.

WANG Junkai，ZHOU Jun，YANG Jiaming，et al. Tailoring the surface of perovskite through in situ growth of Ru/RuO 2 nanoparticles as robust symmetri cal electrodes for reversible solid oxide cells [J ] .Advanced Materials Interfaces，2020，7（23）：2000828.

LI Xue，ZHAO Hailei，ZHOU Xiong，et al.Electrical conductivity and structural stability of La-doped Sr-TiO 3 with A-site deficiency as anode materials for solid oxide fuel cells [J ] .International Journal of Hydrogen Energy，2010，35（15）：7913-7918.

YIN Chaofan，YANG Jiaming，FENG Jiangyuan，et al.Tailoring the reversible phase transition of perovskite nanofiber electrodes for high-performance and durable reversible solid oxide cells [J].Nano-Micro Letters，2025，17（1）：150.

ZHOU Zilin，CUI Jiajia，LIU Zhengrong，et al.Exsolved medium-entropy alloy fecocuni in titanate fibers enables solid oxide cells with superb electrochemical performance [J].Journal of Materials Chemistry A，2025，13（10）：7563-7572.

LIU Zhengrong，JUN Zhou，SUN Yueyue，et al.Tuning exsolution of nanoparticles in defect engineered layered perovskite oxides for efficient CO 2 electrolysis [J ] .Journal of Energy Chemistry，2023，84（9）：219-227.

FALCÓN H，BARBERO J A，ARAUJO G，et al. Double perovskite oxides A 2 FeMoO 6-δ （A = Ca，Sr and Ba）as catalysts for methane combustion [J ] .Applied Catalysis：B Environmental，2004，53（1）：37-45 .

SUN Yueyue，ZHOU Jun，YANG Jiaming，et al. Nanosurface-reconstructed fuel electrode by selective etching for highly efficient and stable solid oxide cells [J]. Advanced Science，2025，12（4）：2409272.

LIU Zhengrong，ZHOU Zilin，YANG Jiaming，et al. Design of a B-site Co-free multielement perovskite oxide as oxygen electrode for efficient CO 2 solid oxide electrolysis cells [J ] .ACS Applied Energy Materials，2024，7（23）：11020-11030.

LEE J G，PARK J H，SHUL Y G.Tailoring gadolinium-doped ceria-based solid oxide fuel cells to achieve 2 W·cm -2 at 550 ℃ [J ] .Nature Communication，2014，5（1）：4045 .

YANG Jiaming，WANG Junkai，FU Lei，et al.Electrospun core-shell fibers for high-efficient composite cathode-based solid oxide fuel cells [J].Energy & Fuels，2021，35（2）：1768-1778.

OUYANG Zhufeng，KOMATSU Y，SCIAZKO A，et al.Operando observations of active three phase boundary of patterned nickel-yttria stabilized zirconia electrode in solid oxide cell [J].Journal of Power Sources，2022，529：231228.

XU Han，DANG Zheng.Numerical investigation of coupled mass transport and electrochemical reactions in porous SOFC anode microstructure [J].International Journal of Heat and Mass Transfer，2017，109：1252-1260.

YAHYA A，RABHI R，DHAHRI H，et al.Numerical simulation of temperature distribution in a planar solid oxide fuel cell using lattice Boltzmann method [J]. Powder Technology，2018，338：402-415.

ZHAO Hongfei，ZHOU Jun，ZONG Zheng，et al. Three-dimensional reconstruction and optimization of porous fuel electrode in reversible solid oxide cells based on the Lattice Boltzmann method [J].Electrochimica Acta，2024，476：143702.

BAE Y，LEE S，YOON K J，et al.Three-dimensional dynamic modeling and transport analysis of solid oxide fuel cells under electrical load change [J]. Energy Conversion and Management，2018，165：405-418.

赵鸿飞，陈前昌，宗正，等.可逆固体氧化物电池发电-电解条件下的运行特性分析[J].电工电能新技术，2022，41（3）：23-32.

ZHAO Hongfei，CHEN Qianchang，ZONG Zheng，et al.Analysis of steady-state characteristics in reversible solid oxide cell[J].Advanced Technology of Electrical Engineering and Energy，2022，41（3）：23-32.

ZONG Zheng，ZHOU Jun，ZHANG Zihang，et al. Dynamic analysis of current overshoots in reversible solid oxide cells [J].International Journal of Hydrogen Energy，2021，46（70）：34896-34911.

赵鸿飞，周峻，宗正，等.可逆固体氧化物电池模式切换时的动态特性分析[J].可再生能源，2022，40（12）：1577-1582.

ZHAO Hongfei，ZHOU Jun，ZONG Zheng，et al. Dynamic characterization of reversible solid oxide cells during the mode-switching process [J].Renewable Energy Resources，2022，40（12）：1577-1582.

JI Chengze，ZHOU Jun，WU Kai，et al.Research on current density overshoot of reversible solid oxide cell during mode switching [C]//2024 9th Asia Conference on Power and Electrical Engineering（ACPEE）.Piscataway，NJ，USA：IEEE，2024：2706-2710.

冀承泽，宗正，戈阳阳，等.可逆固体氧化物电池电-氢双向瞬态转换特性及电流超调机制[J].高电压技术，2025，51（5）：2200-2209.

JI Chengze，ZONG Zheng，GE Yangyang，et al. Transient characteristics and current overshoot mechanism of reversible solid oxide cells during bidirectional mode switching between power generation and hydro gen production[J].High Voltage Engineering，2025，51（5）：2200-2209.

BOTTA G，ROMEO M，FERNANDES A，et al.Dynamic modeling of reversible solid oxide cell stack and control strategy development [J].Energy Conversion and Management，2019，185：636-653.

JI Chengze，ZHOU Jun，SONG Xuhui，et al.Dynamic modeling and optimal control of switching modes in reversible solid oxide cells for integrated electric-hydrogen energy system [J].Applied Energy，2025，397：126270.

XING Xuetao，LIN Jin，SONG Yonghua，et al.Intermodule management within a large-capacity high-temperature power-to-hydrogen plant [J].IEEE Transactions on Energy Conversion，2020，35（3）：1432-1442.

TERA I，ZHANG Shengan，LIU Guilian.A conceptual hydrogen，heat and power polygeneration system based on biomass gasification，SOFC and waste heat recovery units：Energy，exergy，economic and emergy（4E）assessment [J].Energy，2024，295：131015.

周峻，冀承泽，李儒欢，等.电解水制氢技术发展现状及其在新型电力系统中的应用进展[J].高电压技术，2025，51（5）：2096-2113.

ZHOU Jun，JI Chengze，LI Ruhuan，et al.Recent development in the technology of water electrolysis and its applications to new power systems[J].High Voltage Engineering，2025，51（5）：2096-2113.

李远征，任潇，葛磊蛟，等.基于可逆固体氧化物电池的电氢耦合微电网全生命周期规划-运营研究[J].中国电机工程学报，2024，44（13）：5169-5184.

LI Yuanzheng，REN Xiao，GE Leijiao，et al.Research for entire lifecycle planning-operation of electrichydrogen coupled microgrid based on reversible solid oxide cell[J].Proceedings of the CSEE，2024，44（13）：5169-5184.

ZHANG Zihang，ZHOU Jun，ZONG Zheng，et al. Development and modelling of a novel electricity-hydrogen energy system based on reversible solid oxide cells and power to gas technology [J].International Journal of Hydrogen Energy，2019，44（52）：28305-28315.

ZHANG Xuzheng，YU Haoyu，ZHAO Hongfei，et al.Optimal operation of RSOC integrated energy systems considering multi-state transitions [J].Journal of Physics：Conference Series，2022，2404（1）：012023.

黄缨惠，朱振山，温步瀛，等.基于可逆固体氧化物电池的电热氢耦合孤岛微电网容量规划[J/OL].电网技术.（2025-05-28）[2025-08-16].https://doi.org/10.13335/j.1000-3673.pst.2025.0054.

HUANG Yinghui，ZHU Zhenshan，WEN Buying，et al.Capacity planning of electric-thermal-hydrogen coupled island microgrid based on reversible solid oxide cell[J/OL].Power System Technology.（2025-05-28）[2025-08-16].https://doi.org/10.13335/j.1000-3673.pst.2025 .0054.

LI Ruhuan，ZHOU Jun，QIU Zitong，et al.Optimal model-based electrochemical characteristics and thermal management of reversible solid oxide cells [J]. Applied Energy，2025，395：126204.

李儒欢，余浩宇，张旭征，等.计及电价波动的可逆固体氧化物电池“发电-电解产气”综合能源系统建模分析[J].全球能源互联网，2023，6（5）：447-458.

LI Ruhuan，YU Haoyu，ZHANG Xuzheng，et al. Modeling and analysis of “power generation-electrolysis for gas production”integrated energy system of reversible solid oxide battery with electricity price fluctuation[J].Journal of Global Energy Interconnection，2023，6（5）：447-458.

张鹏，张自航，周峻，等.可逆固体氧化物电池在低碳能源系统中的应用前景与挑战[J].电网与清洁能源，2020，36（6）：54-63.

ZHANG Peng，ZHANG Zihang，ZHOU Jun，et al. Application prospects and challenges of reversible solid oxide cells in the low-carbon energy system[J].Power System and Clean Energy，2020，36（6）：54-63.

LI Ruhuan，ZHOU Jun，QIU Zitong，et al.Bi-level optimization of hybrid energy conversion system based on a multi-distinct low-carbon microgrid [J].Renewable Energy，2025，239：122095.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

油电混合-机液复合动力传动系统模式切换协调控制

液压机械传动装置模式切换滚动协调控制

EBSILON软件在热电联产系统优化中的应用综述

电子级超纯氮深冷空分流程节能优化研究

结构-语义-残差协同的图像压缩框架：面向隐私保护与高保真重建