长安大学道路施工技术与装备教育部重点实验室,710064,西安
长安大学工程机械学院,710064,西安
作者简介:马玉钦(1986—),男,副教授。
收稿:2025-08-28,
纸质出版:2026-02-10
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马玉钦, 姚银树, 吕晋书, 等. 氧化石墨烯改性编织碳纤维复合材料弯曲性能研究[J]. 西安交通大学学报, 2026,60(2):218-228.
MA Yuqin, YAO Yinshu, LÜ Jinshu, et al. Study on Bending Performance of Graphene Oxide-Modified Woven Carbon Fiber Composites[J]. Journal of Xi'an Jiaotong University, 2026, 60(2): 218-228.
马玉钦, 姚银树, 吕晋书, 等. 氧化石墨烯改性编织碳纤维复合材料弯曲性能研究[J]. 西安交通大学学报, 2026,60(2):218-228. DOI: 10.7652/xjtuxb202602021.
MA Yuqin, YAO Yinshu, LÜ Jinshu, et al. Study on Bending Performance of Graphene Oxide-Modified Woven Carbon Fiber Composites[J]. Journal of Xi'an Jiaotong University, 2026, 60(2): 218-228. DOI: 10.7652/xjtuxb202602021.
为了提高编织碳纤维复合材料的力学性能及其在实际工程中的应用,提出通过引进氧化石墨烯(GO)并调整其质量分数来优化复合材料力学性能。采用真空浸渗热压工艺制备GO质量分数为0~0.5%的编织碳纤维复合材料,对其进行三点弯曲试验并借助扫描电子显微镜表征微观断口形貌;同时构建代表性体积单元模型,导入仿真软件中进行三点弯曲仿真分析。结果表明:随着GO质量分数从0增至0.5%,材料极限弯曲载荷从150 N提升至292 N,增幅近95%;弯曲强度和模量在其质量分数为0.5%时达最优,分别为164.71 MPa和9.97 GPa,较未添加GO的样品分别提升93.02%和49.47%。试验与仿真结果变化趋势一致且吻合良好,说明GO的添加对碳纤维复合材料微观组织和力学性能影响显著,且在其质量分数为0.5%时作用最突出。该研究结果为高性能碳纤维复合材料的设计与制备提供了数据支撑和理论参考。
To enhance the mechanical properties of woven carbon fiber composites and promote their application in practical engineering,an optimization approach by introducing graphene oxide(GO)and adj usting its mass fraction is proposed.Woven carbon fiber composites with GO mass fractions ranging from 0 to 0.5% were fabricated using vacuum impregnation and hot-pressing processes.Three-point bending tests were performed,and the micro-fracture morphology was characterized by scanning electron microscopy.Concurrently,a representative volume element model was constructed and imported into simulation software for three-point bending simulation analysis. The results show that as the GO mass fraction increases from 0 to 0.5%,the ultimate bending load of the material increases from 150 N to 292 N,representing an improvement of nearly 95%. The bending strength and modulus reach optimal values at a GO mass fraction of 0.5%,measuring 164.71 MPa and 9.97 GPa,respectively,which are 93.02% and 49.47% higher than those of samples without GO.The experimental and simulation results exhibit consistent trends and good agreement,indicating that the addition of GO significantly influences the microstructure and mechanical properties of woven carbon fiber composites,with the most pronounced effect observed at a GO mass fraction of 0.5%.This study provides data support and theoretical reference for the design and fabrication of high-performance carbon fiber composites.
SAYAM A, RAHMAN A N M M, RAHMAN M S, et al.A review on carbon fiber-reinforced hierarchical composites: mechanical performance, manufacturing process, structural applications and allied challenges[J]. Carbon Letters, 2022, 32(5):1173-1205.
ALTIN KARATAŞM, GÖKKAYA H.A review on machinability of carbon fiber reinforced polymer (CFRP)and glass fiber reinforced polymer (GFRP) composite materials[J].Defence Technology, 2018, 14(4):318-326.
ZHANG Zhenzhen, TIE Ying, FAN Congjie, et al. Multiscale analysis of impact-resistance in self-healing poly(ethylene-co-methacrylic acid)(EMAA)plain woven composites[J].Polymers, 2024, 16(19):2740.
KWON D J, PARK S M, KWON I J, et al.Improvement of interlaminar properties of carbon fiber-reinforced epoxy composites using aluminum trihydroxide[J]. Carbon Letters, 2019, 29(2):183-191.
刘玉婷,姚婷婷,宋红艳,等.氧化石墨烯/炭纤维复合增强体的制备及对环氧树脂复合材料界面性能影响[J].新型炭材料, 2018, 33(6):595-604.
LIU Yuting, YAO Tingting, SONG Hongyan, et al. Preparation of carbon fibers grafted to graphene oxide as a reinforcement for epoxy matrix composites[J]. New Carbon Materials, 2018, 33(6):595-604.
叶国锐,晏义伍,曹海琳.氧化石墨烯改性玄武岩纤维及其增强环氧树脂复合材料性能[J].复合材料学报, 2014, 31(6):1402-1408.
YE Guorui, YAN Yiwu, CAO Hailin.Basalt fiber modified with graphene oxide and properties of its reinforced epoxy composites[J].Acta Materiae Compositae Sinica, 2014, 31(6):1402-1408.
ALTIN Y, YILMAZ H, UNSAL O F, et al.Graphene oxide modified carbon fiber reinforced epoxy composites[J].Journal of Polymer Engineering, 2020, 40(5):415-420.
ACAR V, ERDEN S, SARIKANAT M, et al.Graphene oxide modified carbon fiber prepregs:a mechanical comparison of the effects of oxidation methods[J]. Express Polymer Letters, 2020, 14(12):1106-1115.
许欢,叶蓓,陆晶晶,等.硅聚物-氧化石墨烯增强玻璃纤维/环氧树脂复合材料的制备与性能[J].复合材料学报, 2024, 41(11):5976-5984.
XU Huan, YE Bei, LÜ Jingjing, et al.Preparation and properties of silicone polymer-graphene oxide reinforced glass fiber/epoxy resin composites[J].Acta Materiae Compositae Sinica, 2024, 41(11):5976-5984.
侯永刚,吕生华,张佳,等.氧化石墨烯的制备及形成机理[J].精细化工, 2019, 36(4):559-567.
HOU Yonggang, LÜ Shenghua, ZHANG Jia, et al. Preparation and formation mechanism of graphene oxide[J].Fine Chemicals, 2019, 36(4):559-567.
JIANG Jianj un, YAO Xuming, XU Chumeng, et al.Influence of electrochemical oxidation of carbon fiber on the mechanical properties of carbon fiber/graphene oxide/epoxy composites[J].Composites Part A:Applied Science and Manufacturing, 2017, 95:248-256.
芦武刚,葛曷一.碳纤维-氧化石墨烯/环氧树脂复合材料界面性能研究[J/OL].化工新型材料.(2025-02-07)[2025-09-16].https://doi.org/10.19817/j.cnki. issn1006-3536.2025.11.032.
LU Wugang, GE Heyi.Study on the interface properties of carbon fiber graphene oxide/epoxy resin composites[J/OL].New Chemical Materials.(2025-02-07)[2025-09-16].https://doi.org/10.19817/j.cnki. issn1006-3536.2025.11.032.
ZHANG R L, GAO B, MA Q H, et al.Directly grafting graphene oxide onto carbon fiber and the effect on the mechanical properties of carbon fiber composites[J].Materials & Design, 2016, 93:364-369.
ZHANG Jun, KIM D, LEE D, et al.Optimized dispersion and multidimensional mechanical property enhancement mechanisms in reduced graphene oxide nanosheet reinforced epoxy composite coatings[J]. Diamond and Related Materials, 2025, 154:112194.
王杰.真空浸渗热压形状记忆复合材料及其性能研究[D].西安:西安电子科技大学, 2021.
水丽,张凯,于宏.石墨烯含量对石墨烯/Al-15 Si-4Cu-Mg复合材料微观组织和力学性能的影响[J].工程科学学报, 2019, 41(9):1162-1167.
SHUI Li, ZHANG Kai, YU Hong.Effect of graphene content on the microstructure and mechanical properties of graphene-reinforced Al-15 Si-4 Cu-Mg matrix composites[J].Chinese Journal of Engineering, 2019, 41(9):1162-1167.
SHIN S E, BAE D H.Deformation behavior of aluminum alloy matrix composites reinforced with few-layer graphene[J].Composites:Part A Applied Science and Manufacturing, 2015, 78:42-47.
中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.纤维增强塑料弯曲性能试验方法:GB/T 1449—2005[S].北京:中国标准出版社, 2005.
左殿军,陈文亮.DIGIMAT非线性复合材料多尺度模拟平台应用基础[M].北京:中国建筑工业出版社, 2021.
权国政,武东森,黄小双,等.基于Hashin准则的E-玻纤2D编织层铺增强复合材料冲击损伤力学分析[J].功能材料, 2013, 44(S2):334-343.
QUAN Guozheng, WU Dongsen, HUANG Xiaoshuang, et al.Study on the E-glass fiber 2D reinforced compos ite constitutive model of damage mechanics based on Hashin criterion[J].Journal of Functional Materials, 2013, 44(S2):334-343.
张松俊.基于多尺度模型的二维三轴编织复合材料的损伤破坏机理研究[D].长沙:湖南大学, 2018.
王成聃.石墨烯和陶瓷复合材料力学性能的多尺度模拟[D].南京:东南大学, 2021.
刘延超.短柱增强体金属基复合材料的剪切滞后分析[D].沈阳:沈阳工业大学, 2014.
陈宇飞,赵辉,滕成君.MAH-GO/MBMI-E51复合材料的微观结构及力学性能[J].复合材料学报, 2022 , 39(2):601-607.
CHEN Yufei, ZHAO Hui, TENG Chengjun.Microstructure and mechanical properties ofMAH-GO/MB-MI-E51 composites[J].Acta Materiae Compositae Sinica, 2022, 39(2):601-607.
胡涛,赵东林,程兴旺,等.氧化石墨烯增强环氧树脂复合材料的制备及其力学性能研究[J].北京化工大学学报(自然科学版), 2018, 45(6):29-33.
HU Tao, ZHAO Donglin, CHENG Xingwang, et al. Preparation and mechanical properties of graphene oxide reinforced epoxy composites[J].Journal of Beijing University of Chemical Technology (Natural Science Edition), 2018, 45(6):29-33.
ACOCELLA M R, CORCIONE C E, GIURI A, et al. Graphene oxide as a catalyst for ring opening reactions in amine crosslinking of epoxy resins[J].RSC Advances, 2016, 6(28):23858-23865.
PATHAK A K, BORAH M, GUPTA A, et al.Improved mechanical properties of carbon fiber/graphene oxide-epoxy hybrid composites[J].Composites Science and Technology, 2016, 135:28-38.
LIU Liu, YAN Fei, LI Ming, et al.Improving interfacial properties of hierarchical reinforcement carbon fibers modified by graphene oxide with different bonding types[J].Composites:Part A Applied Science and Manufacturing, 2018, 107:616-625.
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