球形颗粒内三重周期极小曲面结构的甲烷水蒸气重整制氢反应性能研究

吴志宏; 杨剑; 王秋旺

doi:10.7652/xjtuxb202510006

您当前的位置：

首页 >

文章列表页 >

球形颗粒内三重周期极小曲面结构的甲烷水蒸气重整制氢反应性能研究

更新时间：2025-09-28

- 球形颗粒内三重周期极小曲面结构的甲烷水蒸气重整制氢反应性能研究
- Study on the Performance of Methane Steam Reforming Reaction for Hydrogen Production in Spherical Particles with Triply Periodic Minimal Surface Structures
- 西安交通大学学报 2025年59卷第10期页码：64-74
- 作者机构：
- 作者简介：
  
  作者简介：吴志宏（1996—），男，博士生；
  王秋旺（通信作者），男，教授，博士生导师。
- 基金信息：
  
  国家自然科学基金资助项目。(52130609)
- DOI：10.7652/xjtuxb202510006
  中图分类号： TK124
- 收稿：2025-02-12，
  
  纸质出版：2025-10-10
- 稿件说明：
移动端阅览
吴志宏, 杨剑, 王秋旺. 球形颗粒内三重周期极小曲面结构的甲烷水蒸气重整制氢反应性能研究[J]. 西安交通大学学报, 2025,59(10):64-74.

WU Zhihong, YANG Jian, WANG Qiuwang. Study on the Performance of Methane Steam Reforming Reaction for Hydrogen Production in Spherical Particles with Triply Periodic Minimal Surface Structures[J]. Journal of Xi'an Jiaotong University, 2025, 59(10): 64-74.
吴志宏, 杨剑, 王秋旺. 球形颗粒内三重周期极小曲面结构的甲烷水蒸气重整制氢反应性能研究[J]. 西安交通大学学报, 2025,59(10):64-74. DOI： 10.7652/xjtuxb202510006.

WU Zhihong, YANG Jian, WANG Qiuwang. Study on the Performance of Methane Steam Reforming Reaction for Hydrogen Production in Spherical Particles with Triply Periodic Minimal Surface Structures[J]. Journal of Xi'an Jiaotong University, 2025, 59(10): 64-74. DOI： 10.7652/xjtuxb202510006.

摘要

为优化颗粒堆积床内的催化剂几何结构并提升制氢效率，研究了三重周期极小曲面结构催化剂对甲烷水蒸气重整反应的影响。使用固体颗粒法数值模拟对比了三重周期极小曲面结构催化剂颗粒与传统通孔催化剂颗粒、球形催化剂颗粒的流动、换热、反应性能。以发生反应的催化剂颗粒为研究对象并结合传统热阻理论，提出了一种热阻评价方法，从热量传递与转化的角度探索反应器内制氢反应的性能。结果表明：所提热阻评价方法可以反映出制氢反应的性能规律；三重周期极小曲面结构球形催化剂，在流动性能上比普通球形结构降低了22.97%的流动能量损耗；在换热性能上具有最高的出口温度，比普通球形结构提高了4.48K，减小了28.68%的对流换热热阻；在反应性能上具有最大的制氢速率，比普通球形结构提高了49.93%，减小了27.45%的化学反应热热阻；综合来看，降低了28.03%的综合热阻。研究结果说明了三重周期极小曲面结构在甲烷水蒸气重整反应中的高效性，并为颗粒堆积床内的性能比较提供了新的分析方法。

Abstract

To optimize catalyst geometric structures in packed beds and enhance hydrogen production efficiency

the effects of triple-periodic minimal surface (TPMS) structured catalysts on methane steam reforming reactions is investigated. The solid particle method is employed for numerical simulations comparing the flow

heat transfer

and reaction performance among TPMS-structured catalyst particles

conventional through-hole catalyst particles

and spherical catalyst particles. By analyzing reactive catalyst particles and incorporating classical thermal resistance theory

a novel thermal resistance evaluation method is developed to evaluate hydrogen production performance from the perspective of heat transfer and conversion. Results demonstrate that: The proposed thermal resistance evaluation method effectively reflects hydrogen production performance characteristics；the TPMS-structured spherical catalysts reduce flow energy loss by 22.97% compared to conventional spherical structures；in terms of heat transfer performance

they achieve the highest outlet temperature

showing a 4.48K increase over conventional spherical structures while reducing convective heat transfer resistance by 28.68%；regarding reaction performance

they exhibit the maximum hydrogen production rate

which is 49.93% higher than that of conventional spherical structures

along with a 27.45% reduction in chemical reaction thermal resistance；overall

they achieve 28.03% reduction in total thermal resistance. These findings demonstrate the superior efficiency of TPMS structures in methane steam reforming and provide a novel analytical approach for performance evaluation in packed beds.

关键词

Keywords

references

郭烈锦 , 黄勇 , 王乐 , 等 . 农林业固废超临界水热化学制氢进展:反应系统及应用 [J ] . 西安交通大学学报 , 2023 , 57 ( 2 ): 1 - 11 .

GUO Liejin , HUANG Yong , WANG Le , et al . Review of thermochemical conversion of agriculture and forestry waste for hydrogen production in supercritical water:reaction systems and applications [J ] . Journal of Xi'an Jiaotong University , 2023 , 57 ( 2 ): 1 - 11 .

凌文 , 李全生 , 张凯 . 我国氢能产业发展战略研究 [J ] . 中国工程科学 , 2022 , 24 ( 3 ): 80 - 88 .

LING Wen , LI Quansheng , ZHANG Kai . Development strategy of hydrogen energy industry in China [J ] . Strategic Study of CAE , 2022 , 24 ( 3 ): 80 - 88 .

ANWAR S , LI Xianguo . Production of hydrogen from fossil fuel:a review [J ] . Frontiers in Energy , 2023 , 17 ( 5 ): 585 - 610 .

闫翔昱 , 吕布楚 , 刘启斌 . 光热协同甲醇水蒸气重整制氢实验和微观机理研究 [J ] . 西安交通大学学报 , 2024 , 58 ( 1 ): 81 - 88 .

YAN Xiangyu , LÜ Buchu , LIU Qibin . Experimental and microscopic mechanism investigation of photothermal methanol steam reforming for hydrogen production [J ] . Journal of Xi'an Jiaotong University , 2024 , 58 ( 1 ): 81 - 88 .

WU Yujie , ZHU Xiaorong , DU Shiqian , et al . Promoted hydrogen and acetaldehyde production from alcohol dehydrogenation enabled by electrochemical hydrogen pumps [J ] . Proceedings of the National Academy of Sciences , 2023 , 120 ( 27 ): e2300625120 .

陈冠益 , 高文学 , 马文超 . 生物质制氢技术的研究现状与展望 [J ] . 太阳能学报 , 2006 , 27 ( 12 ): 1276 - 1284 .

CHEN Guanyi , GAO Wenxue , MA Wenchao . Review on hydrogen-rich gas production from biomass [J ] . Acta Energiae Solaris Sinica , 2006 , 27 ( 12 ): 1276 - 1284 .

IEA . Global hydrogen review 2023 [EB/OL ] .( 2023-09-01 )[ 2025-01-01 ] . https://www.iea.org/reports/global-hydrogen-review-2023 .

PASHCHENKO D , MAKAROV I . Carbon deposition in steam methane reforming over a Ni-based catalyst:experimental and thermodynamic analysis [J ] . Energy , 2021 , 222 : 119993 .

RICHTER J , RACHOW F , ISRAEL J , et al . Reaction mechanism development for methane steam reforming on a Ni/Al 2 O 3 catalyst [J ] . Catalysts , 2023 , 13 ( 5 ): 884 .

ZHANG Jianan , ZHAO Min , YIN Zhiwen , et al . Modification of Al 2 O 3 -based catalyst by rare earth elements for steam reforming of methane [J ] . AIChE Journal , 2023 , 69 ( 7 ): e18070 .

ZARE A A D , YARI M , NAMI H , et al . Low-carbon hydrogen,power and heat production based on steam methane reforming and chemical looping combustion [J ] . Energy Conversion and Management , 2023 , 279 : 116752 .

CAI Lei , HE Tianzhi , XIANG Yanlei , et al . Study on the reaction pathways of steam methane reforming for H 2 production [J ] . Energy , 2020 , 207 : 118296 .

KARPILOV I , PASHCHENKO D . Steam methane reforming over a preheated packed bed:heat and mass transfer in a transient process [J ] . Thermal Science and Engineering Progress , 2023 , 42 : 101868 .

DIXON A G , TASKIN M E , NIJEMEISLAND M , et al . CFD method to couple three-dimensional transport and reaction inside catalyst particles to the fixed bed flow field [J ] . Industrial & Engineering Chemistry Research , 2010 , 49 ( 19 ): 9012 - 9025 .

BEHNAM M , DIXON A G , WRIGHT P M , et al . Comparison of CFD simulations to experiment under methane steam reforming reacting conditions [J ] . Chemical Engineering Journal , 2012 , 207/208 : 690 - 700 .

ZHAO Chunrong , OPOLOT M , LIU Ming , et al . Numerical study of melting performance enhancement for PCM in an annular enclosure with internal-external fins and metal foams [J ] . International Journal of Heat and Mass Transfer , 2020 , 150 : 119348 .

KARTHIK G M , BUWA V V . Effect of particle shape on fluid flow and heat transfer for methane steam reforming reactions in a packed bed [J ] . AIChE Journal , 2017 , 63 ( 1 ): 366 - 377 .

DIXON A G , BOUDREAU J , ROCHELEAU A , et al . Flow, transport, and reaction interactions in shaped cylindrical particles for steam methane reforming [J ] . Industrial & Engineering Chemistry Research , 2012 , 51 ( 49 ): 15839 - 15854 .

THOMAS N , SREEDHAR N , AL-KETAN O , et al . 3D printed triply periodic minimal surfaces as spacers for enhanced heat and mass transfer in membrane distillation [J ] . Desalination , 2018 , 443 : 256 - 271 .

LI Weihong , YU Guopeng , YU Zhibin . Bioinspired heat exchangers based on triply periodic minimal surfaces for supercritical CO 2 cycles [J ] . Applied Thermal Engineering , 2020 , 179 : 115686 .

CHENG Zhilong , LI Xiaoyang , XU Ruina , et al . Investigations on porous media customized by triply periodic minimal surface:heat transfer correlations and strength performance [J ] . International Communications in Heat and Mass Transfer , 2021 , 129 : 105713 .

HOU Kaihu , HUGHES R . The kinetics of methane steam reforming over a Ni/α-Al 2 O catalyst [J ] . Chemical Engineering Journal , 2001 , 82 ( 1/2/3 ): 311 - 328 .

CALIS H P A , NIJENHUIS J , PAIKERT B C , et al . CFD modelling and experimental validation of pressure drop and flow profile in a novel structured catalytic reactor packing [J ] . Chemical Engineering Science , 2001 , 56 ( 4 ): 1713 - 1720 .

ROMKES S J P , DAUTZENBERG F M , VAN DEN BLEEK C M , et al . CFD modelling and experimental validation of particle-to-fluid mass and heat transfer in a packed bed at very low channel to particle diameter ratio [J ] . Chemical Engineering Journal , 2003 , 96 ( 1/2/3 ): 3 - 13 .

VANDERMEERSCH T , GOOVAERTS R , LUYTEN J , et al . Tracking the liquid-liquid extraction performance in mesoflow reactors [J ] . Chemical Engineering Journal , 2015 , 279 : 9 - 17 .

厉勇 , 张英 , 王元华 . 甲烷水蒸气重整技术研究现状及进展 [J ] . 炼油技术与工程 , 2019 , 49 ( 7 ): 1 - 7 .

LI Yong , ZHANG Ying , WANG Yuanhua . Research status and progress of methane steam reforming technology [J ] . Petroleum Refinery Engineering , 2019 , 49 ( 7 ): 1 - 7 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

风光火储耦合氢储能系统的制储氢容量优化和可行性分析

废旧轮胎热解吸附强化重整制氢特性及经济性分析

生物质与煤超临界水气化制氢的实验研究

生物质/煤超临界水气化制氢的主要影响因素

面向高海拔空冷发电机防晕性能演化规律的电热耦合研究