运行参数对质子交换膜燃料电池堆耐久性影响的实验研究

蔡赛杰; 朱昊宁; 张卓; 陈俊宏; 陶文铨

doi:10.7652/xjtuxb202505001

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运行参数对质子交换膜燃料电池堆耐久性影响的实验研究

专题　储能技术 | 更新时间：2025-08-26

- 运行参数对质子交换膜燃料电池堆耐久性影响的实验研究
- Experimental Study on the Impact of Operating Parameters on the Durability of Proton Exchange Membrane Fuel Cell Stacks
- 西安交通大学学报 2025年59卷第5期页码：1-11
- 作者机构：
  
  西安交通大学能源与动力工程学院， 710049，西安
- 作者简介：
  
  蔡赛杰（1995—），男，博士生；
  陶文铨（通信作者），男，教授，博士生导师，中国科学院院士。
- 基金信息：
  
  陕西省重点研发计划资助项目(2019ZDXM3-01);国家储能技术产教融合创新平台（中心）基金资助项目;中国博士后创新人才支持计划资助项目(BX20240285M)
- DOI：10.7652/xjtuxb202505001
  中图分类号： TK91
- 收稿：2024-10-29，
  
  网络首发：2025-01-22，
  
  纸质出版：2025-05-10
- 稿件说明：
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蔡赛杰, 朱昊宁, 张卓, 等. 运行参数对质子交换膜燃料电池堆耐久性影响的实验研究[J]. 西安交通大学学报, 2025,59(5):1-11.

CAI Saijie, ZHU Haoning, ZHANG Zhuo, et al. Experimental Study on the Impact of Operating Parameters on the Durability of Proton Exchange Membrane Fuel Cell Stacks[J]. Journal of Xi’an Jiaotong University, 2025, 59(5): 1-11.
蔡赛杰, 朱昊宁, 张卓, 等. 运行参数对质子交换膜燃料电池堆耐久性影响的实验研究[J]. 西安交通大学学报, 2025,59(5):1-11. DOI： 10.7652/xjtuxb202505001.

CAI Saijie, ZHU Haoning, ZHANG Zhuo, et al. Experimental Study on the Impact of Operating Parameters on the Durability of Proton Exchange Membrane Fuel Cell Stacks[J]. Journal of Xi’an Jiaotong University, 2025, 59(5): 1-11. DOI： 10.7652/xjtuxb202505001.

摘要

针对质子交换膜燃料电池（PEMFC）在多变工况下的耐久性较差的问题，研究了氢燃料电池电堆老化过程中的气体分配、电压恢复和电压衰减速率规律、单片电池膜电极参数之间的差异和电池老化之间的关系。基于新欧洲驾驶循环标准工况制定了耐久性测试流程，在自行设计的8片PEMFC电堆上进行了80 h加速老化测试。实验结果显示，电堆基准电压的平均衰减速率为1.4 mV/h，考虑重启造成的水热状态恢复引起的电压上升，电堆的平均衰减速率降低为0.55 mV/h。各膜电极老化前后的电化学反应面积变化在7%~12%，但其他膜电极指标存在显著差异，表明水热状态存在较大差异。从空气分配特性看，单电池空气侧的流量分布及电压衰减速率呈双峰分布，且随着流量增大，峰值差异加大，流量高点对应的电压衰减速率达到最高，表明老化速率与空气侧流量正相关。靠近端板的电池老化程度明显高于平均水平，但电压衰减速率并非最大，表明其主要经历了可逆老化，较高的电压恢复速率也验证了这一点，中间电池的老化速率都在0.6 mV/h左右。

Abstract

To address the issue of limited durability of limited durability of proton exchange membrane fuel cells (PEMFC) under variable operating conditions

the gas distribution

voltage recovery

and voltage decay rate patterns during the aging process of hydrogen fuel cell stacks

as well as the relationship between variations in membrane electrode assembly (MEA) parameters among individual cells and cell aging was investigated. A durability testing procedure based on the new European driving cycle standard working conditions was established and an accelerated aging test for 80 hours was conducted on a self-designed 8-cell PEMFC stack. The results show that the average baseline voltage decay rate of the stack is 1.4 mV/h

decreasing to 0.55 mV/h considering the voltage increase caused by the recovery of water-thermal state due to restart. The change in the electrochemical reaction area of various membrane electrode assemblies before and after aging ranged between 7% and 12%

but significant differences were observed in other MEA indicators

indicating large variations in the water-thermal state. In terms of air distribution characteristics

the air flow rate distribution and voltage decay rate on the air side of individual cells exhibited a bimodal pattern. As the flow rate increases

the difference in peak values becomes more pronounced. The highest voltage decay rates corresponded to the highest flow rates

suggesting a positive correlation between aging rate and air flow. The cells near the end plates showed higher aging levels than the average

but their voltage decay rates were not the highest

indicating primarily reversible aging

which was further confirmed by higher voltage recovery rates. The aging rates of the middle cells were around 0.6 mV/h.

关键词

Keywords

references

ZHANG Guobin , QU Zhiguo , TAO Wenquan , et al . Advancing next-generation proton-exchange membrane fuel cell development in multi-physics transfer [J ] . Joule , 2024 , 8 ( 1 ): 45 - 63 .

HUO Wenming , FAN Linhao , XU Yunfei , et al . Digitally-assisted structure design of a large-size proton exchange membrane fuel cell [J/OL ] . Energy & Environmental Science . ( 2024-11-22 ) [ 2024-09-12 ] . http://dx.doi.org/10.1039/D4EE04713C http://dx.doi.org/10.1039/D4EE04713C .

HE Pu , CHEN Junhong , ZHANG Chenzi , et al . Optimization of modeling and temperature control of air-cooled PEMFC based on TLBO-DE [J ] . Energy and AI , 2024 , 18 : 100430 .

CHEN Junhong , HE Pu , HE Zehong , et al . Multi-objective decoupling control of thermal management system for PEM fuel cell [J ] . Energy and AI , 2024 , 18 : 100447 .

CHEN Junhong , HE Pu , CAI Saijie , et al . Modeling and temperature control of a water-cooled PEMFC system using intelligent algorithms [J ] . Applied Energy , 2024 , 372 : 123790 .

ZHAO Jian , LI Xianguo . A review of polymer electrolyte membrane fuel cell durability for vehicular applications: degradation modes and experimental techniques [J ] . Energy Conversion and Management , 2019 , 199 : 112022 .

WANG Yun , PANG Yiheng , XU Hui , et al . PEM Fuel cell and electrolysis cell technologies and hydrogen infrastructure development: a review [J ] . Energy & Environmental Science , 2022 , 15 ( 6 ): 2288 - 2328 .

REN Peng , PEI Pucheng , LI Yuehua , et al . Degradation mechanisms of proton exchange membrane fuel cell under typical automotive operating conditions [J ] . Progress in Energy and Combustion Science , 2020 , 80 : 100859 .

SHARMA P , CHENG Lei , AARON D , et al . Unveiling local aging patterns following accelerated stress testing of high-performance polymer electrolyte fuel cells [J ] . Small , 2024 , 20 ( 16 ): 2306433 .

NIU Meixuan , GAO Yuan , PAN Qiwen , et al . Review on factors of voltage consistency and inconsistent degradation in proton exchange membrane fuel cells [J ] . Ionics , 2024 , 30 ( 5 ): 2433 - 2458 .

CHEN Huicui , SONG Zhen , ZHAO Xin , et al . A review of durability test protocols of the proton exchange membrane fuel cells for vehicle [J ] . Applied Energy , 2018 , 224 : 289 - 299 .

DONG Enci , CAO Sida , ZHANG Ruiyuan , et al . A one-dimensional numerical model of carbon corrosion in catalyst layers of proton exchange membrane fuel cells [J ] . Electrochimica Acta , 2024 , 483 : 144030 .

DONG Enci , ZHAO Hancheng , ZHANG Ruiyuan , et al . Effects of gradient structures of cathode catalyst layers on performance and durability of proton exchange membrane fuel cells [J ] . Electrochimica Acta , 2024 , 477 : 143772 .

WU Jinfeng , YUAN Xiaozi , MARTIN J J , et al . A review of PEM fuel cell durability: degradation mechanisms and mitigation strategies [J ] . Journal of Power Sources , 2008 , 184 ( 1 ): 104 - 119 .

NANDJOU F , POIROT-CROUVEZIER J P , CHANDESRIS M , et al . Impact of heat and water management on proton exchange membrane fuel cells degradation in automotive application [J ] . Journal of Power Sources , 2016 , 326 : 182 - 192 .

YANG Yunjie , BAI Minli , ZHOU Zhifu , et al . Comparison of lifetime performance of PEMFC stacks with two cooling strategies under different humidity [J ] . International Journal of Heat and Mass Transfer , 2024 , 231 : 125870 .

LIU D , CASE S . Durability study of proton exchange membrane fuel cells under dynamic testing conditions with cyclic current profile [J ] . Journal of Power Sources , 2006 , 162 ( 1 ): 521 - 531 .

WAHDAME B , CANDUSSO D , FRANÇOIS X , et al . Comparison between two PEM fuel cell durability tests performed at constant current and under solicitations linked to transport mission profile [J ] . International Journal of Hydrogen Energy , 2007 , 32 ( 17 ): 4523 - 4536 .

LIN R , LI B , HOU Y P , et al . Investigation of dynamic driving cycle effect on performance degradation and micro-structure change of PEM fuel cell [J ] . International Journal of Hydrogen Energy , 2009 , 34 ( 5 ): 2369 - 2376 .

PANHA K , FOWLER M , YUAN Xiaozi , et al . Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells [J ] . Applied Energy , 2012 , 93 : 90 - 97 .

FOWLER M , AMPHLETT J C , MANN R F , et al . Issues associated with Voltage Degradation in a PEMFC [J ] . Journal of New Materials for Electrochemical Systems , 2002 , 5 ( 4 ): 255 - 262 .

国家市场监督管理总局 , 国家标准化管理委员会 . 车用质子交换膜燃料电池堆使用寿命测试评价方法：GB/T 38914—2020 [S ] . 北京 : 中国标准出版社 , 2020 .

HE Pu , MU Yutong , PARK J W , et al . Modeling of the effects of cathode catalyst layer design parameters on performance of polymer electrolyte membrane fuel cell [J ] . Applied Energy , 2020 , 277 : 115555 .

SINGH Y , ORFINO F P , DUTTA M , et al . 3D failure analysis of pure mechanical and pure chemical degradation infuel cell membranes [J ] . Journal of the Electrochemical Society , 2017 , 164 ( 13 ): F1331 - F1341 .

王家军 , 耿江涛 , 邵志刚 , 等 . 氢燃料电池电堆寿命影响因素及机理分析 [J ] . 电源技术 , 2023 , 47 ( 5 ): 551 - 557 .

WANG Jiajun , GENG Jiangtao , SHAO Zhigang , et al . Influence factors and mechanisms of lifetime in hydrogen fuel cell stack [J ] . Chinese Journal of Power Sources , 2023 , 47 ( 5 ): 551 - 557 .

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