环氧树脂醇解回收再制备固化动力学研究

赵鑫; 李文栋; 郭旺; 杨雄; 郭广致; 邹方正; 高国新; 张冠军

doi:10.7652/xjtuxb202407009

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环氧树脂醇解回收再制备固化动力学研究

—————————————————————— | 更新时间：2025-07-28

- 环氧树脂醇解回收再制备固化动力学研究
- Research on Alcoholysis Recovery, Re-Preparation, and Curing Kinetics of Epoxy Resin
- 西安交通大学学报 2024年58卷第7期页码：94-104
- 作者机构：
  
  1. 西安交通大学电工材料电气绝缘全国重点实验室,西安,710049
  2. 国网冀北电力有限公司廊坊供电公司,河北,廊坊,065099
  3. 西安交通大学化学学院,西安,710049
- 作者简介：
  
  : 2023-12-18。作者简介: 赵鑫(1997—),男,博士生
  张冠军(通信作者),男,教授,博士生导师。基金项目: 陕西省重点研发计划资助项目(2023-YBGY-394)
- 基金信息：
  
  : 2023-12-18。作者简介: 赵鑫(1997—),男,博士生;张冠军(通信作者),男,教授,博士生导师。基金项目: 陕西省重点研发计划资助项目(2023-YBGY-394);中国电力科学研究院科技项目(SGDK0000ZXJS2207558)
- DOI：10.7652/xjtuxb202407009
  中图分类号： TM215.1
- 纸质出版：2024
- 稿件说明：
移动端阅览
赵鑫, 李文栋, 郭旺, 等. 环氧树脂醇解回收再制备固化动力学研究[J]. 西安交通大学学报, 2024,58(7):94-104.

ZHAO Xin, LI Wendong, GUO Wang, et al. Research on Alcoholysis Recovery, Re-Preparation, and Curing Kinetics of Epoxy Resin[J]. 2024, 58(7): 94-104.
赵鑫, 李文栋, 郭旺, 等. 环氧树脂醇解回收再制备固化动力学研究[J]. 西安交通大学学报, 2024,58(7):94-104. DOI： 10.7652/xjtuxb202407009.

ZHAO Xin, LI Wendong, GUO Wang, et al. Research on Alcoholysis Recovery, Re-Preparation, and Curing Kinetics of Epoxy Resin[J]. 2024, 58(7): 94-104. DOI： 10.7652/xjtuxb202407009.

摘要

针对利用环氧树脂醇解产物制备新树脂固化工艺缺乏分析的问题

首先运用非等温差示扫描量热法

研究了醇解产物含量对再制备树脂固化行为的影响。随后通过固化动力学模型

确定了再制备树脂的固化条件

并以此制备得到新树脂

测量了其介电性能。结果表明:当醇解产物替代双酚A二缩水甘油醚质量分数为25%时

再制备树脂的预固化温度小于120 ℃

后固化温度为160.57 ℃

这是因为

醇解产物中的羟基可促进环氧基的开环反应

使得再制备树脂的固化温度随醇解产物含量增加而降低; 再制备树脂符合自催化双参数固化动力学模型

总反应级数大于1

且固化过程中的表观活化能E

是固化程度α的函数

基于E

(α)函数得到试样实际固化程度接近理论值; 与原始环氧树脂相比

再制备树脂的相对介电常数、介质损耗和击穿电场强度有所增加

其介电性能满足电工用环氧树脂使用要求。该研究内容为醇解回收再制备环氧树脂的固化工艺提供了经验和指导。

Abstract

This study aims to fill the analysis gap regarding the curing process of new resin made from epoxy resin alcoholysis products. Initially

a non-isothermal differential scanning calorimetry method is employed to investigate the influence of alcoholysis product content on the curing behavior of the re-prepared resin. Subsequently

the curing conditions for the re-prepared resin are determined using a curing kinetics model. A new resin is synthesized accordingly

with its dielectric properties measured. The results indicate that substituting 25% bisphenol A diglycidyl ether with

alcoholysis products leads to a pre-curing temperature of the re-prepared resin below 120 ℃ and a final curing temperature of 160.57 ℃. This is attributed to that the hydroxyl groups in the alcoholysis products facilitate the ring-opening reaction of epoxy groups. Consequently

as the alcoholysis products increase

the curing temperature of the re-prepared resin decreases. The re-prepared resin conforms to a self-catalytic dual-parameter curing kinetics model

with a total reaction order exceeding 1. The apparent activation energy E

during the curing process is a function of the curing degree α

and the actual curing degree of the samples obtained from the E

(α)function closely matches theoretical values. Compared to the original epoxy resin

the re-prepared resin exhibits an increase in relative dielectric constant

dielectric loss

and breakdown strength

demonstrating the dielectric performance meeting the requirements for epoxy resins employed in power systems. This study offers valuable insights and guidance to the curing process of epoxy resin re-prepared from alcoholysis recovery.

关键词

Keywords

references

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