电化学阴极制氢耦合阳极废水污染物降解的研究进展

冯江涛; 孙娅星; 林长征; 朱金薇; 延卫

doi:10.7652/xjtuxb202312005

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电化学阴极制氢耦合阳极废水污染物降解的研究进展

—————————————————————— | 更新时间：2025-07-09

- 电化学阴极制氢耦合阳极废水污染物降解的研究进展
- Research Progress in Coupled Anodic Pollutant Degradation of Electrochemical Cathodic Hydrogen Production
- 西安交通大学学报 2023年57卷第12期页码：41-58
- 作者机构：
  
  1. 西安交通大学能源与动力工程学院,西安,710049
  2. 陕西电器研究所,西安,710025
- 作者简介：
  
  : 2023-05-12。作者简介: 冯江涛(1981—),男,教授,博士生导师。基金项目: 国家自然科学基金资助项目(52070155,51978569)。
- 基金信息：
  
  : 2023-05-12。作者简介: 冯江涛(1981—),男,教授,博士生导师。基金项目: 国家自然科学基金资助项目(52070155,51978569)。
- DOI：10.7652/xjtuxb202312005
  中图分类号： X131.2
- 网络首发：2023-12-10，
  
  纸质出版：2023
- 稿件说明：
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冯江涛, 孙娅星, 林长征, 等. 电化学阴极制氢耦合阳极废水污染物降解的研究进展[J]. 西安交通大学学报, 2023,57(12):41-58.

FENG Jiangtao, SUN Yaxing, LIN Changzheng, et al. Research Progress in Coupled Anodic Pollutant Degradation of Electrochemical Cathodic Hydrogen Production[J]. 2023, 57(12): 41-58.
冯江涛, 孙娅星, 林长征, 等. 电化学阴极制氢耦合阳极废水污染物降解的研究进展[J]. 西安交通大学学报, 2023,57(12):41-58. DOI： 10.7652/xjtuxb202312005.

FENG Jiangtao, SUN Yaxing, LIN Changzheng, et al. Research Progress in Coupled Anodic Pollutant Degradation of Electrochemical Cathodic Hydrogen Production[J]. 2023, 57(12): 41-58. DOI： 10.7652/xjtuxb202312005.

摘要

电解水制氢是一种绿色制氢技术

但其能源效率受到阳极析氧反应(OER)动力学的限制。针对这一问题

系统总结和论述了一种将电化学制氢与治污耦合来降低能耗的系统

该系统的优势是以阳极氧化污染物取代OER反应

在降低电解水制氢能耗的同时实现污染物的处理

达到制氢与治污的有机结合。论述了制氢和治污耦合系统中的电解槽设计对耦合反应的关键作用

设计合理的电解槽有利于获得更高的制氢和治污效率; 开发性能稳定的电极材料是实现高效制氢与治污耦合的另一关键方面

镍基、钴基、铜基材料及它们的复合材料都被作为电极材料用于电催化制氢和治污耦合系统

以提高系统的稳定性和制氢及有机污染物降解的效率; 醇类、酚类、醛类、尿素、肼、胺等有机物及液氨和含硫化合物等都被用于与制氢结合构成制氢和治污的耦合体系

这些物质的加入可以提高系统的电子利用率、防止O

混合

不仅可以实现绿色产氢

还能够在制氢的同时降解污染物甚至生成更高附加值的化学品。对有机物去除耦合电解水制氢系统的影响因素、反应机理和存在问题等进行了深入分析

以期为电解水制氢与治污耦合系统的研究和应用提供一定的理论依据

并对耦合系统投入实际应用所存在的机理、经济等方面的困境提出了对应的解决措施与展望。

Abstract

Water electrolysis is a green hydrogen production technology

but its energy efficiency is limited by the kinetics of anodic oxygen evolution reaction(OER). For this problem

this paper systematically summarizes and discusses a system coupling water electrolysis with pollution control to reduce energy consumption

which has an advantage that the OER reaction is replaced by anodic pollutant oxidation

which not only reduces the energy

consumed during the water electrolysis hydrogen production but also treats the pollutants

so as to integrate hydrogen production and pollution control. The important role of electrolytic cell design played in the coupling system was discussed

as a well-designed electrolytic cell is beneficial to the efficiency of hydrogen production and pollution control. The development of electrode materials with stable performance is also important for an efficient coupling system. Nickel-

cobalt-

or copper-based materials and their composites are all used as electrode materials in the coupling system to improve the stability and the efficiency of hydrogen production and organic pollutant degradation. Organic compounds such as alcohols

phenols

aldehydes

urea

hydrazine

and amines

as well as liquid ammonia and sulfur-containing compounds

are also used in the coupling system. The addition of these substances can improve the electronic utilization rate of the system and prevent O

mixing

achieving green hydrogen production and degrading pollutants or even generating higher value-added chemicals during the hydrogen production. This paper also analyzes the influencing factors

reaction mechanism and existing problems of the coupling system

in order to provide a theoretical basis for the research and application of the coupling system. In addition

this paper proposes corresponding solutions and prospects for the difficulties in the mechanism

economy

and other aspects of the application of the coupling system.

关键词

Keywords

references

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