西安交通大学金属材料强度国家重点实验室,西安,710049
: 2023-01-09。作者简介: 王宗科(1997—),男,硕士生
张贵锋(通信作者),男,教授,博士生导师。基金项目: 陕西省科技成果转移与推广计划-吸纳成果转化资助项目(2019CGXNG-026)
网络首发:2023-10-10,
纸质出版:2023
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王宗科, 张贵锋, 张誉. TC4钛合金与316L不锈钢感应钎焊接头的组织与性能[J]. 西安交通大学学报, 2023,57(10):153-162.
Microstructure and Properties of Induction Brazing of TC4 Titanium Alloy/316L Stainless Steel Joint[J]. 2023, 57(10): 153-162.
王宗科, 张贵锋, 张誉. TC4钛合金与316L不锈钢感应钎焊接头的组织与性能[J]. 西安交通大学学报, 2023,57(10):153-162. DOI: 10.7652/xjtuxb202310015.
Microstructure and Properties of Induction Brazing of TC4 Titanium Alloy/316L Stainless Steel Joint[J]. 2023, 57(10): 153-162. DOI: 10.7652/xjtuxb202310015.
为降低钛合金与不锈钢钎焊的工艺成本与钎料成本
采用自主设计制备的Cu-Mn-Ni钎料
在低成本保护气氛氩气下对TC4钛合金与316L不锈钢进行感应钎焊
并从润湿性、接头显微组织与力学性能方面研究其可行性
揭示了界面反应的特征与机制。试验结果表明:钎料对TC4钛合金与316L不锈钢的润湿性优异
两侧接触角分别为8°、12°与6°、7°; 在钎焊温度为900和930 ℃下保温1 min后
接头处的显微组织为TC4/(α+β)Ti/βTi/(βTi+Ti
2
Cu)+Ti
2
Cu/FeTi/γFe/316L; 在钎焊温度为960 ℃下保温1 min后
显微组织为TC4/(α+β)Ti/βTi/βTi+(βTi+FeTi)/FeTi/γFe/316L; 随着钎焊温度升高
接头的抗剪强度先增大后减小
钎焊温度为930 ℃时
保温1 min后接头的抗剪强度达到最大值155 MPa; 断口分析表明316L不锈钢侧为接头的薄弱区域
断裂发生在FeTi扩散层与临近的Ti
2
Cu相内(900和930 ℃)
或更厚更硬的FeTi扩散层内(960 ℃)。
To reduce the cost of filler metals and the manufacturing process for brazing titanium alloy and stainless steel
a study was conducted on the induction brazing of TC4 titanium alloy and 316L stainless steel using Cu-Mn-Ni filler metal and low-cost argon protection. The feasibility of this approach was investigated based on wettability
joint microstructure
and mechanical properties
and the characteristics and mechanism of the interfacial reaction were examined. The results
show that the filler metal exhibited excellent wettability with the contact angles of 8°
12° and 6°
7° on the surfaces of TC4 titanium alloy and 316L stainless steel
respectively. The brazed joint's microstructure was observed to consist of TC4/(α+β)Ti/βTi/(βTi+Ti
2
Cu)+Ti
2
Cu/FeTi/γFe/316L after being brazing at a low temperature of 900°C and 930°C for one minute. At a higher temperature of 960°C for one minute
the microstructure was composed of TC4/(α+β)Ti/βTi/βTi+(βTi+FeTi)/FeTi/γFe/316L. With increasing brazing temperature
the shear strength of the joint initially increased and then decreased. The maximum shear strength of 155 MPa was obtained at 930 ℃ for 1 minute. Fracture analysis indicated that the 316L stainless steel side was the weak area of the joint
with fractures occurring between the FeTi diffusion layer and the adjacent Ti
2
Cu at 900 ℃ and 930 ℃
or within thicker and harder FeTi diffusion layer at 960 ℃.
李毅, 赵永庆, 曾卫东. 航空钛合金的应用及发展趋势 [J]. 材料导报, 2020, 34(z1): 280-282.LI Yi, ZHAO Yongqing, ZENG Weidong. Application and development of aerial titanium alloys [J]. Materials Reports, 2020, 34(z1): 280-282
赵永庆, 葛鹏, 辛社伟. 近五年钛合金材料研发进展 [J]. 中国材料进展, 2020, 39(7): 527-534.ZHAO Yongqing, GE Peng, XIN Shewei. Progresses of R&D on Ti-alloy materials in recent 5 years [J]. Materials China, 2020, 39(7): 527-534
LI Hongguang. Analysis of porosity in welding of titanium alloy [C]//2020 3rd International Conference on Electron Device and Mechanical Engineering(ICEDME). Piscataway, NJ, USA: IEEE, 2020: 486-489
ZHANG Wenjun, LIU Fenggang, LIU Lixin, et al. Effect of grain size and distribution on the corrosion behavior of Y2O3 dispersion-strengthened 304 stainless steel [J]. Materials Today Communications, 2022, 31: 103723
李帅, 夏月庆, 王星星, 等. 钛合金/钢异种材料熔化焊研究现状 [J]. 材料导报, 2022, 36(14): 184-190.LI Shuai, XIA Yueqing, WANG Xingxing, et al. Research status for the fusion welding between titanium alloy and steel [J]. Materials Reports, 2022, 36(14): 184-190
李继红, 谢威威, 杨军, 等. 钛/钢复合板熔化焊接头的组织和性能 [J]. 金属热处理, 2016, 41(5): 48-51, 52.LI Jihong, XIE Weiwei, YANG Jun, et al. Microstructure and properties of melting welded joint of Ti/steel composite plates [J]. Heat Treatment of Metals, 2016, 41(5): 48-51, 52
刘阳, 张贵锋, 王士元. 钛合金与不锈钢异种金属钎焊的研究进展 [J]. 焊管, 2019, 42(3): 1-7.LIU Yang, ZHANG Guifeng, WANG Shiyuan. Research progress on dissimilar metal brazing of titanium alloy and stainless steel [J]. Welded Pipe and Tube, 2019, 42(3): 1-7
ZHANG Guifeng, SU Wei, ZHANG Jianxun, et al. Friction stir brazing: a novel process for fabricating Al/steel layered composite and for dissimilar joining of Al to steel [J]. Metallurgical and Materials Transactions A, 2011, 42(9): 2850-2861
罗海龙, 张敏, 褚巧玲, 等. T2-TA1搅拌摩擦钎焊接头显微组织及结合机理分析 [J]. 兵器材料科学与工程, 2019, 42(3): 12-16.LUO Hailong, ZHANG Min, CHU Qiaoling, et al. Microstructure and bonding mechanism of friction stir brazing T2-TA1 lap joint [J]. Ordnance Material Science and Engineering, 2019, 42(3): 12-16
YAO Yujie, HAN Yong, ZHANG Kaiyu, et al. The dependence of fracture mode on interfacial microstructure in TA1 pure titanium/AgCuNi/304 stainless steel vacuum brazed joints [J]. Vacuum, 2022, 203: 111318
夏月庆. Ti--Cu基钎料设计及钛合金/不锈钢真空钎焊机理研究 [D]. 大连: 大连理工大学, 2020
YANG Mei, WU Xin, GONG Xiufang, et al. Interfacial microstructure and mechanical properties of TC4 titanium alloy/316L stainless steel joint brazed with Ag70.5Cu27.5Ti2 filler metal [J]. Transactions of the Indian Institute of Metals, 2021, 74(8): 1907-1916
LEE J G, LEE M K. Microstructure and mechanical behavior of a titanium-to-stainless steel dissimilar joint brazed with Ag-Cu alloy filler and an Ag interlayer [J]. Materials Characterization, 2017, 129: 98-103
BAI Xueyin, LIU Minqian, PANG Shujie, et al. Novel Ti-Zr-Co-Cu-M(M = Sn, V, Al)amorphous/nanocrystalline brazing fillers for joining Ti-6Al-4V alloy [J]. Materials Characterization, 2023, 196: 112607
CAO Xu, DONG Kewei, ZHU Rui, et al. A high-strength vacuum brazed TC4/316L joint with a Ti-Zr-based amorphous ribbon as the filler metal [J]. Vacuum, 2021,187: 110070
XIA Yueqing, DONG Honggang, HAO Xiaohu, et al. Vacuum brazing of Ti6Al4V alloy to 316L stainless steel using a Ti-Cu-based amorphous filler metal [J]. Journal of Materials Processing Technology, 2019, 269: 35-44
朱瑞, 李国选, 汪月勇, 等. TC4钛合金-316L不锈钢真空钎焊接头组织与性能研究 [J]. 有色金属工程, 2021, 11(12): 8-14.ZHU Rui, LI Guoxuan, WANG Yueyong, et al. An investigation on microstructure and mechanical properties of vacuum brazed TC4 titanium to 316L stainless steel [J]. Nonferrous Metals Engineering, 2021, 11(12): 8-14
徐锦锋, 郭嘉宝, 田健, 等. 基于焊缝金属高熵化的钛/钢焊材设计与制备 [J]. 铸造技术, 2014, 35(11): 2674-2676.XU Jinfeng, GUO Jiabao, TIAN Jian, et al. Design and preparation of welding materials applied to welding titanium and steel based on weldmetal high entropy converting [J]. Foundry Technology, 2014, 35(11): 2674-2676
西安理工大学. 应用高熵效应焊接钛与钢的方法及焊接材料: CN201210143862.0 [P]. 2012-09-19
CHU Qiaoling, LI Yi, CAO Qilu, et al. Microstructure and mechanical properties of Ti/Cu/Fe dissimilar joints [J/OL]. Journal of Materials Engineering and Performance, 2022 [2022-12-20]. https://doi.org/10.1007/s11665-022-07445-5
JIANG Xin, ZHANG Guifeng, ZHANG Yu, et al. High temperature brazing of C/C using Hastelloy C-276 as filler and joint formation mechanism [J]. Composites Part A: Applied Science and Manufacturing, 2023, 168: 107487
唐仁政, 田荣璋. 二元合金相图及中间相晶体结构 [M]. 长沙: 中南大学出版社, 2009
VIGRAMAN T, RAVINDRAN D, NARAYANASAMY R. Effect of phase transformation and intermetallic compounds on the microstructure and tensile strength properties of diffusion-bonded joints between Ti-6Al-4V and AISI 304L [J]. Materials & Design(1980-2015), 2012, 36: 714-727
张启运, 庄鸿寿, 曲文卿, 等. 三元系合金相图集 [M]. 北京: 化学工业出版社, 2022
LI Zhumin, LI Xiaona, WANG Chenyu, et al. Comparative studies on microstructures and properties of Cu-Ni-M alloys controlled by strong interaction between elements [J]. Journal of Alloys and Compounds, 2019, 805: 404-414.
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