太阳能光催化分解水气泡动力学研究进展

郭烈锦; 曹振山; 王晔春; 张博; 冯雨杨; 徐强

doi:10.7652/xjtuxb202303001

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太阳能光催化分解水气泡动力学研究进展

专题新能源与储能 | 更新时间：2025-07-09

- 太阳能光催化分解水气泡动力学研究进展
- Review of Bubble Dynamics in Solar Photocatalytic Water Splitting
- 西安交通大学学报 2023年57卷第3期页码：1-22
- 作者机构：
  
  西安交通大学动力工程多相流国家重点实验室,西安,710049
- 作者简介：
  
  : 2022-08-23。作者简介: 郭烈锦(1963—),男,教授,博士生导师,中国科学院院士。基金项目: 国家自然科学基金资助项目(51888103)。
- 基金信息：
  
  : 2022-08-23。作者简介: 郭烈锦(1963—),男,教授,博士生导师,中国科学院院士。基金项目: 国家自然科学基金资助项目(51888103)。
- DOI：10.7652/xjtuxb202303001
  中图分类号： O359
- 网络首发：2023-03-10，
  
  纸质出版：2023
- 稿件说明：
移动端阅览
郭烈锦, 曹振山, 王晔春, 等. 太阳能光催化分解水气泡动力学研究进展[J]. 西安交通大学学报, 2023,57(3):1-22.

GUO Liejin, CAO Zhenshan, WANG Yechun, et al. Review of Bubble Dynamics in Solar Photocatalytic Water Splitting[J]. 2023, 57(3): 1-22.
郭烈锦, 曹振山, 王晔春, 等. 太阳能光催化分解水气泡动力学研究进展[J]. 西安交通大学学报, 2023,57(3):1-22. DOI： 10.7652/xjtuxb202303001.

GUO Liejin, CAO Zhenshan, WANG Yechun, et al. Review of Bubble Dynamics in Solar Photocatalytic Water Splitting[J]. 2023, 57(3): 1-22. DOI： 10.7652/xjtuxb202303001.

摘要

太阳能光催化分解水制氢中的气泡动力学

涉及多物理场和光催化反应之间的相互作用

相比传统的沸腾换热和电解水领域气泡动力学更加复杂且具有独特性。本文从光催化分解水基本原理出发

综述了催化剂表面气泡成核生长动力学规律及其行为调控的研究进展。对于光催化分解水的气泡成核尺度和过饱和度

可以通过经典成核理论估算

然而受现有测试方式的制约

尚无法同时获取高空间和高时间分辨率的成核过程信息。对于催化剂表面气泡的生长规律

通常可由惯性控制、扩散控制和化学反应控制3种机制进行描述

而决定气泡生长控制机制的关键是有效反应表面与气泡尺寸的相对大小。为了有效降低气泡覆盖对光催化反应系统带来的负面影响

可通过添加表面活性剂、调节催化剂表面结构和润湿性为主的被动调控方式

以及施加外部流场、声场、磁场和周期性光照为主的主动调控方式

对气泡行为进行定向调控加以实现。当前研究面临的主要挑战是揭示光催化分解水过程中复杂物理场作用下的相间作用和能质输运机理

从而为未来低成本、高效利用太阳能光催化分解水制氢应用提供指导。

Abstract

The bubble dynamics in solar photocatalytic hydrogen production involves the interaction between multiple physical fields and photocatalytic reactions

which is unique and more complicated than the classic bubble dynamics in the field of boiling heat exchange and water electrolysis. Based on the basic principle of photocatalytic water splitting

this paper reviews the research progress in the dynamics of bubble nucleation and growth on the catalyst surface and the regulation of bubble behavior. The scale and supersaturation of bubble nucleation for photocatalytic water splitting can be estimated by the classical nucleation theory

however

the information of bubble nucleation process with high spatial and temporal resolution cannot be obtained simultaneously yet due to the constraints of existing testing methods. For the bubble growth on the catalyst surface

it can usually be described by three mechanisms: inertia control

diffusion control and chemical reaction control

and the key to determine the bubble growth control mechanism is the relative size of the effective reaction surface to the bubble size. The negative impact of bubble coverage on the photocatalytic reaction system can be effectively reduced by directional regulation of bubble behavior

including passive regulation methods based on the addition of surfactants and modulation of catalyst surface structure and wettability

and active regulation methods based on the application of external flow field

acoustic field

magnetic field and periodic illumination. The primary challenges of current research are to reveal the mechanisms of interphase interactions and energy-mass transport under the action of complex physical fields

thereby providing guidance for future low-cost and efficient solar photocatalytic hydrogen production applications.

关键词

Keywords

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