西安交通大学环境工程系,西安,710049
网络首发:2020-03-10,
纸质出版:2020
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谢瑾琢, 刘红霞, 冯鑫鑫, 等. 氩等离子体技术降解玉米表面毒死蜱的研究[J]. 西安交通大学学报, 2020,54(3):113-118+178.
Degradation of Chlorpyrifos on Mai-e Surface by Argon Plasma[J]. 2020, 54(3): 113-118+178.
谢瑾琢, 刘红霞, 冯鑫鑫, 等. 氩等离子体技术降解玉米表面毒死蜱的研究[J]. 西安交通大学学报, 2020,54(3):113-118+178. DOI: 10.7652/xjtuxb202003014.
Degradation of Chlorpyrifos on Mai-e Surface by Argon Plasma[J]. 2020, 54(3): 113-118+178. DOI: 10.7652/xjtuxb202003014.
为克服传统农药降解方法效率低、能耗高、二次污染等问题
在自行设计的介质阻挡放电反应器中
以氩为放电气体、以玉米表面残留的有机磷农药毒死蜱为实验对象
改变放电功率、放电时间、放电间隙、毒死蜱初始质量浓度和氩气流量等放电参数
对毒死蜱降解效果及降解后玉米表面特征和营养成分进行了分析。实验结果表明:当毒死蜱初始质量浓度为20 mg/L时
在放电功率为35 W、放电时间为60 s、放电间隙为6 mm、氩气流量为0.25 L/min条件下
玉米表面毒死蜱降解率可达87%
达到农药残留量的国标要求。农药降解过程中
氩等离子体在玉米表面产生轻微刻蚀
同时促使玉米水分含量降低
有利于玉米储存。处理后玉米的重要营养成分维生素B
2
质量分数并无显著变化
淀粉的质量分数降低
脂肪酸的质量分数增加
但并不影响玉米品质和贮藏价值。因此
氩等离子体技术是一种高效、快速、安全、绿色无污染的农药残留降解技术
具有进一步工业化应用的潜力。
To overcome the shortcomings of the conventional methods for pesticides degradation
such as low efficiency
high energy consumption
and secondary pollution
a self-designed dielectric barrier discharge reactor was used to degrade pesticides on mai-e
and chlorpyrifos was chosen as the research object. The effects of chlorpyrifos degradation
as well as the surface characteristics and the nutrients of mai-e
after degradation were studied by changing the discharge parameters(discharge power
treatment time
discharge gap)
initial concentration of chlorpyrifos
and argon flux. The results showed that at discharge power of 35 W
treatment time of 60 s
discharge gap of 6 mm and argon flux of 0.25 L/min
87% of chlorpyrifos with initial concentration of 20 mg/L could be successfully degraded
which met the national standard about pesticide residues. In the process of pesticides degradation
argon plasma treatment attributed to slight etching on the surface of mai-e
which could reduce t
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