添加Ti0.9Zr0.1Mn1.5复合球磨对Ti9.6V86.4Fe4合金储氢性能的影响

罗翔 1; 郑坊平 1; 2; 王春涛 3; 杭州明 1; 葛红卫 1; 李寿权 1; 陈立新 1

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添加Ti_0.9Zr_0.1Mn_1.5复合球磨对Ti_9.6V_86.4Fe₄合金储氢性能的影响

氢能研究 | 更新时间：2025-12-08

- 添加Ti_0.9Zr_0.1Mn_1.5复合球磨对Ti_9.6V_86.4Fe₄合金储氢性能的影响
- Influence of Composite Ball-Milling with Ti_0.9Zr_0.1Mn_1.5 on Hydrogen Storage Properties of Ti_9.6V_86.4Fe₄ Alloy
- 西安交通大学学报 2007年41卷第12期页码：1491-1494+1502
- 作者机构：
  
  浙江大学材料科学与工程学系,杭州,310027
- 作者简介：
- 基金信息：
  
  : 2007-08-10. 作者简介: 罗翔(1984～),男,硕士生;陈立新(联系人),男,教授,博士生导师. 基金项目: 国家高技术研究发展计划资助项目(2006AA05Z144);国家重点基础研究发展计划资助项目(2007CB209700);浙江省重大科技专项资助项目(2006C11233)
- DOI：
  中图分类号： TG139.7
- 网络首发：2007-12-10，
  
  纸质出版：2007
- 稿件说明：
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罗翔 1, 郑坊平 1, 2, 等. 添加Ti_0.9Zr_0.1Mn_1.5复合球磨对Ti_9.6V_86.4Fe₄合金储氢性能的影响[J]. 西安交通大学学报, 2007,41(12):1491-1494+1502.

罗翔 1, 郑坊平 1, 2, et al. Influence of Composite Ball-Milling with Ti_0.9Zr_0.1Mn_1.5 on Hydrogen Storage Properties of Ti_9.6V_86.4Fe₄ Alloy[J]. 2007, 41(12): 1491-1494+1502.
罗翔 1, 郑坊平 1, 2, 等. 添加Ti_0.9Zr_0.1Mn_1.5复合球磨对Ti_9.6V_86.4Fe₄合金储氢性能的影响[J]. 西安交通大学学报, 2007,41(12):1491-1494+1502. DOI：

罗翔 1, 郑坊平 1, 2, et al. Influence of Composite Ball-Milling with Ti_0.9Zr_0.1Mn_1.5 on Hydrogen Storage Properties of Ti_9.6V_86.4Fe₄ Alloy[J]. 2007, 41(12): 1491-1494+1502. DOI：

摘要

系统研究了Ti

9.6

86.4

储氢合金中掺入10%(质量分数)的Ti

0.9

0.1

1.5

进行复合球磨对其相结构及储氢性能的影响.X射线衍射分析表明

9.6

86.4

铸态合金具有单一的体心立方(BCC)结构固溶体相

当添加10%的Ti

0.9

0.1

1.5

复合球磨后

复合物由BCC主相和C14型Laves第2相组成.扫描电子显微镜及X射线能量色散谱仪分析表明

9.6

86.4

合金粉颗粒表面包覆了一层Ti

0.9

0.1

1.5

微粒.储氢性能测试表明

9.6

86.4

中掺入10%的 Ti

0.9

0.1

1.5

复合球磨后

虽然室温最大吸氢量(质量分数)从3.86%略微降低至3.61%

但其有效储氢量(质量分数)由2.01%提高到2.11%

活化性能和P-C-T曲线平台特性都得到了明显改善.

Abstract

The influence of composite ball-milling with 10%(mass fraction)T

i0.9

Zr0.1Mn

1.5

on the phase structure and hydrogen storage properties of Ti

9.6

86.4

alloy were investigated. X-ray diffraction analysis shows that the

as-cast Ti

9.6

86.4

alloy consists of single solid solution phase with body-centered cubic(BCC)structure

and the ball-milled composite(Ti

9.6

86.4

+10% Ti

0.9

0.1

1.5

)has a C14 type Laves secondary phase besides the BCC main phase. Scanning electron microscopy and energy dispersive X-ray spectrometer analysis show that there is a layer of Ti

0.9

0.1

1.5

particles on the surface of the composite alloy. Compared with the as-cast Ti

9.6

86.4

alloy

the effective hydrogen storage capacity of the ball-milled composite at room temperature increases from 2.01% to 2.11%

the activation behavior and P-C-T plateau characteristics are also improved

while the maximum hydrogen absorption capacity decreases from 3.86% to 3.61%.

关键词

Keywords

references

胡子龙. 储氢材料[M]. 北京:化学工业出版社, 2002: 394-442.

大角泰章. 金属氢化物的性质与应用[M]. 吴永宽,苗艳秋,译.北京:化学工业出版社, 1990: 215-240.

Lynch J F, Maeland A J, Libowitz G G. Lattice parameter variation and thermodynamics of dihydride formation in the vanadium-rich V-Ti-Fe/H2 system[J]. Zeitschrift fur Physikalische Chemic, 1985, 145: 51-59.

Nomura K, Akiba E. H2 absorbing-desorbing characterization of the Ti-V-Fe alloy system [J]. J Alloys and Compounds, 1995, 231(1/2): 513-517.

Park J G, Kim D M, Jang K J, et al. The intrinsic degradation behavior of(V0.53Ti0.47)0.925Fe0.075 alloy during temperature-induced hydrogen absorption-desorption cycling [J]. J Alloys and Compounds, 1999, 293/295: 150-155.

郑坊平,郑传祥,王新华,等.(Ti0.1V0.9)100-xFex(x=0～6)储氢合金的微观结构及储氢特性[J]. 稀有金属材料与工程,2006,35(9): 1371-1374.

Zheng Fangping, Zheng Chuanxiang, Wang Xinhua, et al. Microstructures and hydrogen storage characteristics of(Ti0.1V0.9)100-xFex(x=0～6)alloys [J]. Rare Metal Materials and Engineering, 2006,35(9): 1371-1374.

Okada M, Kuriiwa T, Kamegawa A, et al. Role of intermetallics in hydrogen storage materials [J]. Materials Science and Engineering:A, 2002, 329/331: 305-312.

Akiba E, Iba H. Hydrogen absorption by Laves phase related BCC solid solution [J]. Intermetallics, 1998, 6(6): 461-470.

Wang Wei, Chen Changpin, Chen Lixin, et al. Change in structure and hydrogen storage properties of La2Mg16Ni alloy after modification by mechanical grinding in THF [J]. J Alloys and Compounds, 2002, 339(1/2): 175-179.

陈立新,郑传祥,郑坊平,等. 球磨改性处理对Ti0.9Zr0.1Mn1.5合金相结构及储氢性能的影响[J]. 稀有金属材料与工程, 2006, 35(8): 1268-1271.

Chen Lixin, Zheng Chuanxiang, Zheng Fangping, et al. Effect of ball-milling on the phase structure and hydrogen storage properties of Ti0.9Zr0.1Mn1.5alloy [J]. Rare Metal Materials and Engineering, 2006, 35(8): 1268-1271.

Yu X B, Wu Z, Xia B J, et al. Improvement of activation performance of the quenched Ti-V-based BCC phase alloys [J]. J Alloys and Compounds, 2005, 386(1/2): 258-260.

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