球磨改性处理对Ti9.6Cr11V75.4Fe4合金储氢性能的影响

杭州明 1; 郑坊平 2; 王春涛 3; 范修林 1; 李寿权 1; 陈长聘 1; 陈立新 1

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球磨改性处理对Ti_9.6Cr₁₁V_75.4Fe₄合金储氢性能的影响

氢能研究 | 更新时间：2025-12-08

- 球磨改性处理对Ti_9.6Cr₁₁V_75.4Fe₄合金储氢性能的影响
- Influence of Ball-Milling on Hydrogen Storage Properties of Ti_9.6V_75.4Cr₁₁Fe₄ Alloy
- 西安交通大学学报 2008年42卷第1期页码：114-118
- 作者机构：
  
  浙江大学材料科学与工程学系,杭州,310027
- 作者简介：
- 基金信息：
  
  : 2007-08-01. 作者简介: 杭州明(1980-),男,博士生;陈立新(联系人),男,教授,博士生导师. 基金项目: 国家高技术研究发展计划资助项目(2006AA05Z144);国家自然科学基金资助项目(50571089);浙江省重大科技专项资助项目(2006C11233)
- DOI：
  中图分类号： TG139.7
- 网络首发：2008-01-10，
  
  纸质出版：2008
- 稿件说明：
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杭州明 1, 郑坊平 2, 王春涛 3, 等. 球磨改性处理对Ti_9.6Cr₁₁V_75.4Fe₄合金储氢性能的影响[J]. 西安交通大学学报, 2008,42(1):114-118.

杭州明 1, 郑坊平 2, 王春涛 3, et al. Influence of Ball-Milling on Hydrogen Storage Properties of Ti_9.6V_75.4Cr₁₁Fe₄ Alloy[J]. 2008, 42(1): 114-118.
杭州明 1, 郑坊平 2, 王春涛 3, 等. 球磨改性处理对Ti_9.6Cr₁₁V_75.4Fe₄合金储氢性能的影响[J]. 西安交通大学学报, 2008,42(1):114-118. DOI：

杭州明 1, 郑坊平 2, 王春涛 3, et al. Influence of Ball-Milling on Hydrogen Storage Properties of Ti_9.6V_75.4Cr₁₁Fe₄ Alloy[J]. 2008, 42(1): 114-118. DOI：

摘要

系统研究了机械球磨改性处理时间(t=0

8 h)对Ti

9.6

75.4

合金相结构和储氢性能的影响.XRD及扫描电镜分析表明

9.6

75.4

合金在球磨前后均为体心立方结构的固溶体单相

随着球磨时间的增加

合金的晶胞体积略微减小

合金颗粒逐渐细化并发生团聚.储氢性能测试表明

球磨改性处理能有效地改善合金的活化性能

随着球磨时间的增加

合金的室温可逆有效储氢量先增加后降低.其中

当球磨时间为2 h时

合金具有最佳的综合储氢性能

其室温最大吸氢量(质量分数)为3.7%

可逆有效储氢量(质量分数)为2.23%.

Abstract

The changes in phase structure and hydrogen storage properties of Ti

9.6

75.4

alloy after modification by ball-milling for different time(t=0

8 h)are systematically investigated. The XRD and SEM analyses show that all of the as-cast and ball-milled alloys consist of a single V-based solid solution phase with BCC structure. The cell volume and the particle size decrease gradually and the powder appears aggregation with the increasing ball-milling time. It is found that the ball-milling enables to improve the activation behavior of Ti

9.6

75.4

alloy effectively. With the increasing ball-milling time

the effective hydrogen storage capacity at room temperature increases first and then decreases. Ti

9.6

75.4

alloy ball-milled for 2 h is endowed with fine overall properties

whose maximum hydrogen absorption capacity and effective hydrogen storage capacity at room temperature approach to 3.7% and 2.23%

respectively.

关键词

Keywords

references

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WANG Wei, CHEN Changpin, CHEN Lixin, et al. Change in structure and hydrogen storage properties of La2Mg16Ni alloy after modification by mechanical grinding in THF [J]. J of Alloys and Compounds, 2002, 339: 175-179.

任国新,陈长聘,陈立新,等.在四氢呋喃中球磨改性处理的LaMg11Ni吸放氢特性研究[J].稀有金属材料与工程,2004, 33(9): 988-991.

REN Guoxin, CHEN Changpin, CHEN Lixin, et al. Hydriding/dehydriding behaviour of LaMg11Ni alloy modified by mechanical grinding in tetrahydrofuran [J]. Rare Metal Materials and Engineering, 2004, 33(9): 988-991.

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