变负荷条件下的大型合成氨装置特性研究

余云松 1; 朱建立 2; 3; 李青 1; 李云 2; 莫沅 3; 张早校 1

您当前的位置：

首页 >

文章列表页 >

变负荷条件下的大型合成氨装置特性研究

更新时间：2025-07-09

- 变负荷条件下的大型合成氨装置特性研究
- Characteristics of Large-Scale Synthesis Ammonia Plant under Varying Load Conditions
- 西安交通大学学报 2009年43卷第10期页码：114-118+123
- 作者机构：
  
  西安交通大学动力工程多相流国家重点实验室,西安,710049
- 作者简介：
- 基金信息：
  
  : 2009-04-02. 作者简介: 余云松(1984-),男,博士生;张早校(联系人),男,教授,博士生导师. 基金项目: “985工程”能源科学技术创新平台节能技术子平台资助项目
- DOI：
  中图分类号： TQ021.8
- 网络首发：2009-10-10，
  
  纸质出版：2009
- 稿件说明：
移动端阅览
余云松 1, 朱建立 2, 3, 等. 变负荷条件下的大型合成氨装置特性研究[J]. 西安交通大学学报, 2009,43(10):114-118+123.

Characteristics of Large-Scale Synthesis Ammonia Plant under Varying Load Conditions[J]. 2009, 43(10): 114-118+123.
余云松 1, 朱建立 2, 3, 等. 变负荷条件下的大型合成氨装置特性研究[J]. 西安交通大学学报, 2009,43(10):114-118+123. DOI：

Characteristics of Large-Scale Synthesis Ammonia Plant under Varying Load Conditions[J]. 2009, 43(10): 114-118+123. DOI：

摘要

为了探讨变负荷条件对合成氨过程的影响

结合某大型合成氨装置的流程和运行参数

利用ASPEN PLUS模拟整个合成氨过程

分析了在常用的部分负荷下整个合成氨装置的运行性能

获得了在部分负荷下加热炉、一段炉、辅锅等关键设备的热效率、火用效率以及反应器的反应转化率

提出了可以通过减少加热炉和一段炉的引风量和增加一段炉对流段蒸汽过热盘管面积来有效利用能量.采用Newton插值多项式的拟合方法

拟合出产量为1 000～1 500 t/d的大型合成氨装置在常见85%～100%负荷范围内的吨氨能耗与负荷间的三次拟合曲线和公式

得出该合成氨装置的吨氨能耗模拟值为36.707～40.797 GJ/t

和实测值吻合较好

误差小于3%.研究结果为实际的合成氨装置在变负荷下的生产运行与操作优化提供了参考依据.

Abstract

To investigate the effect of varying load on the synthesis ammonia

the process of a large-scale ammonia synthesis plant is simulated with the process and operational parameters of the petrochemical company by ASPEN PLUS

and the operational characteristics on varying load conditions from 85% to 100% are analyzed. Thermal efficiency and exergy efficiency of the key equipment

such as heating-furnace

primary reformer and auxiliary boiler are evaluated

and reaction conversion ratio of the reactors is obtained. It is suggested that reducing the amount of input air to the heating-furnace and primary reformer and enlarging the area of the steam overheating coil in the convection part of the primary reformer can utilize energy efficiently. The curve and expression between energy consumption of the ammonia synthesis with load of 85% to 100% are fitted by Newton interpolation polynomial for synthesis ammonia output in the plant from 1 000 t/d to 1 500 t/d. Thus it is predicted that energy consumption of the synthesis ammonia approaches 36.707 GJ/t to 40.797 GJ/t

which agree well with the field data with a deviation less than 3%.

关键词

Keywords

references

蒋德军. 合成氨工艺技术的现状及其发展趋势[J]. 现代化工,2005,25(8):9-16.

JIANG Dejun. Present situation and development of technology for ammonia synthetic process [J]. Modern Chemical Industry, 2005,25(8):9-16.

李青,余云松,姜钧,等.一种改进的二氧化碳吸收减排法研究[J]. 西安交通大学学报,2008,42(11):1413-1417.

LI Qing, YU Yunsong, JIANG Jun, et al. Improved CO2 capture method by absorption[J]. Journal of Xi'an Jiaotong University, 2008,42(11):1413-1417.

KIROVA-YORDANOVA Z. Exergy analysis of industrial ammonia synthesis [J]. Energy, 2004, 29(8): 2373-2384.

XU Q C, LIN J D, FU X Z, et al. Effects of solvent stabilizer in the preparation of highly active potassium promoted Ru/MgO catalysts for ammonia synthesis [J]. Catalysis Communications, 2008,9(6): 1214-1218.

HAGEN S,BARFOD R, FEHRMANN R, et al. Ammonia synthesis with barium-promoted iron-cobalt alloys supported on carbon [J]. Journal of Catalysis, 2003, 214(8):327-335.

SKOGESTAD S. Control structure design for the ammonia synthesis process [J]. Computer and Chemical Engineering, 2008, 32(12):2920-2932.

陈志奎,武宝琛.合成氨(油头)甲醇洗流程模拟——Aspen Plus应用范例[J].化学工程,1999,27(3):52-55.

CHEN Zhikui, WU Baochen. Simulation of methanol washing process in ammonia synthesis-Aspen Plus application [J]. Chemical Engineering, 1999, 27(3):52-55.

陈实,袁令,高林.合成氨工艺系统的火用分析及节能研究[J].北京理工大学学报,2004,24(11): 1016-1019.

CHEN Shi, YUAN Ling, GAO Lin. Exergy analysis on texaco synthetic ammonia system[J]. Transactions of Beijing Institute of Technology, 2004,24(11): 1016-1019.

张杰卿.影响合成氨综合能耗主要因素的分析[J].大氮肥,2002,25(2):116-118.

ZHANG Jieqing. Analysis of the main factors affecting the comprehensive energy consumption of synthetic ammonia[J]. Large Scale Nitrogenous Fertilizer Industry,2002, 25(2):116-118.

袁红年. 宁夏石化合成氨装置节能改造方案分析[J]. 石油和化工节能, 2006(2):10-13.

YUAN Hongnian. Analysis on refinery project of equipment in ammonia synthesis system in Ningxia Petrochemical [J]. Petroleum and Chemical Energy Conservation, 2006(2):10-13.

蒋蓉. 论合成氨综合能耗的影响因素[J].化工技术经济,2002(2): 33-35.

JIANG Rong. Influential factors of general energy consumption in ammonia production [J]. Chemical Techno-Economics, 2002(2): 33-35.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

多工况下离心压气机叶轮-机匣一体联合设计优化

EBSILON软件在热电联产系统优化中的应用综述

电动车辆间接热系统快速除湿响应迟滞机理及优化控制策略

水蒸气掺混对氨裂解气旋流燃烧与排放特性的影响研究

结构-语义-残差协同的图像压缩框架：面向隐私保护与高保真重建