微型反应器中甲醇水蒸气重整制氢研究

王锋; 李隆键; 漆波; 崔文智; 辛明道; 陈清华; 邓联锋

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微型反应器中甲醇水蒸气重整制氢研究

氢能研究 | 更新时间：2025-12-08

- 微型反应器中甲醇水蒸气重整制氢研究
- Methanol Steam Reforming for Hydrogen Production in a Minireactor
- 西安交通大学学报 2008年42卷第4期页码：509-514
- 作者机构：
  
  重庆大学动力工程学院,重庆,400030
- 作者简介：
- 基金信息：
  
  : 2007-08-10. 作者简介:王锋(1977-),男,在职博士生,助教. 基金项目: 国家自然科学基金资助项目(50276073);重庆市自然科学基金资助项目(CSTC2006BB6221)
- DOI：
  中图分类号： TK16
- 网络首发：2008-04-10，
  
  纸质出版：2008
- 稿件说明：
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王锋, 李隆键, 漆波, 等. 微型反应器中甲醇水蒸气重整制氢研究[J]. 西安交通大学学报, 2008,42(4):509-514.

王锋, 李隆键, 漆波, et al. Methanol Steam Reforming for Hydrogen Production in a Minireactor[J]. 2008, 42(4): 509-514.
王锋, 李隆键, 漆波, 等. 微型反应器中甲醇水蒸气重整制氢研究[J]. 西安交通大学学报, 2008,42(4):509-514. DOI：

王锋, 李隆键, 漆波, et al. Methanol Steam Reforming for Hydrogen Production in a Minireactor[J]. 2008, 42(4): 509-514. DOI：

摘要

为了强化甲醇水蒸气重整制氢过程

研制了一种集燃料预热、汽化、过热和重整反应功能于一体的微型反应器.实验考察了反应温度、水醇摩尔比、液体空速等对甲醇转化率、产氢率、反应器出口氢气和一氧化碳浓度的影响

建立了该反应器的数学和动力学模型并进行了三维数值模拟.结果表明

所建模型能较好地反映出反应器的性能

当反应温度、水醇摩尔比和液体空速分别为260 ℃、1.3、0.2 h

-1

时

产氢率达0.2 mol/(h·g)

可为氢气利用率为80%、效率为60%的燃料电池提供10.2 W的功率.

Abstract

In order to intensify the process of methanol steam reforming for hydrogen production

a minireactor is designed and fabricated. The reactor includes the functions of preheating

evaporation

superheating and reaction. The effects of temperature

water and methanol molar ratio

liquid space velocity on the reactor outlet parameters such as methanol conversion are studied through experiments. A 3-D model is established for the reactor as to describe the performance of the reactor. Results show that when the reaction temperature is 260 ℃

water and methanol molar ratio is 1.3

liquid space velocity is 0.2 h

-1

the yield of hydrogen reaches 0.2 mol/(h·g). This yield can provide the hydrogen for 10.2 W fuel cell with the hydrogen utility efficiency of 80% and cell efficiency of 60%.

关键词

Keywords

references

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