喷涂条件与热处理对La0.5Sr0.5CoO3-δ涂层含氧量的影响

高敏; 李长久; 李成新; 范圣强

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喷涂条件与热处理对La_0.5Sr_0.5CoO_3-δ涂层含氧量的影响

更新时间：2025-05-01

- 喷涂条件与热处理对La_0.5Sr_0.5CoO_3-δ涂层含氧量的影响
- Effects of Spray Condition and Annealing Treatment on Oxygen Contents of Thermally Sprayed La_0.5Sr_0.5CoO_3-δCoatings
- 西安交通大学学报 2010年44卷第3期页码：115-119
- 作者机构：
  
  西安交通大学材料科学与工程学院,西安,710049
- 作者简介：
- 基金信息：
  
  : 2009-09-03. 作者简介: 高敏(1968-),女,博士生,讲师;李长久(联系人),男,教授,博士生导师. 基金项目: 国家高技术研究发展计划资助项目(2007AA05Z135)
- DOI：
  中图分类号： O655.23
- 网络首发：2010-03-10，
  
  纸质出版：2010
- 稿件说明：
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高敏, 李长久, 李成新, 等. 喷涂条件与热处理对La_0.5Sr_0.5CoO_3-δ涂层含氧量的影响[J]. 西安交通大学学报, 2010,44(3):115-119.

Effects of Spray Condition and Annealing Treatment on Oxygen Contents of Thermally Sprayed La_0.5Sr_0.5CoO_3-δCoatings[J]. 2010, 44(3): 115-119.
高敏, 李长久, 李成新, 等. 喷涂条件与热处理对La_0.5Sr_0.5CoO_3-δ涂层含氧量的影响[J]. 西安交通大学学报, 2010,44(3):115-119. DOI：

Effects of Spray Condition and Annealing Treatment on Oxygen Contents of Thermally Sprayed La_0.5Sr_0.5CoO_3-δCoatings[J]. 2010, 44(3): 115-119. DOI：

摘要

采用火焰喷涂与等离子喷涂方法制备了La

0.5

CoO

3-δ

涂层

并在1 000 ℃热处理3 h

用碘滴定法测定了涂层热处理前、后的含氧量

研究了喷涂方法、制备条件及热处理对该阴极涂层含氧量的影响.结果表明:受喷涂过程中高温加热过程的影响

原始涂层存在大量的氧空位

含氧量较低; 等离子喷涂层的氧损失量显著高于火焰喷涂层.经热处理后

缺失的氧得到一定程度的回复

涂层含氧量增加.较高的氧空位浓度使喷涂态La

0.5

CoO

3-δ

涂层发生晶格畸变

从而使其发生从钙钛矿结构的立方晶向四方晶的转变

而热处理引起的氧回复则可使结构回复至立方晶.

Abstract

1-x

CoO

3-δ

(LSCO)is a promising cathode material for solid oxide fuel cells(SOFCs). The properties of the LSCO cathode are significantly influenced by its oxygen content. In this paper

0.5

CoO

3-δ

coatings are prepared by both flame spraying and plasma spraying. Annealing treatment of the LSCO coatings is performed at 1 000 ℃ for 3 hours. Oxygen contents of different samples are investigated by iodine titration. The effects of spray condition and annealing treatment on the oxygen content of the La

0.5

CoO

3-δ

are investigated. The results show that oxygen contents in the as-sprayed coatings get significantly lower than tha

t in the starting powder owing to heating to a high temperature of spray particles by high temperature flame. The escaped oxygen of plasma-sprayed La

0.5

CoO

3-δ

is more than that of flame-sprayed one. The oxygen content significantly increases after annealing treatment. It is clear that the deficit oxygen can be recovered through annealing treatment. The lattice distortion occurs in the thermally sprayed coatings due to large concentration of oxygen vacancies

which induces tetragonal phase formation. It is also found that recovery of oxygen through annealing treatment leads to a recovery phase transformation from tetragonal phase to perovskite cubic phase.

关键词

Keywords

references

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