维度调控对铁酸铋压电催化活性与过氧化氢产率的影响研究

彭亚雯; 杨龙; 兰申玉; 延卫

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维度调控对铁酸铋压电催化活性与过氧化氢产率的影响研究

更新时间：2025-11-18

- 维度调控对铁酸铋压电催化活性与过氧化氢产率的影响研究
- Study of Effect of Dimension Regulation on Bismuth Ferrite Piezocatalytic Activity and Hydrogen Peroxide Yield
- 默认刊物名称 2025年
- 作者机构：
  
  西安交通大学能源与动力工程学院环境科学与工程系,陕西省西安市710049
- 作者简介：
  
  彭亚雯(2001—)，女，博士生
- 基金信息：
  
  国家自然科学基金资助项目(52474443)
- DOI：
  中图分类号： X12;TQ421.1
- 收稿：2025-05-21，
  
  修回：2025-07-11，
  
  录用：2025-07-21，
- 稿件说明：
移动端阅览
彭亚雯, 杨龙, 兰申玉, 等. 维度调控对铁酸铋压电催化活性与过氧化氢产率的影响研究[J/OL]. 默认刊物名称, 2025.

PENG Yawen, YANG Long, LAN Shenyu, et al. Study of Effect of Dimension Regulation on Bismuth Ferrite Piezocatalytic Activity and Hydrogen Peroxide Yield[J/OL]. Moren Journal, 2025.
彭亚雯, 杨龙, 兰申玉, 等. 维度调控对铁酸铋压电催化活性与过氧化氢产率的影响研究[J/OL]. 默认刊物名称, 2025. DOI：

PENG Yawen, YANG Long, LAN Shenyu, et al. Study of Effect of Dimension Regulation on Bismuth Ferrite Piezocatalytic Activity and Hydrogen Peroxide Yield[J/OL]. Moren Journal, 2025. DOI：

摘要

为了阐明压电催化剂维度对压电催化性能的影响，本文利用水热法分别合成了一维线状和二维片状铁酸铋（BiFeO

）压电材料，并系统研究了BiFeO

在低频超声振动下压电催化原位产H

的性能和机制。研究发现：线状BiFeO

的H

产率为2553.5 μmol·g

-1

·h

-1

，高于片状BiFeO

的2078.9 μmol·g

-1

·h

-1

，表明形貌对压电催化性能具有显著影响；相对于二维片状，一维线状BiFeO

在外力作用下更易形变弯曲，从而产生更强的压电响应、更高的压电电势、更低的界面电阻及更大的压电电流；·OH、·O

−

、电子和空穴在H

生成过程中均起到重要作用，线状BiFeO

压电催化原位产生H

同时来源于水氧化和氧还原路径。研究通过“材料结构设计-催化性能测试-内在性质表征-反应机制探索”四维关联模型，为压电催化剂设计提供跨尺度优化策略，可为H

高效原位产生提供参考。

Abstract

To elucidate the effect of piezocatalyst dimension on piezocatalytic performance

1D line-like and 2D sheet-like bismuth ferrite (BiFeO

) piezocatalytic materials were synthesized via a hydrothermal method

their piezocatalytic performance and mechanism for in-situ H

production were investigated systematically under low-frequency ultrasonic vibration. The results demonstrated that line-like BiFeO

exhibited a superior H

production rate of 2553. 5 μmol·g

-1

·h

-1

compared to sheet-like BiFeO

at 2078.9 μmol·g

-1

·h

-1

indicating morphology-dependent enhancement of piezocatalytic activity. Compared to 2-D sheets

1-D line-like BiFeO

was more prone to deformation and bending under external forces

thereby generating stronger piezoelectric response

higher piezoelectric p

otential

lower interfacial resistance

and enhanced piezoelectric current. ·OH

·O₂⁻

electrons

and holes all play crucial roles in the H

generation process. The piezocatalytic in-situ production of H

by line-like BiFeO

originated from both water oxidation and oxygen reduction pathways. By establishing a four-dimensional correlation framework integrating material structure design

catalytic performance evaluation

intrinsic property characterization

and reaction mechanism exploration

this work proposes cross-scale optimization strategies for piezocatalyst engineering and provides reference for highly efficient in-situ H

production.

关键词

Keywords

references

HOU Huilin , ZENG Xiangkang , ZHANG Xiwang . Production of Hydrogen Peroxide by Photocatalytic Processes [J ] . Angewandte Chemie International Edition , 2020 , 59 ( 40 ): 17356 - 17376 .

邹黄磊 . 基于氮化碳材料的光催化产过氧化氢及其应用 [D ] . 南京 : 南京邮电大学 , 2022 : 1 - 2 .

游贤德 . 双氧水在造纸工业中的应用 [J ] . 造纸化学品 , 2000 ( 3 ): 31 - 34 .

YOU Dexian . Application of hydrogen peroxid in paper industry [J ] . Paper Chemicals , 2000 ( 3 ): 31 - 34 .

ZHAO Qian , AN Jingkun , WANG Xin , et al . In-situ hydrogen peroxide synthesis with environmental applications in bioelectrochemical systems: A state-of-the-art review [J ] . International Journal of Hydrogen Energy , 2021 , 46 ( 4 ): 3204 - 3219 .

ASGHAR A , ABDUL R A A , WANDAUD W M A . Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review [J ] . Journal of Cleaner Production , 2015 , 87 : 826 - 838 .

SANTOS D M F , SATURNINO P G , LOBO R F M , et al . Direct borohydride/peroxide fuel cells using Prussian Blue cathodes [J ] . Journal of Power Sources , 2012 , 208 : 131 - 137 .

中国石化有机原料科技情报中心站 . 大化所循环流化床双氧水制环氧氯丙烷工艺通过评价 [J ] . 石油化工技术与经济 , 2024 , 40 ( 2 ): 44 .

China Petrochemical Corporation Organic Raw Materials Science and Technology Information Center . The circulating fluidized bed hydrogen peroxide-to-epichlorohydrin process developed by the Dalian Institute of Chemical Physics (DICP) has passed technical evaluation [J ] . Technology & Economics in Petrochemicals ， 2024 , 40 ( 2 ): 44 .

LIU Wei , WANG Peifang , CHEN Juan , et al . Unraveling the mechanism on ultrahigh efficiency photocatalytic H 2 O 2 generation for Dual‐Heteroatom incorporated polymeric carbon nitride [J ] . Advanced Functional Materials , 2022 , 32 ( 38 ): e2205119 .

ZHANG Qichang , JIA Yanmin , WU Wenwen , et al . Review on strategies toward efficient piezocatalysis of BaTiO 3 nanomaterials for wastewater treatment through harvesting vibration energy [J ] . Nano Energy , 2023 , 113 : e108507 .

WANG Chunyang , HU Cheng , CHEN Fang , et al . Polar layered bismuth‐rich oxyhalide piezoelectrics Bi 4 O 5 X 2 (X=Br, I): Efficient piezocatalytic pure water splitting and interlayer anion-dependent activity [J ] . Advanced Functional Materials , 2023 , 33 ( 29 ): e2301144 .

SHERRELL P C , FRONZI M , SHEPELIN N A , et al . A bright future for engineering piezoelectric 2D crystals [J ] . Chem Soc Rev , 2022 , 51 ( 2 ): 650 - 671 .

XU Jing ， FUJITSUKA M ， KIM S ， et al . Unprecedented effect of CO 2 calcination atmosphere on photocatalytic H 2 production activity from water using g-C 3 N 4 synthesized from triazole polymerization [J ] . Applied Catalysis B: Environmental ， 2019 ， 241 : 141 - 148 .

ZHOU Yuanyi , DONG Haojie , XU Zhaofen , et al . Carbon modification facilitates piezocatalytic H 2 O 2 production over BiOCl nanosheets: Correlation between piezoresponse and surface reaction [J ] . Applied Catalysis B: Environmental , 2024 , 343 : e123504 .

WANG Kai , SHU Zhu , ZHOU Jun , et al . Enhancing piezocatalytic H 2 O 2 production through morphology control of graphitic carbon nitride [J ] . Journal of Colloid and Interface Science , 2023 ， 648 : 242 - 250 .

CAI Kuan ， HUANG Huancheng ， XU Yanhao ， et al . Reversible heterostructure CuI/CuII@BaTiO 3 constructed to enhance piezocatalytic activity [J ] . Nano Energy , 2024 , 130 : e110090 .

WANG Kai , ZHANG Manqi , LI Degang , et al . Ternary BaCaZrTi perovskite oxide piezocatalysts dancing for efficient hydrogen peroxide generation [J ] . Nano Energy , 2022 , 98 : e107251 .

JIA Pengwei , LI Jianming , HUANG Hongwei . Piezocatalysts and piezo-photocatalysts: From material design to diverse applications [J ] . Advanced functional materials , 2024 , 34 ( 44 ): e2407309 .

WANG Chunyang , HU Cheng , CHEN Fang , et al . Design strategies and effect comparisons toward efficient piezocatalytic system [J ] . Nano Energy , 2023 , 107 : e108093 .

WU Jiang , QIN Ni , BAO Dinghua . Effective enhancement of piezocatalytic activity of BaTiO 3 nanowires under ultrasonic vibration [J ] . Nano Energy , 2018 , 45 : 44 - 51 .

ZHAO T , SCHOLL A , ZAVALICHE F , et al . Electrical control of antiferromagnetic domains in multiferroic BiFeO 3 films at room temperature [J ] . Nature Materials , 2006 , 5 ( 10 ): 823 - 829 .

TEAN V , CHEN D . Ag 2 O@BiFeO 3 heterostructure composite coupling built-in electric field with piezopotential for enhanced photocatalytic pollutant degradation and photoelectrochemical water splitting [J ] . Applied Surface Science , 2023 , 625 : e157175 .

HE Jie , WANG Xuandong , LAN Shenyu , et al . Breaking the intrinsic activity barriers of perovskite oxides photocatalysts for catalytic CO 2 reduction via piezoelectric polarization [J ] . Applied Catalysis B: Environmental , 2022 , 317 : e121747 .

TU Shuchen , GUO Yuxi , ZHANG Yihe , et al . Piezocatalysis and piezo‐photocatalysis: catalysts classification and modification strategy, reaction mechanism, and practical application [J ] . Advanced Functional Materials , 2020 , 30 ( 48 ): e2005158 .

刘思宇 . 离子掺杂BiFeO 3 基材料的制备与性能研究 [D ] . 上海 : 上海应用技术大学 , 2019 : 28 .

WEN Yingying , CHEN Juan , GAO Xin Gao , et al . Two birds with one stone: Cobalt-doping induces to enhanced piezoelectric property and persulfate activation ability of ZnO nanorods for efficient water purification [J ] . Nano energy , 2023 , 107 : e108173 .

WEN Yingying , LIU Wei , WANG Peifang , et al . Interface Interaction Enhanced Piezo-catalytic hydrogen peroxide generation via one-electron water oxidation [J ] . Advanced Functional Materials , 2023 , 33 : e 2308084 .

WEI Yan , ZHANG Yiwen , GENG Wei , et al . Efficient bifunctional piezocatalysis of Au/BiVO 4 for simultaneous removal of 4-chlorophenol and Cr (VI) in water [J ] . Applied Catalysis B: Environmental , 2019 , 259 : e118084 .

TIAN Wenrou , QIU Jiahao , LI Najun , et al . Efficient piezocatalytic removal of BPA and Cr (VI) with SnS 2 /CNFs membrane by harvesting vibration energy [J ] . Nano Energy , 2021 , 86 : e106036 .

BANOO M , ROY R S , BHAKARr M , et al . Bi 4 TaO 8 Cl as a new class of layered perovskite oxyhalide materials for piezopotential driven efficient seawater splitting [J ] . Nano Letters , 2022 , 22 ( 22 ): 8867 - 8874 .

WANG Shijie , ZHANG Haoqing , NIE Ran , et al . Effective modification of photocatalytic and piezocatalytic performances for poly (heptazine imide) by carbon dots decoration [J ] . Dalton Transactions , 2022 , 51 ( 34 ): 13015 - 13021 .

LI Yuekun , LI Li , LIU Fangyan , et al . Robust route to H 2 O 2 and H 2 via intermediate water splitting enabled by capitalizing on minimum vanadium-doped piezocatalysts [J ] . Nano Research , 2022 , 15 ( 9 ): 7986 - 7993 .

HE Yiwei , TIAN Na , AN Yue , et al . Morphology regulation and oxygen vacancy construction synergistically boosting t he piezocatalytic degradation and pure water splitting of SrTiO 3 [J ] . Small , 2024 , 20 ( 52 ): e2407624 .

RAN Maoxi , DU Bibai , LIU Wenyuan , et al . Dynamic defects boost in-situ H 2 O 2 piezocatalysis for water cleanup [J ] . Proceedings of the National Academy of Sciences , 2024 , 121 ( 9 ): e2317435121 .

CUI Yongfei , WANG Fenghui , YUAN Panpan , et al . Harvesting vibration energy to produce hydrogen peroxide with Bi 3 TiNbO 9 nanosheets through a water oxidation dominated Dual-Channel pathway [J ] . ACS Sustainable Chemistry & Engineering , 2024 , 12 ( 9 ): 3595 - 3607 .

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