Applications and Challenges of Alkali-Doped Anion Exchange Membranes in Alkaline Electrolyzers and Fuel Cells

SHI Le; WANG Yindong; HAN Haoqi

doi:10.7652/xjtuxb202606001

您当前的位置：

首页 >

文章列表页 >

Applications and Challenges of Alkali-Doped Anion Exchange Membranes in Alkaline Electrolyzers and Fuel Cells

Special Topic Electrochemical Materials | 更新时间：2026-06-12

- Applications and Challenges of Alkali-Doped Anion Exchange Membranes in Alkaline Electrolyzers and Fuel Cells
- Journal of Xi'an Jiaotong University Vol. 60, Issue 6, Pages: 1-18(2026)
- 作者机构：
  
  西安交通大学电气工程学院，710049，西安
  西安交通大学电工材料电气绝缘全国重点实验室，710049，西安
  西安交通大学新型储能与能量转换纳米材料研究中心，710049，西安
- 作者简介：
- 基金信息：
- DOI：10.7652/xjtuxb202606001
  CLC： TK91
- Received：14 September 2025，
  
  Published：10 June 2026
- 稿件说明：
移动端阅览
SHI Le, WANG Yindong, HAN Haoqi. Applications and Challenges of Alkali-Doped Anion Exchange Membranes in Alkaline Electrolyzers and Fuel Cells[J]. Journal of Xi'an Jiaotong University, 2026, 60(6): 1-18.
DOI：

SHI Le, WANG Yindong, HAN Haoqi. Applications and Challenges of Alkali-Doped Anion Exchange Membranes in Alkaline Electrolyzers and Fuel Cells[J]. Journal of Xi'an Jiaotong University, 2026, 60(6): 1-18. DOI： 10.7652/xjtuxb202606001.

摘要

阴离子交换膜（AEMs）作为阴离子交换膜电解槽（AEMWEs）与阴离子交换膜燃料电池（AEMFCs）的核心部件，普遍面临离子传导率有限、官能团易降解、碱性稳定性不足等问题，严重制约了相关电化学器件的长期稳定运行。近年来，碱掺杂型AEMs因其离子传导过程不依赖有机阳离子官能团，表现出优异的碱性稳定性和离子传导性能，成为该领域的研究热点。研究系统综述了聚苯并咪唑（PBI）、氧化石墨烯（GO）和层状双氢氧化物（LDH）等碱掺杂AEMs制备中常用材料的性能。在离子传导方面，指出PBI主要依赖有机氮位点对KOH的吸附，以及KOH诱导形成的亲水网络实现OH

传导，而GO与LDH则借助其表面官能团与KOH构建的亲水区域促进离子迁移，三者离子迁移机理均与Grotthuss机制相似。在性能优化方面，总结了运行温度、碱类型、碱负载量、碱浓度、碱浸泡时间以及离子传输通路等关键因素的影响，结果表明，碱掺杂型AEMs在8 mol/L的KOH溶液中浸泡6d能够达到最优的处理效果；通过设计合理的膜结构，能够增大碱负载量并优化离子传输通路，显著提升膜离子传导率。在应用层面，综述了碱掺杂型AEMs在AEMWEs与AEMFCs中的最新研究进展，并对其未来发展方向进行了展望。该研究可为碱掺杂型AEMs的开发制备提供参考。

Abstract

Anion exchange membranes（AEMs），as core components of anion exchange membrane water electrolyzers（AEMWEs）and anion exchange membrane fuel cells（AEMFCs），commonly suffer from limited ion conductivity，facile degradation of functional groups，insufficient alkaline stability，and more，which severely restrict the long-term stable operation of the related electrochemical devices. In recent years，the research on alkali-doped AEMs has become a hit because their ion conduction processes are not reliant on organic cationic functional groups and consequently exhibit enhanced alkaline stability and ionic conductivity.The properties of materials commonly used in the preparation of alkali-doped AEMs，including polybenzimidazole（PBI），graphene oxide（GO），and layered double hydroxides（LDH），are systematically reviewed. With respect to ion conduction，it is indicated that PBI primarily depends on adsorption of KOH at organic nitrogen sitesandonformationofa KOH-inducedhydrophilicnetworktoenable OH

conduction，whereas GO and LDH promote ion migration through hydrophilic regions formed by interactions between their surface functional groups and KOH；the ion migration mechanisms of all three materials are analogous to the Grotthuss mechanism.Regarding performance optimization，the influences of key parameters such as operating temperature，alkali species，alkali loading，alkali concen

tration，alkali-soaking duration，and ion transport pathways are summarized.It is demonstrated that，the immersion of alkali-doped AEMs in 8 mol/L of KOH for 6 days yields an optimal treatment effect.Moreover，by rational membrane structure design，alkali loading can be increased and ion transport pathways can be optimized，resulting in significant enhancement of membrane ionic conductivity.Recent research advances on the application of alkali-doped AEMs in AEMWEs and AEMFCs are reviewed，and future development directions are envisaged.This study is expected to provide a useful reference for the development and preparation of alkali-doped AEMs.

关键词

Keywords

references

YUAN Jiahai，KANG Jiangang，ZHAO Changhong，et al.Energy consumption and economic growth：evi dence from China at both aggregated and disaggregated levels[J].Energy Economics，2008，30（6）：3077-3094.

周睿.能源消耗、经济增长与CO 2 排放量：基于新兴经济体的实证研究[J ] .世界经济研究，2015（11）：118-126.

ZHOU Rui.Energy consumption，economic growth and CO 2 emission in the new emerging economy[J ] . World Economy Studies，2015（11）：118-126.

邹洋，王剑晓，戴璟，等.欧洲能源危机成因、影响与应对措施[J].电力系统自动化，2023，47（17）：1-13.

ZOU Yang，WANG Jianxiao，DAI Jing，et al.Causes，impacts and mitigation measures of European energy crisis[J].Automation of Electric Power Systems，2023，47（17）：1-13.

滕吉文，张永谦，阮小敏.发展可再生能源和新能源与必须深层次思考的几个科学问题：非化石能源发展的必由之路[J].地球物理学进展，2010，25（4）：1115-1152.

TENG Jiwen，ZHANG Yongqian，RUAN Xiaomin. Some important scientific problems for development of renewable and new energy：the only way for development of non-fossil energy[J].Progress in Geophysics，2010，25（4）：1115-1152.

苗安康，袁越，吴涵，等.“双碳”目标下绿色氢能技术发展现状与趋势研究[J].分布式能源，2021，6（4）：15-24.

MIAO Ankang，YUAN Yue，WU Han，et al.Research on development status and trend of green hydrogen energy technologies under targets of carbon peak and carbon neutrality[J].Distributed Energy，2021，6（4）：15-24.

中华人民共和国国家发展和改革委员会.国家发展改革委、国家能源局联合印发《氢能产业发展中长期规划（2021—2035年）》[EB/OL].（2022-03-23）[2025-05-21]. https：//www.ndrc.gov.cn/xxgk/jd/jd/202203/t20220323_1320045.html.

张启媛，王宏起，杨仲基，等.政策耦合协同路径对创新绩效的影响研究：以我国氢能产业为例[J].科学学研究，2026，44（3）：586-598.

ZHANG Qiyuan，WANG Hongqi，YANG Zhongji，et al. Research on the impact of policy coupling synergy paths on innovation performance：a case study of China’s hydrogen energy industry [J].Studies in Science of Science，2026，44（3）：586-598.

黄丽丽，宋碧桑，王鸿，等.氢电耦合的应用场景、发展现状与挑战分析[J].中国资源综合利用，2024，42（6）：129-133.

HUANG Lili，SONG Bisang，WANG Hong，et al. Analysis of application scenarios，development status，and challenges of hydrogen electric coupling[J].China Resources Comprehensive Utilization，2024，42（6）：129-133.

张盛，郑津洋，戴剑锋，等.可再生能源大规模制氢及储氢系统研究进展[J].太阳能学报，2024，45（1）：457-465.

ZHANG Sheng，ZHENG Jinyang，DAI Jianfeng，et al. Research progress on renewable energy system coupled with large-scale hydrogen production and storage[J]. Acta Energiae Solaris Sinica，2024，45（1）：457-465.

冯作全，刘晨荣，郭晨阳，等.离网型氢电耦合储能系统设计与仿真分析[J].能源工程，2024，44（4）：20-25.

FENG Zuoquan，LIU Chenrong，GUO Chenyang，et al.Design and simulation analysis of off-grid hydrogen-electric coupling energy storage system[J].Energy Engineering，2024，44（4）：20-25.

解蒙.Power-Gas-Power可再生能源氢电耦合系统核心工艺设计[J].电气应用，2024，43（10）：75-84.

XIE Meng.Core process design of power-gas-power renewable energy hydrogen electric coupling system[J]. Electrotechnical Application，2024，43（10）：75-84.

宋鹏飞，侯建国，王秀林.可再生能源氢储能与氢转化利用技术及发展模式分析[J].天然气化工（C1化学与化工），2022，47（3）：26-32.

SONG Pengfei，HOU Jianguo，WANG Xiulin.Analysis of hydrogen energy storage for renewables and hydrogen conversion technology and development model [J]. Natural Gas Chemical Industry，2022，47（3）：26-32.

童鑫，熊哲，高新宇，等.质子交换膜燃料电池研究现状及发展[J].硅酸盐通报，2022，41（9）：3243-3258.

TONG Xin，XIONG Zhe，GAO Xinyu，et al.Research status and development of proton exchange membrane fuel cell[J].Bulletin of the Chinese Ceramic Society，2022，41（9）：3243-3258.

贾双珠，李会勇，李长安，等.质子交换膜燃料电池关键材料的研究现状与进展[J].化工新型材料，2019，47（2）：6-10.

JIA Shuangzhu，LI Huiyong，LI Changan，et al.Research status and development of key material for proton exchange membrane fuel cells[J].New Chemical Materials，2019，47（2）：6-10.

LEI Huiyu，YANG Xiaohua，CHEN Zhangsen，et al. Multiscale understanding of anion exchange membrane fuel cells：mechanisms，electrocatalysts，polymers，and cell management[J].Advanced Materials，2025，37（8）：2410106.

ZHANG Fan，ZU Bingfeng，WANG Bowen，et al. Developing long-durability proton-exchange membrane fuel cells[J].Joule，2025，9（3）：101853.

GOHIL J M，DUTTA K.Structures and properties of polymers in ion exchange membranes for hydrogen generation by water electrolysis[J].Polymers for Advanced Technologies，2021，32（12）：4598-4615.

温昶，张博涵，王雅钦，等.高效质子交换膜电解水制氢技术研究进展[J].华中科技大学学报（自然科学版），2023，51（1）：111-122.

WEN Chang，ZHANG Bohan，WANG Yaqin，et al. Research progress of high efficiency proton exchange membrane water electrolysis technology [J].Journal of Huazhong University of Science and Technology（Natural Science Edition），2023，51（1）：111-122.

邢学奇，宋鹏翔，申爱景，等.电解水制氢用阴离子交换膜研究进展[J].储能科学与技术，2024，13（11）：3856-3870.

XING Xueqi，SONG Pengxiang，SHEN Aijing，et al. Recent progress of anion exchange membrane for hydrogen production via water electrolysis [J].Energy Storage Science and Technology，2024，13（11）：3856-3870.

QU Erli，HAO Xiaofeng，XIAO Min，et al.Proton exchange membranes for high temperature proton exchange membrane fuel cells：challenges and perspectives [J]. Journal of Power Sources，2022，533：231386.

YANG Yaxiong，LI Peng，ZHENG Xiaobo，et al. Anion-exchange membrane water electrolyzers and fuel cells[J].Chemical Society Reviews，2022，51（23）：9620-9693.

WOONG RYOO G，HWA PARK S，CHANG KWON K，et al.Towards high-performance and robust anion exchange membranes（AEMs）for water electrolysis：super-acid-catalyzed synthesis of AEMs [J].Journal of Energy Chemistry，2024，93：478-510.

HYUN J，KIM H T.Powering the hydrogen future：current status and challenges of anion exchange membrane fuel cells[J].Energy & Environmental Science，2023，16（12）：5633-5662.

李佳纯，韩晨光，胡超，等.电解水制氢以及氢燃料电池用聚电解质阴离子交换膜的研究进展[J].高分子通报，2024，37（9）：1210-1221.

LI Jiachun，HAN Chenguang，HU Chao，et al.Research progress of hydrogen production from water electrolysis of polyelectrolyte anion exchange mem brane and fuel cell [J]. Polymer Bulletin，2024，37（9）：1210-1221.

CHEN Nanjun，LEE Y M.Anion exchange polyelectrolytes for membranes and ionomers[J].Progress in Polymer Science，2021，113：101345.

MARX D，CHANDRA A，TUCKERMAN M E. Aqueous basic solutions：hydroxide solvation，structural diffusion，and comparison to the hydrated proton [J]. Chemical Reviews，2010，110（4）：2174-2216.

DONG Dengpan，ZHANG Weiwei，VAN DUIN A C T，et al.Grotthuss versus vehicular transport of hydroxide in anion-exchange membranes：insight from combined reactive and nonreactive molecular simulations [J].Journal of Physical Chemistry Letters，2018，9（4）：825-829.

PELTIER C R，YOU Wei，VOLCANJK D F，et al. Quaternary ammonium-functionalized polyethylene-based anion exchange membranes：balancing performance and stability[J].ACS Energy Letters，2023，8（5）：2365-2372.

崔福军，刘勇，张扬，等.柔性含醚季鏻侧链聚砜阴离子交换膜研究[J].膜科学与技术，2022，42（2）：16-24.

CUI Fujun，LIU Yong，ZHANG Yang，et al.Flexible ether bond quaternary phosphonium side chain based polysulfone anion exchange membrane[J].Membrane Science and Technology，2022，42（2）：16-24.

WANG Chenyi，TAO Zhengwang，ZHAO Xiaoyan，et al.Poly（aryl ether nitrile）s containing flexible sidechain-type quaternary phosphonium cations as anion exchange membranes [J]. Science China Materials，2020，63（4）：533-543.

SHERAZI T A，ZAHOOR S，RAZA R，et al.Guanidine functionalized radiation induced grafted anion-exchange membranes for solid alkaline fuel cells[J].International Journal of Hydrogen Energy，2015，40（1）：786-796.

邸慧双，崔珺，可春钰，等.Guanidine分子在燃料电池用阴离子交换膜中的应用[J].高分子材料科学与工程，2017，33（7）：172-178.

DI Huishuang，CUI Jun，KE Chunyu，et al.Application of guanidine molecules in anion exchange membrane for fuel cell [J].Polymer Materials Science &Engineering，2017，33（7）：172-178.

ZHANG Feng，HE Xiaohui，CHENG Changwen，et al. Bis-imidazolium functionalized self-crosslinking block polynorbornene anion exchange membrane [J]. International Journal of Hydrogen Energy，2020，45（23）：13090-13100.

袁文森，李杏杏，祝缓缓，等.基于双核咪唑盐阴离子交换膜的制备与表征[J].高分子材料科学与工程，2019，35（1）：35-40.

YUAN Wensen，LI Xingxing，ZHU Huanhuan，et al. Synthesis and characterization of anion exchange membrane based on binuclearimidazolium salt[J].Polymer Materials Science & Engineering，2019，35（1）：35-40.

GOTTESFELD S，DEKEL D R，PAGE M，et al. Anion exchange membrane fuel cells：current status and remaining challenges [J]. Journal of Power Sources，2018，375：170-184.

HU Xu，HU Bin，NIU Chengyuan，et al.An operationally broadened alkaline water electrolyser enabled by highly stable poly（oxindole biphenylene）ion-solvating membranes [J].Nature Energy，2024，9（4）：401-410.

KRAGLUND M R，CARMO M，SCHILLER G，et al.Ion-solvating membranes as a new approach towards high rate alkaline electrolyzers [J].Energy &Environmental Science，2019，12（11）：3313-3318.

HENKENSMEIER D，CHO W C，JANNASCH P，et al.Separators and membranes for advanced alkaline water electrolysis[J].Chemical Reviews，2024，124（10）：6393-6443.

VOGEL H，MARVEL C S.Polybenzimidazoles，new thermally stable polymers [J].Journal of Polymer Science，1961，50（154）：511-539.

ARAYA S S，ZHOU Fan，LISO V，et al.A comprehensive review of PBI-based high temperature PEM fuel cells[J].International Journal of Hydrogen Energy，2016，41（46）：21310-21344.

WU Q X，PAN Z F，AN L.Recent advances in alkalidoped polybenzimidazole membranes for fuel cell applications[J].Renewable and Sustainable Energy Reviews，2018，89：168-183.

XING B，SAVADOGO O.Hydrogen/oxygen polymer electrolyte membrane fuel cells（PEMFCs）based on alkaline-doped polybenzimidazole（PBI）[J].Electrochemistry Communications，2000，2（10）：697-702.

HOU Hongying，SUN Gongquan，HE Ronghuan，et al.Alkali doped polybenzimidazole membrane for high performance alkaline direct ethanol fuel cell[J].Journal of Power Sources，2008，182（1）：95-99.

ZENG L，ZHAO T S，AN L，et al.Physicochemical properties of alkaline doped polybenzimidazole membranes for anion exchange membrane fuel cells [J]. Journal of Membrane Science，2015，493：340-348.

HOU Hongying，WANG Suli，JIANG Qian，et al. Durability study of KOH doped polybenzimidazole membrane for air-breathing alkaline direct ethanol fuel cell [J].Journal of Power Sources，2011，196（6）：3244-3248.

GUPTA A，SAKTHIVEL T，SEAL S.Recent development in 2D materials beyond graphene[J].Progress in Materials Science，2015，73：44-126.

SUN Pengzhan，MA Renzhi，SASAKI T.Recent progress on exploring exceptionally high and anisotropic H + /OH - ion conductionin two-dimensional materials[J ] . Chemical Science，2018，9（1）：33-43.

GEORGAKILAS V，TIWARI J N，KEMP K C，et al.Noncovalent functionalization of graphene and graphene oxide for energy materials，biosensing，catalytic，and biomedical applications [J].Chemical Reviews，2016，116（9）：5464-5519.

NAUMAN JAVED R M，AL-OTHMAN A，TAWALBEH M，et al.Recent developments in graphene and graphene oxide materials for polymer electrolyte membrane fuel cells applications[J].Renewable and Sustainable Energy Reviews，2022，168：112836.

ZHANG Lei，LIU Zhuo，YANG Chenxing，et al. Conduction mechanism in graphene oxide membranes with varied water content：from proton hopping dominant to ion diffusion dominant[J].ACS Nano，2022，16（9）：13771-13782.

FUKUDA M，ISLAMM S，SHUDO Y，et al.Ion conduction switching between H + and OH - induced by pH in graphene oxide[J ] .Chemical Communications，2020，56（31）：4364-4367.

BAYER T，CUNNING B V，SELYANCHYN R，et al. Alkaline anion exchange membranes based on KOH-treated multilayer graphene oxide [J].Journal of Membrane Science，2016，508：51-61.

SUN Pengzhan，CHEN Fashen，ZHOU Wei，et al. Superionic conduction along ordered hydroxyl networks in molecular-thin nanosheets [J]. Materials Horizons，2019，6（10）：2087-2093.

SUN Pengzhan，MA Renzhi，BAI Xueyin，et al.Singlelayer nanosheets with exceptionally high and anisotropic hydroxyl ion conductivity [J]. Science Advances，2017，3（4）：e1602629.

SHI Le，YING Zhixuan，XU Ao，et al.Unraveling the hydroxide ion transportation mechanism along the surface of two-dimensional layered double hydroxide nanosheets [J].The Journal of Physical Chemistry：C，2021，125（2）：1240-1248.

JHENG L C，HSU S L C，LIN Biyun，et al.Quaternized polybenzimidazoles with imidazolium cation moieties for anion exchange membrane fuel cells[J].Journal of Membrane Science，2014，460：160-170.

WANG Yindong，YING Zhixuan，LIU Meijuan，et al. High-temperatureinorganic anion exchange membranes based on layered double hydroxides for anion exchange membrane fuel cell applications[J].Journal of Membrane Science，2024，695：122453.

AN L，ZHAO T S，WU Q X，et al.Comparison of different types of membrane in alkaline direct ethanol fuel cells[J].International Journal of Hydrogen Energy，2012，37（19）：14536-14542.

HU Xu，LIU Minghui，HUANG Yingda，et al.Sulfonate-functionalized polybenzimidazole as ion-solvating membrane toward high-performance alkaline water electrolysis[J].Journal of Membrane Science，2022，663：121005.

ZARRIN H，JIANG Gaopeng，LAM G Y Y，et al. High performance porous polybenzimidazole membrane for alkaline fuel cells[J].International Journal of Hydrogen Energy，2014，39（32）：18405-18415.

ZENG Lin，ZHAO T S，AN Liang，et al.A high-performance sandwiched-porous polybenzimidazole membrane with enhanced alkaline retention for anion exchange membrane fuel cells [J].Energy & Environmental Science，2015，8（9）：2768-2774.

AN Liang，ZHAO Ts，LI Yinshi，et al.Charge carriers in alkaline direct oxidation fuel cells[J].Energy &Environmental Science，2012，5（6）：7536-7538.

WANG Ed，ZHAO T S，YANG W W.Poly（vinyl alcohol）/3-（trimethylammonium）propyl-functionalized silica hybrid membranes for alkaline direct ethanol fuel cells[J].International Journal of Hydrogen Energy，2010，35（5）：2183-2189.

SIPOS P M，HEFTER G，MAY P M.Viscosities and densities of highly concentrated aqueous MOH solutions（M + =Na + ，K + ，Li + ，Cs + ，（CH 3 ） 4 N + ）at 25.0℃[J ] .Journal of Chemical & Engineering Data，2000，45（4）：613-617.

ALAM A，PARK C，LEE J，et al.Comparative analysis of performance of alkaline water electrolyzer by using porous separator and ion-solvating polybenzimidazole membrane[J].Renewable Energy，2020，166：222-233.

LUO Hongze，VAIVARS G，AGBOOLA B，et al. Anion exchange membrane based on alkali doped poly（2，5-benzimidazole）for fuel cell[J].Solid State Ion ics，2012，208：52-55.

VEGA J A，CHARTIER C，MUSTAIN W E.Effect of hydroxide and carbonate alkaline media on anion exchange membranes [J].Journal of Power Sources，2010，195（21）：7176-7180.

AILI D，HANSEN M K，RENZAHO R F，et al. Heterogeneous anion conducting membranes based on linear and crosslinked KOH doped polybenzimidazole for alkaline water electrolysis [J].Journal of Membrane Science，2013，447：424-432.

LI Qingfeng，HE Ronghuan，BERG R W，et al. Water uptake and acid doping of polybenzimidazoles as electrolyte membranes for fuel cells [J].Solid State Ionics，2004，168（1/2）：177-185.

LEE M T.Designing anion exchange membranes with enhanced hydroxide ion conductivity by mesoscale simulations[J].The Journal of Physical Chemistry：C，2020，124（8）：4470-4482.

HAN K W，KO K H，ABU-HAKMEH K，et al. Molecular dynamics simulation study of a polysulfonebased anion exchange membrane in comparison with the proton exchange membrane[J].Journal of Physical Chemistry：C，2014，118（24）：12577-12587.

HERRANZ D，ESCUDERO-CID R，MONTIEL M，et al.Poly（vinyl alcohol）and poly（benzimidazole）blend membranes for high performance alkaline direct ethanol fuel cells[J].Renewable Energy，2018，127：883-895.

DIAZ L A，COPPOLA R E，ABUIN G C，et al.Alkali-doped polyvinyl alcohol：polybenzimidazole membranes for alkaline water electrolysis [J].Journal of Membrane Science，2017，535：45-55.

MAEGAWA K，HIKIMA K，TAN W K，et al.Enhancing water uptake and hydroxide ion conductivity of alkali fuel cell electrolyte membrane by layered double hydroxide[J].Solid State Ionics，2022，385：116021.

YU B C，WANG Yichun，LU H C，et al.Hydroxideion selective electrolytes based on a polybenzimidazole/graphene oxide composite membrane [J]. Energy，2017，134：802-812.

XIAN Fang，JIA Lulu，SUGAHARA Y，et al.Constructing fast transmembrane pathways in a layered double hydroxide nanosheets/nanoparticles composite film for an inorganic anion-exchange membrane [J]. ACS Applied Materials & Interfaces，2022，14（45）：51212-51221.

WANG Yindong，LIU Wei，SHANG Shu，et al.An LDH-enhanced porous polyethersulfone membrane doped with alkali for anion exchange membrane fuel cells[J].Materials Horizons，2025，12（18）：7570-7579.

DIAZ L A，HNÁT J，HEREDIA N，et al.Alkali doped poly（2，5-benzimidazole）membrane for alkaline water electrolysis：characterization and performance[J]. Journal of Power Sources，2016，312：128-136.

HUANG Zequan，ZHU Danyi，MA Mingjie，et al. Highly efficient and durable water electrolysis at high KOH concentration enabled by cationic group-free ion solvating membranes in free-standing gel form [J]. Small，2025，21（4）：2408159.

LEE J Y，CHOI Y B，LEE H J，et al.Optimized structure of asymmetric polybenzimidazole membranes to improve anion exchange membrane water electrolysis performance[J].Materials Today Energy，2025，48：101755.

LI Tiantian，SONG Xiangju，ZHANG Yajing，et al. Tailoring long-range ordered nanochannels in Nafion intercalated GO membrane for improved proton conduction [J]. Journal of Membrane Science，2025，724：123946.

XIAO Wei，LUO Xi，ZHOU Yongnan，et al.Poly（vinyl alcohol）/poly（ethylene glycol）ion-solvating membrane with NiFe-LDH for high-performance alkaline water electrolysis [J]. Separation and Purification Technology，2025，366：132769.

LIU Xiang，WEI Hongsen，ZHANG Ailing，et al. PPD cross-linked GO/WG anion exchange membrane with adjustable nanochannels [J].International Journal of Hydrogen Energy，2025，112：31-44.

LIU Xiang，ZHANG Ailing，YU Hao，et al.3 nmsized porous graphene-based anion exchange membranes for efficient and stable water electrolysis [J]. International Journal of Hydrogen Energy，2024，96：829-840.

PISMENSKAYA N，SARAPULOVA V，NEVAKSHENOVA E，et al.Concentration dependencies of diffusion permeability of anion-exchange membranes in sodium hydrogen carbonate，monosodium phosphate，and potassium hydrogen tartrate solutions[J].Membranes，2019，9（12）：170.

CHEN Rong，HUNG S F，ZHOU Daojin，et al.Layered structure causes bulk NiFe layered double hydroxide unstable in alkaline oxygen evolution reaction[J].Advanced Materials，2019，31（41）：1903909.

ROY CHOWDHURY P，MEDHI H，BHATTACHARYYA K G，et al.Recent progress in the design and functionalization strategies of transition metalbased layered double hydroxides for enhanced oxygen evolution reaction：a critical review[J].Coordination Chemistry Reviews，2023，483：215083.

PENG Lishan，YANG Na，YANG Yuqi，et al.Atomic cation-vacancy engineering of NiFe-layered double hydroxides for improved activity and stability towards theoxygenevolutionreaction [J].Angewandte Chemie International Edition，2021，60（46）：24612-24619.

ZHANG Jingfang，LIU Jieyu，XI Lifei，et al.Singleatom Au/NiFe layered double hydroxide electrocatalyst：probing the origin of activity for oxygen evolution reaction[J].Journal of the American Chemical Society，2018，140（11）：3876-3879.

TADANAGA K，FURUKAWA Y，HAYASHI A，et al.Direct ethanol fuel cell using hydrotalcite clay as a hydroxide ion conductive electrolyte [J].Advanced Materials，2010，22（39）：4401-4404.

ZENG L，ZHAO T S.Integrated inorganic membrane electrode assembly with layered double hydroxides as ionic conductors for anion exchange membrane water electrolysis[J].Nano Energy，2015，11：110-118.

WAN Lei，PANG Maobin，LE Junfa，et al.Oriented intergrowth of the catalyst layerin membrane electrode assembly for alkaline water electrolysis [J].Nature Communications，2022，13（1）：7956.

WAN Lei，XU Ziang，WANG Baoguo.Green preparation of highly alkali-resistant PTFE composite membranes for advanced alkaline water electrolysis [J]. Chemical Engineering Journal，2021，426：131340.

LIU Yizhe，XU Li，ZHANG Jian，et al.A rolling strategy for layered double hydroxide membrane to boost alkaline water electrolysis[J].Journal of Membrane Science，2025，720：123778.

LUFRANO E，SIMARI C，LO VECCHIO C，et al. Barrier properties of sulfonated polysulfone/layered double hydroxides nanocomposite membrane for direct methanol fuel cell operating at high methanol concentrations[J].International Journal of Hydrogen Energy，2020，45（40）：20647-20658.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Progress in the Construction of Ion Transport Pathways in Fuel Cell Membrane Electrodes Using Two-Dimensional Nanomaterials

Research on Proton Exchange Membrane Fuel Cell with Gradient Gas Diffusion Layer

Analysis of Impedance with Different Discharge Current in Proton Exchange Membrane Fuel Cell

Bi-Level Multi-Obj ective Optimization of a Wind-Solar Coupled Hydrogen Production System Based on the Synergy of Hybrid Electrolyzer Arrays

Windage Loss and Flow Characteristics in Impeller Back Gaps of sCO2 Radial Inflow Turbines

Related Author

HAN Haoqi

WANG Yindong

SHI Le

CHENG Yonghong

LIU Wei

SHI Le

CHENG Yonghong

Related Institution

School of Electrical Engineering，Xi'an Jiaotong University

State Key Laboratory of Electrical Insulation and Power Equipment，Xi'an Jiaotong University

The Center of Nanomaterials for Renewable Energy，Xi 'an Jiaotong University

State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology

⁰