Influences of Fuel Type,Combustion Phase,and Photoaging on Volatile Organic Compound Emissions and Health Risks

CHEN Zhiwen; YE Xinpeng; YANG Jiaer; HE Kun; SUN Jian; PENG Zezhi; SHEN Zhenxing

doi:10.7652/xjtuxb202602012

您当前的位置：

首页 >

文章列表页 >

Influences of Fuel Type,Combustion Phase,and Photoaging on Volatile Organic Compound Emissions and Health Risks

Special Topic Pollution Control and Resource Utilization in the "Dual Carbon" Context | 更新时间：2026-02-09

- Influences of Fuel Type,Combustion Phase,and Photoaging on Volatile Organic Compound Emissions and Health Risks
- Journal of Xi'an Jiaotong University Vol. 60, Issue 2, Pages: 125-135(2026)
- 作者机构：
  
  西安交通大学能源与动力工程学院，710049，西安
- 作者简介：
- 基金信息：
- DOI：10.7652/xjtuxb202602012
  CLC： X511
- Received：29 May 2025，
  
  Published：10 February 2026
- 稿件说明：
移动端阅览
CHEN Zhiwen, YE Xinpeng, YANG Jiaer, et al. Influences of Fuel Type,Combustion Phase,and Photoaging on Volatile Organic Compound Emissions and Health Risks[J]. Journal of Xi'an Jiaotong University, 2026, 60(2): 125-135.
DOI：

CHEN Zhiwen, YE Xinpeng, YANG Jiaer, et al. Influences of Fuel Type,Combustion Phase,and Photoaging on Volatile Organic Compound Emissions and Health Risks[J]. Journal of Xi'an Jiaotong University, 2026, 60(2): 125-135. DOI： 10.7652/xjtuxb202602012.

摘要

从健康视角出发，采用飞行时间质谱仪表征玉米秸秆、烟煤和煤基生物质型煤燃烧时的挥发性有机物（VOCs）排放特征，分析其健康风险。首先，根据燃烧效率分析不同燃烧阶段对各类燃料总挥发性有机物（TVOC）的排放影响；然后，基于美国环境保护署健康风险模型，计算不同燃料燃烧过程中的实时健康风险；最后，采用氧化流动反应器对燃烧烟气进行紫外辐照处理，评估光化学老化对VOCs排放特征的影响。研究结果表明：玉米秸秆燃烧产生的TVOC质量浓度最高，烟煤次之，型煤最低；修正燃烧效率与VOCs的生成量呈负相关，不完全燃烧使得污染物排放强度显著提升；健康风险评估模型评估显示，玉米秸秆、烟煤和型煤3种燃料的非致癌风险指数均大于30，累积致癌风险指数均大于1.0×10

-4

，超过了安全阈值，非致癌风险和致癌风险较高；光老化使得致癌风险降低了70.46%，但对非致癌风险的削减程度有限。研究结果可为公共健康防护政策制定和清洁能源利用策略提供科学依据。

Abstract

From a healthy combustion perspective，time-of-flight mass spectrometry was employed to characterize volatile organic compounds（VOCs）emissions from corn straw，bituminous coal，and coal-biomass briquettes，and to assess their associated health risks. First，the influence of different combustion phases on total volatile organic compound（TVOC）emissions from various fuels was analyzed based on combustion efficiency.Second，the U.S.environmental protection agency health risk model was used to calculate real-time health risks during the combustion of different fuels.Finally，an oxidation flow reactor was applied to simulate ultraviolet irradiation of combustion flue gas，and the effect of ph

otochemical aging on VOC emission characteristics was evaluated.The results show that the TVOC mass concentration emitted from corn straw combustion was the highest，followed by bituminous coal，with coal-based biomass briquettes being the lowest.A negative correlation was observed between modified combustion efficiency and VOC generation，and incomplete combustion significantly increased pollutant emission intensity. Health risk assessment indicated that the hazard index for all three fuels exceeded 30，and the cumulative carcinogenic risk exceeded 1×10

-4

，surpassing safety thresholds and indicating high non-carcinogenic and carcinogenic risks.Photoaging reduced carcinogenic risk by 70.46%，but had a limited mitigating effect on non-carcinogenic risk.The findings provide a scientific basis for the formulation of public health protection policies and clean energy utilization strategies.

关键词

Keywords

references

张蕊,孙雪松,王裕,等.北京市城区夏季大气VOCs变化特征及臭氧生成潜势[J].环境科学, 2023, 44(4):1954-1961.

ZHANG Rui, SUN Xuesong, WANG Yu, et al.Variation characteristics and ozone formation potential of ambient VOCs in urban Beijing in summer[J].Environmental Science, 2023, 44(4):1954-1961.

曹梦瑶,林煜棋,章炎麟.南京工业区秋季大气挥发性有机物污染特征及来源解析[J].环境科学, 2020, 41(6):2565-2576.

CAO Mengyao, LIN Yuqi, ZHANG Yanlin.Charac-teristics and source apportionment of atmospheric VOCs in the Nanjing industrial area in autumn[J]. Environmental Science, 2020, 41(6):2565-2576.

司雷霆,王浩,李洋,等.太原市夏季大气VOCs污染特征及臭氧生成潜势[J].中国环境科学, 2019, 39(9):3655-3662.

SI Leiting, WANG Hao, LI Yang, et al.Pollution characteristics and ozone formation potential of ambient VOCs in summer in Taiyuan[J].China Environmental Science, 2019, 39(9):3655-3662.

KARAKOÇAK B B, PATEL S, RAVI N, et al. Investigating the effects of stove emissions on ocular and cancer cells[J].Scientific Reports, 2019 , 9(1 ):1870.

NIU Xinyi, LIU Xinyao, ZHANG Bin, et al.Health benefits from substituting raw biomass fuels for charcoal and briquette fuels:in vitro toxicity analysis[J]. Science of the Total Environment, 2023, 866:161332.

DESSERVETTAZ M, PIKRIDAS M, STAVROU-LAS I, et al.Emission of volatile organic compounds from residential biomass burning and their rapid chemical transformations[J].Science of the Total Environment, 2023, 903:166592.

HUANG Guanghan, WANG Shuxiao, CHANG Xing, et al.Emission factors and chemical profile of I/SVOCs emitted from household biomass stove in China[J]. Science of the Total Environment, 2022, 842:156940.

IHANTOLA T, DI BUCCHIANICO S, HAPPO M, et al.Influence of wood species on toxicity of log-wood stove combustion aerosols:a parallel animal and airliquid interface cell exposure study on spruce and pine smoke[J].Particle and Fibre Toxicology, 2020, 17(1):27.

CHEN Yuexi, XIE Shuojia, CHEN Xirong, et al.Impact of solid fuel use on asthma prognosis and consistent peak expiratory flow changes:evidence from China[J]. Ecotoxicology and Environmental Safety, 2025, 290:117555.

HE Kun, SHEN Zhenxing, ZHANG Bin, et al. Emission profiles of volatile organic compounds from various geological maturity coal and its clean coal briquetting in China[J].Atmospheric Research, 2022, 274:106200.

KIM Y H, WARREN S H, KRANTZ Q T, et al. Mutagenicity and lung toxicity of smoldering vs.flaming emissions from various biomass fuels:implications for health effects from wildland fires[J].Environmental Health Perspectives, 2018, 126(1):017011.

MAO J, REN X, BRUNE W H, et al. Airborne measurement of OH reactivity during INTEX-B[J]. Atmospheric Chemistry and Physics, 2009, 9 (1 ):163-173.

URBANSKI S P.Combustion efficiency and emission factors for wildfire-season fires in mixed conifer forests of the northern Rocky Mountains, US[J].Atmospheric Chemistry and Physics, 2013, 13(14):7241-7262.

U.S.Environmental Protection Agency.Air toxics risk assessment reference library volume 2 facility-specific assessment[EB/OL].[2025-03-15].https://www. epa.gov/sites/default/files/2013-08/documents/volume _2_facilityassess.pdf.

DEMIRBAS A.Combustion efficiency impacts of biofuels[J].Energy Sources:Part A Recovery, Utilization, and Environmental Effects, 2009, 31(7):602609 .

SIEGMUND T, GOLLMER C, SCHERZINGER M, et al.A review of CO emissions during solid biofuel combustion:formation mechanisms and fuel-related reduction measures[J].Journal of the Energy Institute, 2024, 116:101762.

TU Ren, SUN Yan, WU Yujian, et al.Improvement of corn stover fuel properties via hydrothermal carbonization combined with surfactant[J].Biotechnology for Biofuels, 2019, 12(1):249.

WEI Qingwen, PANG Keliang, LIANG Cai, et al. Co-pyrolysis of coal with biomass residues and coke breeze for superior quality coke via hot pressing technology[J].Journal of Analytical and Applied Pyrolysis, 2024, 180:106547.

SUN Jian, SHEN Zhenxing, ZHANG Bin, et al. Chemical source profiles of particulate matter and gases emitted from solid fuels for residential cooking and heating scenarios in Qinghai-Tibetan Plateau[J].Environmental Pollution, 2021, 285:117503.

DULA M, KRASZKIEWICZ A, PARAFINIUK S. Combustion efficiency of various forms of solid biofuels in terms of changes in the method of fuel feeding into the combustion chamber[J].Energies, 2024, 17(12):2853.

张鹤丰.中国农作物秸秆燃烧排放气态、颗粒态污染物排放特征的实验室模拟[D].上海:复旦大学, 2009.

YAN Zhonghao, GAO Yu, ZHANG Yong, et al. Study on the emission characteristics of VOCs under the condition of biomass blending combustion[J].Heliyon, 2023, 9(12):e22340.

XU Jingxin, ZHU Fahua, GE Xinlei, et al.Research progress on volatile organic compounds emissions from coal-fired power plants[J].Current Pollution Reports, 2022, 8(3):303-314.

ZHANG Dong, HE Bing, YUAN Minghao, et al. Characteristics, sources and health risks assessment of VOCs in Zhengzhou, China during haze pollution season[J].Journal of Environmental Sciences, 2021, 108:44-57.

SUN Xue, LI Chaolin, YU Boping, et al.Removal of gaseous volatile organic compounds via vacuum ultraviolet photodegradation:review and prospect[J].Journal of Environmental Sciences, 2023, 125:427-442.

宋彦龙,游俊琴,张忠良,等.真空紫外光降解苯的研究[J].环境工程学报, 2008, 2(11):1535-1538.

SONG Yanlong, YOU Junqin, ZHANG Zhongliang, et al.Study on degradation of benzene by vacuum ultraviolet[J].Chinese Journal of Environmental Engineering, 2008, 2(11):1535-1538.

CHEN Jin, FAN Bo, LI Ji, et al.Development of human health ambient water quality criteria of 12 polycyclic aromatic hydrocarbons (PAH)and risk assessment in China[J].Chemosphere, 2020, 252:126590.

ZHU Lifu, JIA Xueqian, XIE Haibo, et al.Trichloroethylene exposure, multi-organ injury, and potential mechanisms:a narrative review[J].Science of the Total Environment, 2024, 946:174029.

ANWER M B, AL-MASHHADANI M H, AL-SAYED R, et al.Optimizing PVC photostability and UV blocking capability through nanoparticles incorporation:a comprehensive review[J].Journal of Vinyl and Additive Technology, 2025, 31(2):259-278.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Influences of Fuel Types, Combustion Phases, and Photoaging Effects on Atmospheric Volatile Organic Compounds Emissions and Health Risks

A Quantitative Detection System of Volatile Organic Compounds Based on Combining Sensor Array and BP Neural Network

Concentration Monitoring Method with Infrared Sensor for Determining Safe Concentration of Main VOCs in Nuclear Containment

Influence of Injection Strategy on Combustion and Emissions of Multi-point Injection Natural Gas Engine

Molecular Simulation Study on Effects of Char Pore Characteristics on VOC Adsorption Behaviors

Related Author

Shen Zhenxing

Peng Zezhi

Sun Jian

He Kun

Yang Jiaer

Ye Xinpeng

CHEN Zhiwen

王海容

Related Institution

School of Energy and Power Engineering, Xi’an Jiaotong University

State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University

School of Mechanical Engineering, Xi'an Jiaotong University

China Nuclear Power Technology Research Institute Co. Ltd.

College of Power and Energy Engineering, Harbin Engineering University

⁰