Characteristics and Economic Analysis of Hydrogen Production Process through Pyrolysis and Adsorption Enhanced Reforming of Waste Tires

SHEN Mengfei; SONG Huchao; XING Dingyi; WANG Bo; LIU Yinhe

doi:10.7652/xjtuxb202410020

您当前的位置：

首页 >

文章列表页 >

Characteristics and Economic Analysis of Hydrogen Production Process through Pyrolysis and Adsorption Enhanced Reforming of Waste Tires

更新时间：2025-07-28

- Characteristics and Economic Analysis of Hydrogen Production Process through Pyrolysis and Adsorption Enhanced Reforming of Waste Tires
- Vol. 58, Issue 10, Pages: 222-232(2024)
- 作者机构：
  
  1. 西安交通大学动力工程多相流国家重点实验室,西安,710049
  2. 西安交通大学能源与动力工程学院,西安,710049
- 作者简介：
- 基金信息：
- DOI：10.7652/xjtuxb202410020
  CLC： X705
- Online First：10 October 2024，
  
  Published：2024
- 稿件说明：
移动端阅览
SHEN Mengfei, SONG Huchao, XING Dingyi, et al. Characteristics and Economic Analysis of Hydrogen Production Process through Pyrolysis and Adsorption Enhanced Reforming of Waste Tires[J]. 2024, 58(10): 222-232.
DOI：

SHEN Mengfei, SONG Huchao, XING Dingyi, et al. Characteristics and Economic Analysis of Hydrogen Production Process through Pyrolysis and Adsorption Enhanced Reforming of Waste Tires[J]. 2024, 58(10): 222-232. DOI： 10.7652/xjtuxb202410020.

摘要

为实现废旧轮胎资源化利用

提出一种废旧轮胎热解耦合吸附强化重整制氢工艺。基于吉布斯自由能最小化原理以及能量和质量守恒定律

以CaO为吸附剂构建了废旧轮胎热解耦合吸附强化重整制氢工艺流程

将传统重整与CO

原位吸附相结合。分析考察了重整反应温度、反应压力、水与碳物质的量比(n

/n(C))、钙与碳物质的量比(n(Ca)/n(C))作参数对工艺热力学性能的影响

并从技术经济性角度分析了该工艺的可行性。研究结果表明:温度和n

/n(C)的增加都可以提高氢气产率

但是制氢效率会随着重整温度和n

/n(C)的不断增加而降低; n(Ca)/n(C)增加可以提高氢气产率及制氢效率

但是当n(Ca)/n(C)>1时提升不大。综合考虑

最佳操作参数如下:重整温度为650 ℃、重整压力为1 MPa、n

/n(C)为3.5、n(Ca)/n(C)为1

此时氢气产率为0.203

制氢效率为57.9%。经济性分析表明

废旧轮胎制氢成本约为10.87元/kg

投资回收期为4 a

具有较高的经济效益。研究结果可为废旧轮胎高值化利用提供参考。

Abstract

To promote the efficient utilization of waste tires

a hydrogen production process involving pyrolysis

adsorption

and enhanced reforming of waste tires is proposed. Based on the principles of minimizing Gibbs free energy and maintaining energy and mass conservation

the proposed process flow employs CaO as the adsorbent to combine traditional reforming with in-situ CO

adsorption. The thermodynamic performance of the p

rocess is analyzed by examining the effects of reforming reaction temperature

reaction pressure

steam-to-carbon ratio(n

/n(C))

and calcium-to-carbon ratio(n(Ca)/n(C)). Additionally

a techno-economic evaluation is conducted to assess the feasibility of the process. The research findings indicate that increasing the reforming temperature and n

/n(C)enhances hydrogen yield. However

the hydrogen production efficiency decreases as the reforming temperature and n

/n(C)increase. On the other hand

increasing the n(Ca)/n(C)ratio improves both hydrogen yield and production efficiency

although the improvement becomes less significant when n(Ca)/n(C)exceeds 1. Considering all factors

the optimal operating parameters are determined as follows: a reforming temperature of 650 ℃

a reforming pressure of 1 MPa

an n

/n(C)ratio of 3.5

and an n(Ca)/n(C)ratio of 1. Under these conditions

the hydrogen yield is 0.203

and the hydrogen production efficiency reaches 57.9%. Economic analysis reveals that the cost of hydrogen production from waste tires is approximately 10.87 yuan/kg

with a payback period of 4 a. These results indicate significant economic benefits associated with the process. The research outcomes provide valuable insights for the high-value utilization of waste tires.

关键词

Keywords

references

MOUNEIR S M, EL-SHAMY A M. A review on harnessing the energy potential of pyrolysis gas from scrap tires: challenges and opportunities for sustainable energy recovery [J]. Journal of Analytical and Applied Pyrolysis, 2024, 177: 106302.

MMEREKI D, MACHOLA B, MOKOKWE K. Status of waste tires and management practice in Botswana [J]. Journal of the Air Waste Management Association, 2019, 69(10): 1230-1246.

ROGACHUK B E, OKOLIE J A. Waste tires based biorefinery for biofuels and value-added materials production [J]. Chemical Engineering Journal Advances, 2023, 14: 100476.

OBOIRIEN B O, NORTH B C. A review of waste tyre gasification [J]. Journal of Environmental Chemical Engineering, 2017, 5(5): 5169-5178.

王晓初, 江必有, 聂晓梅. 中国废旧轮胎循环利用前景与建议 [J]. 橡塑技术与装备, 2022, 48(8): 5-8.

WANG Xiaochu, JIANG Biyou, NIE Xiaomei. Prospects and suggestions for recycling of waste tires in China [J]. China Rubber/Plastics Technology and Equipment, 2022, 48(8): 5-8.

SATHISKUMAR C, KARTHIKEYAN S. Recycling of waste tires and its energy storage application of by-products: a review [J]. Sustainable Materials and Technologies, 2019, 22: e00125.

ROWHANI A, RAINEY T J. Scrap tyre management pathways and their use as a fuel: a review [J]. Energies, 2016, 9(11): 888.

RAMARAD S, KHALID M, RATNAM C T, et al. Waste tire rubber in polymer blends: a review on the evolution, properties and future [J]. Progress in Materials Science, 2015, 72: 100-140.

CZARNA-JUSZKIEWICZ D, KUNECKI P, CADER J, et al. Review in waste tire management: potential applications in mitigating environmental pollution [J]. Materials, 2023, 16(17): 5771.

DOWNARD J, SINGH A, BULLARD R, et al. Uncontrolled combustion of shredded tires in a landfill: part 1 characterization of gaseous and particulate emissions [J]. Atmospheric Environment, 2015, 104: 195-204.

SIENKIEWICZ M, KUCINSKA-LIPKA J, JANIK H, et al. Progress in used tyres management in the European Union: a review [J]. Waste Management, 2012, 32(10): 1742-1751.

ZEAITER J, AZIZI F, LAMEH M, et al. Waste tire pyrolysis using thermal solar energy: an integrated approach [J]. Renewable Energy, 2018, 123: 44-51.

MARTÍNEZ J D, PUY N, MURILLO R, et al. Waste tyre pyrolysis: a review [J]. Renewable and Sustainable Energy Reviews, 2013, 23: 179-213.

DOU Binlin, WANG Chao, SONG Yongchen, et al. Solid sorbents for in-situ CO2 removal during sorption-enhanced steam reforming process: a review [J]. Renewable and Sustainable Energy Reviews, 2016, 53: 536-546.

WANG Yinxiang, MEMON M Z, SEELRO M A, et al. A review of CO2 sorbents for promoting hydrogen production in the sorption-enhanced steam reforming process [J]. International Journal of Hydrogen Energy, 2021, 46(45): 23358-23379.

ABBAS S Z, DUPONT V, MAHMUD T. Modelling of high purity H2 production via sorption enhanced chemical looping steam reforming of methane in a packed bed reactor [J]. Fuel, 2017, 202: 271-286.

刘璐, 许凯, 荆洁颖, 等. CO2吸附强化CH4/H2O重整制氢催化剂研究进展 [J]. 洁净煤技术, 2021, 27(1): 73-82.

LIU Lu, XU Kai, JING Jieying, et al. Research progress on catalysts for hydrogen production by CO2 sorption enhancement of CH4/H2O reforming [J]. Clean Coal Technology, 2021, 27(1): 73-82.

陈玲, 祁华清. 废弃轮胎气化制氢过程技术经济分析 [J]. 广东化工, 2022, 49(17): 117-119.

CHEN Ling, QI Huaqing. Process simulation and techno-economic analysis of hydrogen production from end-of-life tires by gasification [J]. Guangdong Chemical Industry, 2022, 49(17): 117-119.

FAJIMI L I, OBOIRIEN B O, ADAMS T A II. Simulation studies on the co-production of syngas and activated carbon from waste tyre gasification using different reactor configurations [J]. Energy Conversion and Management: X, 2021, 11: 100105.

ZANG Guiyan, JIA Guiyan, SHI Yunye, et al. Modeling and economic analysis of waste tire gasification in fluidized and fixed bed gasifiers [J]. Waste Management, 2019, 89: 201-211.

LI Bin, FABRICE MAGOUA MBEUGANG C, LIU Dongjing, et al. Simulation of sorption enhanced staged gasification of biomass for hydrogen production in the presence of calcium oxide [J]. International Journal of Hydrogen Energy, 2020, 45(51): 26855-26864.

DETCHUSANANARD T, IM-ORB K, MARÉCHAL F, et al. Analysis of the sorption-enhanced chemical looping biomass gasification process: performance assessment and optimization through design of experiment approach [J]. Energy, 2020, 207: 118190.

SANTOS M P S, HANAK D P. Techno-economic feasibility assessment of sorption enhanced gasification of municipal solid waste for hydrogen production [J]. International Journal of Hydrogen Energy, 2022, 47(10): 6586-6604.

杨金航. 木质素热解机理及纤维素乙醇多联产工艺技术经济性研究 [D]. 天津: 河北工业大学, 2022.

FENG Fuyuan, LI Tongyu, AN Jizhen, et al. Performance assessment of a novel polygeneration system based on the integration of waste plasma gasification, tire pyrolysis, gas turbine, supercritical CO2 cycle and organic Rankine cycle [J]. Journal of Thermal Science, 2023, 32(6): 2196-2214.

KHOJASTEH SALKUYEH Y, SAVILLE B A, MACLEAN H L. Techno-economic analysis and life cycle assessment of hydrogen production from natural gas using current and emerging technologies [J]. International Journal of Hydrogen Energy, 2017, 42(30): 18894-18909.

HAMELINCK C N, FAAIJ A P C. Future prospects for production of methanol and hydrogen from biomass [J]. Journal of Power Sources, 2002, 111(1): 1-22.

HAAF M, ANANTHARAMAN R, ROUSSANALY S, et al. CO2 capture from waste-to-energy plants: techno-economic assessment of novel integration concepts of calcium looping technology [J]. Resources, Conservation and Recycling, 2020, 162: 104973.

BI Rongshan, ZHANG Yan, JIANG Xiao, et al. Simulation and techno-economical analysis on the pyrolysis process of waste tire [J]. Energy, 2022, 260: 125039.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Optimization of Hydrogen Production and Storage Capacity and Feasibility Analysis of Wind-Solar-Thermal-Storage Coupled Hydrogen Energy Storage System

Study on the Performance of Methane Steam Reforming Reaction for Hydrogen Production in Spherical Particles with Triply Periodic Minimal Surface Structures

Experimental Research on Production from Biomass and Coal Gasified in Supercritical Water

Influence of Main Parameters on Hydrogen Production During Biomass/Coal Gasification in Supercritical Water

Integrated and Joint Design Optimization of Centrifugal Compressor Impeller and Casing Treatment at Multiple Working Points

Related Author

LIU Yinhe

HAO Junli

JIN Senwang

SONG Huchao

WU Wenting

MENG Xianchen

LIU Tao

LIN Xiaolong

Related Institution

Bayanhot Power Generation Branch, Inner Mongolia Huadian Tenggeli Green Energy Co., Ltd., Alxa League, Inner Mongolia 750300, China

Northwest Electric Power Design Institute Co., Ltd., China Power Engineering Consulting Group, Xi’an 710075, China

State key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China

西安交通大学热流科学与工程教育部重点实验室，710049，西安MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China

Inner Mongolia Huadian Tenggeli Green Energy Co., Ltd. Bayanhot Power Generation Branch, Alxa League

⁰