Zinc Ash Recycling and the System of Supercritical Hydrothermal Synthesis of Nano-Zinc Oxide

LIU Lu; WANG Shuzhong; LIU Wei; ZHANG Baoquan; LIU Hui; LIU Hui; ZHAO Jun'an

doi:10.7652/xjtuxb202403018

您当前的位置：

首页 >

文章列表页 >

Zinc Ash Recycling and the System of Supercritical Hydrothermal Synthesis of Nano-Zinc Oxide

更新时间：2025-07-09

- Zinc Ash Recycling and the System of Supercritical Hydrothermal Synthesis of Nano-Zinc Oxide
- Vol. 58, Issue 3, Pages: 193-203(2024)
- 作者机构：
  
  西安交通大学能源与动力工程学院,西安,710049
- 作者简介：
- 基金信息：
- DOI：10.7652/xjtuxb202403018
  CLC： O781;TM912.9
- Online First：10 March 2024，
  
  Published：2024
- 稿件说明：
移动端阅览
LIU Lu, WANG Shuzhong, LIU Wei, et al. Zinc Ash Recycling and the System of Supercritical Hydrothermal Synthesis of Nano-Zinc Oxide[J]. 2024, 58(3): 193-203.
DOI：

LIU Lu, WANG Shuzhong, LIU Wei, et al. Zinc Ash Recycling and the System of Supercritical Hydrothermal Synthesis of Nano-Zinc Oxide[J]. 2024, 58(3): 193-203. DOI： 10.7652/xjtuxb202403018.

摘要

为了对锌灰进行资源化回收及对其经济性进行分析

将湿法回收工艺和超临界水热合成技术相结合

将锌灰生成价值较高的纳米氧化锌产品

采用Aspen Plus软件平台

建立了完整的系统工艺

并分析了系统运行过程中的物料成本及能耗成本。在硫酸浓度为2 mol·L

-1

、固液比为1:8、浸出温度为50 ℃、浸出时间为2 h、搅拌器转速为300 r·min

-1

的条件下

锌灰中锌的浸出率达到了95%以上。除杂过程除去了Fe、Al、Ni、Cu等杂质

除杂后的溶液中锌的质量分数达到了97%。利用锌灰浸出液在400 ℃和25 MPa的超临界条件下

合成了平均粒径为26 nm的纳米氧化锌

晶体结晶度良好

纯度较高。通过与纯物料所合成的纳米氧化锌进行对比

验证了该技术的可行性

显著提升了系统运行的经济性。

Abstract

In this study

a combination of wet recovery process and supercritical hydrothermal synthesis technology is employed to produce high-value nano-zinc oxide products from zinc ash

and an economic analysis of this approach to zinc ash recycling is conducted. A sound system is established using Aspen Plus

and material costs and energy consumption during system operation are analyzed. The leaching rate of zinc in the zinc ash exceeds 95%

under the conditions of sulfuric acid concentration of 2 mol·L

-1

solid-liquid ratio of 1:8

leaching temperature of 50 ℃

leaching time of 2 h

and stirrer speed of 300

r·min

-1

. Fe

Cu and other impurities are eliminated in the impurity removal process

and the zinc content in the solution after impurity removal reaches 97%. The leaching solution of zinc ash is used to synthesize nano-zinc oxide with an average particle size of 26 nm under supercritical conditions of 400 ℃ and 25 MPa. The resulting zinc oxide exhibits excellent crystallinity and high purity. The comparison with nano-zinc oxide synthesized from pure materials validates the feasibility of this technology

which significantly improves the system's economic viability.

关键词

Keywords

references

佘雪峰, 薛庆国, 王静松, 等. 钢铁厂含锌粉尘综合利用及相关处理工艺比较 [J]. 炼铁, 2010, 29(4): 56-62.

SHE Xuefeng, XUE Qingguo, WANG Jingsong, et al. Comprehensive utilization of zinc-bearing dust and comparison of treatment processes [J]. Ironmaking, 2010, 29(4): 56-62.

诸荣孙, 吴争, 伊廷锋, 等. 硫酸浸出转底炉高锌铅粉尘的研究 [J]. 矿冶工程, 2012, 32(3): 103-106.

ZHU Rongsun, WU Zheng, YI Tingfeng, et al. Study on leaching high Zn-Pb dust from rotary hearth furnace by sulfuric acid solution [J]. Mining and Metallurgical Engineering, 2012, 32(3): 103-106.

孙红燕, 森维, 孔馨, 等. 用盐酸从锌烟尘中浸出铅锌试验研究 [J]. 湿法冶金, 2014, 33(1): 20-22.

SUN Hongyan, SEN Wei, KONG Xin, et al. Leaching of lead and Zinc from Zinc dust using hydrochloric acid [J]. Hydrometallurgy of China, 2014, 33(1): 20-22.

KARLFELDT FEDJE K, ANDERSSON S. Zinc recovery from waste-to-energy fly ash-a pilot test study [J]. Waste Management, 2020, 118: 90-98.

于泳. 纳米氧化锌在轮胎胶料中的应用研究 [J]. 轮胎工业, 2002, 22(12): 729-732.

YU Yong. Application of nano-zinc oxide to tire compound [J]. Tire Industry, 2002, 22(12): 729-732.

李硕, 代静, 李莉, 等. 进口防晒剂中纳米氧化锌和纳米二氧化钛检测结果分析 [J]. 日用化学工业, 2019, 49(9): 621-626.

LI Shuo, DAI Jing, LI Li, et al. Determination of zinc oxide and titanium dioxide nanoparticles in imported sunscreen cosmetics [J]. China Surfactant Detergent Cosmetics, 2019, 49(9): 621-626.

吕瑛, 谢嘉颖. 防晒剂中纳米氧化锌的安全性研究进展 [J]. 中国化妆品, 2011(5): 62-65.

LÜ Ying, XIE Jiaying. Research progress on the safety of nano zinc oxide in sunscreen agents [J]. China Cosmetics Review, 2011(5): 62-65.

ADSCHIRI T, KANAZAWA K, ARAI K. Rapid and continuous hydrothermal crystallization of metal oxide particles in supercritical water [J]. Journal of the American Ceramic Society, 1992, 75(4): 1019-1022.

SUE K, MURATA K, KIMURA K, et al. Continuous synthesis of zinc oxide nanoparticles in supercritical water [J]. Green Chemistry, 2003, 5(5): 659-662.

SUE K, KIMURA K, ARAI K. Hydrothermal synthesis of ZnO nanocrystals using microreactor [J]. Materials Letters, 2004, 58(25): 3229-3231.

SUE K, KIMURA K, YAMAMOTO M, et al. Rapid hydrothermal synthesis of ZnO nanorods without organics [J]. Materials Letters, 2004, 58(26): 3350-3352.

VISWANATHAN R, GUPTA R B. Formation of zinc oxide nanoparticles in supercritical water [J]. The Journal of Supercritical Fluids, 2003, 27(2): 187-193.

SØNDERGAARD M, BØJESEN E D, CHRISTENSEN M, et al. Size and morphology dependence of ZnO nanoparticles synthesized by a fast continuous flow hydrothermal method [J]. Crystal Growth Design, 2011, 11(9): 4027-4033.

LEYBROS A, PIOLET R, ARIANE M, et al. CFD simulation of ZnO nanoparticle precipitation in a supercritical water synthesis reactor [J]. The Journal of Supercritical Fluids, 2012, 70: 17-26.

SONG Shaole, SUN Wei, WANG Li, et al. Recovery of cobalt and zinc from the leaching solution of zinc smelting slag [J]. Journal of Environmental Chemical Engineering, 2019, 7(1): 102777.

RUDNIK E. Recovery of zinc from zinc ash by leaching in sulphuric acid and electrowinning [J]. Hydrometallurgy, 2019, 188: 256-263.

王雷. 含锌烟灰回收锌的工艺研究 [J]. 烧结球团, 2020, 45(3): 67-71.

WANG Lei. Research on the technology of zinc recovery from zinc-containing dust [J]. Sintering and Pelletizing, 2020, 45(3): 67-71.

DVORˇÁK P, JANDOVÁ J. Hydrometallurgical recovery of zinc from hot dip galvanizing ash [J]. Hydrometallurgy, 2005, 77(1/2): 29-33.

郑东升, 肖松, 梁杰. 含锗烟尘的硫酸浸出工艺研究 [J]. 云南化工, 2012, 39(6): 1-5.

ZHENG Dongsheng, XIAO Song, LIANG Jie. Study on leaching process of germanium fly ash with sulfuric acid [J]. Yunnan Chemical Technology, 2012, 39(6): 1-5.

JIANG Tao, ZHANG Tao, YE Fengchun, et al. Occurrence state and sulfuric-acid leaching behavior of germanium in secondary zinc oxide [J]. Minerals Engineering, 2019, 137: 334-343.

KURSUNOGLU S, TOP S, KAYA M. Recovery of zinc and lead from Yahyali non-sulphide flotation tailing by sequential acidic and sodium hydroxide leaching in the presence of potassium sodium tartrate [J]. Transactions of Nonferrous Metals Society of China, 2020, 30(12): 3367-3378.

KURSUNOGLU S, KURSUNOGLU N, HUSSAINI S, et al. Selection of an appropriate acid type for the recovery of zinc from a flotation tailing by the analytic hierarchy process [J]. Journal of Cleaner Production, 2021, 283: 124659.

ASADI ZEYDABADI B, MOWLA D, SHARIAT M H, et al. Zinc recovery from blast furnace flue dust [J]. Hydrometallurgy, 1997, 47(1): 113-125.

罗文波, 王吉坤, 赵兴凡, 等. 含铟氧化锌烟尘加压硫酸浸出工艺优化 [J]. 过程工程学报, 2015, 15(6): 982-987.

LUO Wenbo, WANG Jikun, ZHAO Xingfan, et al. Optimization of pressure leaching process of indium-bearing Zinc oxide dust with sulfuric acid [J]. The Chinese Journal of Process Engineering, 2015, 15(6): 982-987.

SHAWABKEH R A. Hydrometallurgical extraction of zinc from Jordanian electric arc furnace dust [J]. Hydrometallurgy, 2010, 104(1): 61-65.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study of Crystallization Mechanism of Nano-BaTiO3 by Supercritical Hydrothermal Synthesis

I/O Performance Modeling and Prediction Method for Large-Scale Parallel Applications Using Machine Learning

A Structure-Semantics-Residual Collaborative Image Compression Framework：Towards Privacy Protection and High-Fidelity Reconstruction

Integrated and Joint Design Optimization of Centrifugal Compressor Impeller and Casing Treatment at Multiple Working Points

Windage Loss and Flow Characteristics in Impeller Back Gaps of sCO2 Radial Inflow Turbines

Related Author

ZHANG Wenjin

WANG Shuzhong

LIU Hui

CHEN Shuangping

DENG Xuetao

YANG Jianqiao

LI Zicheng

Related Institution

School of Energy and Power Engineering，Xi’an Jiaotong University

School of Energy and Power Engineering, Xi’an Jiaotong University

⁰