In order to study the effect of iodine value on the emission characteristics of biodiesel combustion particulate matter
the engine exhaust particle sizer and carbon analyzer were used to analyze the particle size distribution and carbon component of particulate matter from different biodiesels. The results show that the maximum explosion pressure
combustion temperature and combustion duration of three biodiesels are higher than that of diesel at the maximum engine torque speed 2 400 r/min and 100% load. The greater the iodine value is
the shorter the combustion duration becomes. The use of biodiesel can effectively reduce the amount of particulate matter emissions
with a maximum reduction of 85%
and the particle size of biodiesel particles is decreased. The higher the iodine value is
the more the particulate matter is produced. The emission concentration of soybean oil methyl ester particles with larger iodine value is 5.3 times that of waste oil methyl ester particles with lower iodine value. The main components of organic carbon(OC)in the carbonaceous component of particulate matter are OC1 and OC4
which account for more than 60% of the total carbon(TC). The main component of elemental carbon(EC)is EC2
which accounts for more than 50% of the total EC. The ratio of diesel particulate organic carbon(OC)to elemental carbon(EC)in the carbonaceous component of particulate matter is 7.4
and the biodiesel OC/EC value is 18.2-24.5. The higher the iodine value of biodiesel
the higher the OC/EC value of particulate matter carbon component. Using biodiesel with lower iodine value can reduce particulate matter emission more effectively.
WEI Yanjiu, WANG Wenrui, HUANG Jin, et al. Study on the origination of soluble organic fractions in diesel engine-out particulate matters [J]. Journal of Xi'an Jiaotong University, 2013, 47(5): 6-11.
WANG Jian, SHU Jiaze, CHEN Xinyu, et al. Chinese journal of tuberculosis and respiratory diseases [J]. Chinese Journal of Tuberculosis and Respiratory Diseases, 2013, 36(12): 970-972.
YOU-NING X U, CONG C, QING-KE L I, et al. Analysis of PM2.5 and PM10 pollution characteristics during heating period in Shenyang [J]. Journal of Engineering for Thermal Energy and Power, 2017, 32(7): 121-125.
SILVA R A, ADELMAN Z, FRY M M, et al. The impact of individual anthropogenic emissions sectors on the global burden of human mortality due to ambient air pollution [J]. Environmental Health Perspectives, 2016, 124(11): 1776-1784.
LOU Diming, ZHANG Jiuyang, TAN Piqiang, et al. Emission test and analysis of biodiesel produced by ships burning B10 cooking waste oil [J]. Environmental Engineering, 2020, 38(2): 86-90.
MEI Deqing, WANG Zhong, YUAN Yinnan, et al. Analysis of particle characteristics of biodiesel in diesel engine exhaust [J]. Journal of Agricultural Engineering, 2006(12): 113-116.
CHUEPENG S, XU Hongming, TSOLAKIS A, et al. Particulate matter size distribution in the exhaust gas of a modern diesel engine fuelled with a biodiesel blend [J]. Biomass and Bioenergy, 2011, 35(10): 4280-4289.
POPOVICHEVA O, ENGLING G, LIN Kuanting, et al. Diesel/biofuel exhaust particles from modern internal combustion engines: microstructure, composition, and hygroscopicity [J]. Fuel, 2015, 157: 232-239.
HU Zhiyuan, ZHANG Haochen, TAN Piqiang, et al. Emission characteristics of soluble organic fraction and polycyclic aromatic hydrocarbons from a diesel bus fueled with waste cooking oil-based biodiesel blends [J]. Journal of Tongji University(Natural Science), 2019, 47(7): 1046-1054.
YE Peng, BOEHMAN A L. An investigation of the impact of injection strategy and biodiesel on engine NOx and particulate matter emissions with a common-rail turbocharged DI diesel engine [J]. Fuel, 2012, 97: 476-488.
狄亚格, CHEUNG C S. 生物柴油掺烧比对柴油机颗粒物排放影响的试验研究 [J]. 现代车用动力, 2020(2): 38-41.
DI Yage, CHEUNG C S. Experimental study on the effect of biodiesel blending ratio on particulate matter emission of diesel engine [J]. Modern Vehicle Power, 2020(2): 38-41.
LUO Kun, LI Yaoting, HUANG Yongcheng, et al. Fuel properties and combustion/emission characteristics of the extracted liquid from bio-oil by biodiesel [J]. Journal of Xi'an Jiaotong University, 2019, 53(11): 34-41.
SHI Xiaoyan, HE Kebin, ZHANG Jie, et al. Effects of oxygenated fuels on emissions and carbon composition of fine particles from diesel engine [J]. Chinese Journal of Environmental Science, 2009, 30(6): 1561-1566.
CHOI C, BOWER G, REITZ R. Effects of biodiesel blended fuels and multiple injection on D.I. diesel engine [J]. SAE Transactions, 1997, 106: 388-407.
陈鬃. 柴油机颗粒物分形维数与碳组分的研究 [D]. 镇江: 江苏大学, 2016.
GOPINATH A, SAIRAM K, VELRAJ R, et al. Effects of the properties and the structural configurations of fatty acid methyl esters on the properties of biodiesel fuel: a review [J]. Proceedings of the Institution of Mechanical Engineers: Part D Journal of Automobile Engineering, 2015, 229(3): 357-390.
VANHOVE G, RIBAUCOUR M, MINETTI R. On the influence of the position of the double bond on the low-temperature chemistry of hexenes [J]. Proceedings of the Combustion Institute, 2005, 30(1): 1065-1072.
HU Zhiyuan, LIN Jianjun, TAN Piqiang, et al. NEDC particle number and size emission characters of a diesel car fueled with biodiesel blends in laboratory [J]. Journal of Tongji University(Natural Science), 2012, 40(6): 937-941.
SCHÖNBORN A, LADOMMATOS N, WILLIAMS J, et al. The influence of molecular structure of fatty acid monoalkyl esters on diesel combustion [J]. Combustion and Flame, 2009, 156(7): 1396-1412.
程远. 含碳气溶胶采样与分析方法研究 [D]. 北京: 清华大学, 2011.
BIAN Qijing, ALHARBI B, SHAREEF M M, et al. Sources of PM2.5 carbonaceous aerosol in Riyadh, Saudi Arabia [J]. Atmospheric Chemistry and Physics, 2018, 18(6): 3969-3985.
HUANG Rui, TAN Jing, LIU Qiongyu. Determination of organic and elemental carbon in fine particulate matters(PM2.5)[J]. Journal of Jianghan University(Natural Sciences), 2016, 44(1): 11-17.