Effect of Amorphous TiB<sub>2</sub>@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH<sub>4</sub>

doi:10.7652/xjtuxb202101002

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Effect of Amorphous TiB₂@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH₄

更新时间：2025-07-09

- Effect of Amorphous TiB₂@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH₄
- Vol. 55, Issue 1, Pages: 10-16(2021)
- 作者机构：
  
  宁夏大学物理与电子电气工程学院,银川,750021
- 作者简介：
- 基金信息：
- DOI：10.7652/xjtuxb202101002
  CLC： TG139.7
- Online First：10 January 2021，
  
  Published：2021
- 稿件说明：
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Effect of Amorphous TiB₂@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH₄[J]. 2021, 55(1): 10-16. DOI: 10.7652/xjtuxb202101002.
DOI：

Effect of Amorphous TiB₂@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH₄[J]. 2021, 55(1): 10-16. DOI: 10.7652/xjtuxb202101002. DOI：

摘要

为了提高NaAlH

的吸放氢动力学性能

采用球磨烧结两步法制备了非晶态TiB

和C复合催化剂(简写为TiB

@C)

并系统地研究了TiB

@C对NaAlH

合成和储氢性能的影响。研究结果表明

以NaH和Al为原料

添加质量分数为6%的TiB

@C作为复合催化剂

在室温、5 MPa氢压下进行球磨成功制备出NaAlH

。相对于球磨后的纯NaAlH

复合体系的起始放氢温度、三步放氢过程的峰值温度和前两步放氢过程的表观活化能均大幅降低。吸放氢测试结果显示

TiB

@C能够有效地改善NaAlH

的吸放氢动力学性能

且复合体系在10次吸氢循环过程中表现出优异的循环稳定性。这一系列性能的改善主要源于TiB

@C催化剂中TiB

和C的协同催化效应。

Abstract

To improve the hydrogenation/dehydrogenation kinetics ofNaAlH

an amorphousTiB

@C catalyst was prepared by a two-step process

and the effect of this catalyst on the synthesis and reversible hydrogen storage performance ofNaAlH

was systematically studied. Results show thatTiB

@C can catalyze the synthesis ofNaAlH

by usingNaH and Al as raw materials through a ball milling procedure at room temperature under 5 MPa hydrogen pressure. Compared with as-milled pureNaAlH

the desorption temperature and apparent activati

on energy of the as-preparedNaAlH

-6%TiB

@C are dramatically reduced. Moreover

this composite shows obviously increased hydrogen absorption/desorption kinetics and excellent cycling stability during 10 hydrogen absorption/desorption cycles. The improvements of the synthesis and reversible hydrogen storage performances ofNaAlH

are mainly due to the synergistic catalytic effect ofTiB

and C inTiB

@C catalyst.

关键词

Keywords

references

周超, 王辉, 欧阳柳章, 等. 高压复合储氢罐用储氢材料的研究进展 [J]. 材料导报, 2019, 33(1): 117-126.

ZHOU Chao, WANG Hui, OUYANG Liuzhang, et al. Research progress of hydrogen storage materials for high pressure hybrid tanks [J]. Material Review, 2019, 33(1): 117-126.

WANG Yanran, CHEN Xiaowei, ZHANG Hongyu, et al. Heterostructures built in metal hydrides for advanced hydrogen storage reversibility [J]. Advanced Materials, 2020, 32(31): 2002647.

SCHNEEMANN A, WHITE J L, KANG S, et al. Nanostructured metal hydrides for hydrogen storage [J]. Chemical Reviews, 2018, 118(22): 10775-10839.

KOJIMA Y. Hydrogen storage materials for hydrogen and energy carriers [J]. International Journal of Hydrogen Energy, 2019, 44(33): 18179-18192.

LIU Yongfeng, REN Zhuanghe, ZHANG Xin, et al. Development of catalyst-enhanced sodium alanate as an advanced hydrogen-storage material for mobile applications [J]. Energy Technology, 2018, 6(3): 487-500.

ZHANG Xin, REN Zhuanghe, LU Yunhao, et al. Facile synthesis and superior catalytic activity of Nano-TiN@N-C for hydrogen storage in NaAlH4 [J]. ACS Applied Materials and Interfaces, 2018, 10(18): 15767-15777.

武汪洋, 方方, 孙大林. 有序介孔碳球阵列约束下NaAlH4的脱/加氢性能 [J]. 复旦学报(自然科学版), 2018, 57(1): 14-21.

WU Wangyang, FANG Fang, SUN Dalin. Dehydrogenation/hydrogenation of NaAlH4 under the constraint of ordered mesoporous carbon sphere array [J]. Journal of Fudan University(Natural Science), 2018, 57(1): 14-21.

MUSTAFA N S, HALIM Y F A, YAHYA M S, et al. The hydrogen storage properties and reaction mechanism of the NaAlH4 + Ca(BH4)2 composite system [J]. International Journal of Hydrogen Energy, 2018, 43(24): 11132-11140.

BOGDANOVIXC B, SCHWICKARDI M. Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials [J]. Journal of Alloys and Compounds, 1997, 253/254: 1-9.

SANDROCK G, GROSS K, THOMAS G, et al. Engineering considerations in the use of catalyzed sodium alanates for hydrogen storage [J]. Journal of Alloys and Compounds, 2002, 330/331/332: 696-701.

WANG Ping, KANG Xiangdong, CHENG Huiming. Improved hydrogen storage of TiF3-doped NaAlH4 [J]. Chemphyschem, 2005, 6(12): 2488-2491.

ZHANG Xin, REN Zhuanghe, ZHANG Xuelian, et al. Triggering highly stable catalytic activity of metallic titanium for hydrogen storage in NaAlH4 by preparing ultrafine nanoparticles [J]. Journal of Materials Chemistry: A, 2019, 7(9): 4651-4659.

LI Li, WANG Ying, QIU Fangyuan, et al. Reversible hydrogen storage properties of NaAlH4 enhanced with TiN catalyst [J]. Journal of Alloys and Compounds, 2013, 566: 137-141.

LI Li, QIU Fangyuan, WANG Ying, et al. Improved dehydrogenation performances of TiB2-doped sodium alanate [J]. Materials Chemistry and Physics, 2012, 134(2): 1197-1202.

邱昊辰, 米菁, 王吉宁, 等. Ti31Cr15.5V45Fe8.5Ce0.5对CeH2掺杂NaAlH4放氢动力学的影响 [J]. 金属功能材料, 2019, 26(3): 36-40.

QIU Haochen, MI Jing, WANG Jining, et al. Effect of Ti31Cr15.5V45Fe8.5Ce0.5 on the dehydrogenation kinetics of CeH2 doped NaAlH4 [J]. Metal Functional Materials, 2019, 26(3): 36-40.

ZHANG Xin, LIU Yongfeng, WANG Ke, et al. Remarkably improved hydrogen storage properties of nanocrystalline TiO2-modified NaAlH4 and evolution of Ti-containing species during dehydrogenation/hydrogenation [J]. Nano Research, 2015, 8(2): 533-545.

CHENG Honghui, XU Linhua, FAN Xiaolu, et al. Synergistic effects played by CMK-3 and NbF5 co-additives on de/re-hydrogenation performances of NaAlH4 [J]. International Journal of Hydrogen Energy, 2018, 43(20): 9705-9712.

ISAGAWA K, SANO H, HATTORI M, et al. Catalytic hydroboration of olefins by use of titanium complex as catalyst [J]. Chemistry Letters, 1979, 8(9): 1069-1072.

BOGDNOVI B, BRAND R A, MARJANOVI A, et al. Metal-doped sodium aluminium hydrides as potential new hydrogen storage materials [J]. Journal of Alloys and Compounds, 2000, 302(1/2): 36-58.

PASKEVICIUS M, FILSØ U, KARIMI F, et al. Cyclic stability and structure of nanoconfined Ti-doped NaAlH4 [J]. International Journal of Hydrogen Energy, 2016, 41(7): 4159-4167.

LI Yongtao, FANG Fang, FU Hongliang, et al. Carbon nanomaterial-assisted morphological tuning for thermodynamic and kinetic destabilization in sodium alanates [J]. Journal of Materials Chemistry: A, 2013, 1(17): 5238-5246.

CHOI J, HA T, PARK J, et al. Mechanochemical synthesis of Ce3Al11 powder and its catalytic effect on the hydrogen sorption properties of NaAlH4 [J]. Journal of Alloys and Compounds, 2019, 784: 313-318.

MUSTAFA N S, YAHYA M S, SAZELEE N, et al. Dehydrogenation properties and catalytic mechanism of the K2NiF6-doped NaAlH4 system [J]. ACS Omega, 2018, 3(12): 17100-17107.

BERSETH P A, HARTER A G, ZIDAN R, et al. Carbon nanomaterials as catalysts for hydrogen uptake and release in NaAlH4 [J]. Nano Letters, 2009, 9(4): 1501-1505.

曹志杰,马晓波.Mo部分替代Ti对V40Ti50Fe10合金储氢性能的影响.2019,53(9):137-144.[~10.7652/xjtuxb201909 018]

曹鑫鑫,杨福胜,吴震,等.机械合金化Mg2Ni储氢材料的吸氢动力学实验研究.2013,47(5):44-50.[~10.7652/xjtuxb201305008]

杜建伟,李栋梁,陈玉凤,等.II型二元氢气水合物相边界条件测定及分解焓计算.2011,45(9):79-83.[~10.7652/xjtuxb201109015]

苗鹤,刘永锋,高明霞,等.Co替代Ni对钛钒基储氢电极合金循环稳定性的影响.2008,42(5):630-633.[~10.7652/xjtuxb200805026]

庄鹏辉,刘晓鹏,李志念,等.球磨时间对TiZr氢化物掺杂NaAlH4储放氢性能的影响.2008,42(5):639-642.[~10.7652/xjtuxb200805028]

贝雅耀,王新华,潘洪革,等.LiAlH4/LiNH2复合材料的储氢特性及其机理研究.2008,42(5):643-646.[~10.7652/xjtuxb200805029]

裴沛,宋西平,惠希东,等.V-Ti-Cr系储氢合金吸氢动力学机制研究.2008,42(4):501-504.[~10.7652/xjtuxb200804 026]

郑青榕,顾安忠,蔡振雄,等.氢分子在活性炭上的吸附特性分析.2008,42(4):505-508.[~10.7652/xjtuxb200804027]

韩树民,李媛,张忠,等.Ni/MH电池负极用高容量稀土-镁-镍基储氢合金.2008,42(3):377-380.[~10.7652/xjtuxb 200803027]

孙泰,黄存可,董汉武,等.球磨处理对LiAlH4放氢动力学的影响.2008,42(5):256-260.[~10.7652/xjtuxb200802 029]

刘广成,王春涛,葛红卫,等.Mg+10%TiFe1-xCrx(x=0,0.3)复相合金的储氢特性.2008,42(1):119-122.[~10.7652/xjtuxb200801027]

罗翔,郑坊平,王春涛,等.添加Ti0.9Zr0.1Mn1.5复合球磨对Ti9.6V86.4Fe4合金储氢性能的影响.2007,41(12):1491-1494.[~10.7652/xjtuxb200712024]

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⁰

Effect of Amorphous TiB2@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH4

DOI：10.7652/xjtuxb202101002

摘要

Abstract

关键词

Keywords

references

Effect of Amorphous TiB₂@C Catalyst on the Synthesis and Reversible Hydrogen Storage Performances of NaAlH₄