Graphene oxide films are prepared in situ by the ultraviolet light and the ozone(UVO)method and then combined with a two-terminal electronic device to construct gas sensing sensors with high performance. The sensitivity
time response
selectivity and retention rate of the graphene oxide gas sensing sensor to NH
3
are tested. Results show that the graphene oxide gas sensing sensor obtained by the UVO method has fast response speed
good recovery performance and nigh stability. The processing parameters such as UVO treatment time have significant influences on the performance of the graphene oxide gas sensing sensor. When the time of UVO process is 7 min
the sensitivity of the graphene oxide gas sensing sensor to NH
3
reaches the maxi
mum
and power consumption is low(test power is less than 1 mW)and the long-term retention rate is nigh. The sensor shows obvious selectivity for NH
3
compared with acetone and absolute ethanol. Graphene oxide prepared by the UVO method has less pollution to devices than that by the chemical method. The patterning process of graphene oxide film is compatible with the integrated circuit manufacturing process.
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Keywords
references
TIMMER B, OLTHUIS W, VAN A, et al. Ammonia sensors and their applications: a review [J]. Sensors and Actuators: B Chemical, 2005, 107(2): 666-677.
NIU Mengnian. The present and future of semiconductor field-effect gas sensors [J]. Sensor Transducer Technology, 1993(3): 6-11.
NAGELLI E, NAIK R, XUE Y, et al. Sensor arrays from multicomponent micropatterned nanoparticles and graphene [J].Nanotechnology, 2013,24(44): 444010.
YANG Guohai, LI Yongjie, RANA R K, et al. Pt-Au/nitrogen-doped graphene nanocomposites for enhanced electrochemical activities [J]. Journal of Materials Chemistry: A, 2013, 1(5): 1754-1762.
YU Lingzhu, SONG Hongjie, TANG Yurong, et al. Controllable deposition of ZnO-doped SnO2 nanowires on Au/graphene and their application in cataluminescence sensing for alcohols and ketones [J]. Sensors Actuators B: Chemical, 2014, 203: 726-735.
WANG Xiaona, SUN Xiuling, ZHANG Jia, et al. Colorimetric sensor based on self-assembled polydiacetylene/graphene-stacked composite film for vapor-phase volatile organic compounds [J]. Advanced Functional Materials, 2013, 23(48): 6044-6050.
YOO S, LI X, WU Y, et al. Ammonia gas detection by tannic acid functionalized and reduced graphene oxide at room temperature [J]. Journal of Nanomaterials, 2014(7): 1-6.
KEI T, RYO F, SHINYA H, et al. Recent progress in application of graphene oxide for gas sensing: a review [J]. Analytica Chimica Acta, 2015, 878(9): 43-53.
SONG Hui, LI Xin, CUI Ping, et al. Sensitivity investigation for the dependence of monolayer and stacking graphene NH3 gas sensor [J]. Diamond Related Materials, 2017, 73: 56-61.
LI Xin, ZHANG Juan, LI Quanfu, et al. A controllable preparation method for IC-oriented large scale single crystal graphene [J]. Journal of Xi'an Jiaotong University, 2014, 48(6): 103-109.
SUN Hongyan, CHEN Ding, WU Yuming, et al. High quality graphene films with a clean surface prepared by an UV/ozone assisted transfer process [J]. Journal of Materials Chemistry: C, 2017, 5(8): 1880-1884.
HOU Shuyong, HU Zhubin, GUAN Fuxin, et al. Effect of ozone treatment on gas-sensitivity of graphene-based NO2 gas sensor [J]. Transducer and Microsystem Technologies, 2014, 33(8): 15-17.
BAI Shouli, ZHAO Yangbo, SUN Jianhua, et al. Ultrasensitive room temperature NH3 sensor based on a graphene-polyaniline hybrid loaded on PET thin film [J]. Chemical Communications, 2015, 51(35): 7524-7527.
YANG C M, CHEN T, YANG Y C, et al. Ultraviolet illumination effect on monolayer graphene-based resistive sensor for acetone detection [J]. Vacuum, 2017, 140: 89-95.
CHUNG M G, KIM D H, LEE H M, et al. Highly sensitive NO2 gas sensor based on ozone treated graphene [J]. Sensors and Actuators: B Chemical, 2012, 166/167(6): 172-176.