Polycyclic aromatic hydrocarbons(PAHs)emitted from a gasoline direct injection(GDI)engine during start were extracted via Soxhlet extraction system and analyzed by GS-MS. Three kinds of fuel
gasoline
gasoline blended with 10% volume fraction ethanol(E10)
and gasoline blended with 15% volume fraction methanol(M15)
were considered. The results show that compared with gasoline
PAHs mass concentration of the exhaust extraction from the engine fueled with E10 decreases by 39.03% and 23.78% under 20 ℃ and 80 ℃ coolant start conditions
respectively; PAHs mass concentration from the engine fueled with M15 decreases by 30.17% and 66.06%
respectively. Toxicity of PAHs was assessed under different coolant's temperature start conditions. Under 20 ℃ coolant start condition
benzo(a)pyrene equivalent toxicity values of PAHs from the engine fueled with E10 and M10 decrease by 23.25% and 21.47% compared with gasoline; under 80 ℃ coolant start condition
benzo(a)pyrene equivalent toxicity values of PAHs from the engine fueled with E10 and M10 decrease by 33.26% and 50.46% compared with gasoline. In contrast to 20 ℃ coolant start condition
benzo(a)pyrene equivalent toxicity values of PAHs from the engine fueled with gasoline
E10 and M15 decrease the values by 44.25%
50.80% and 64.84% respectively under 80 ℃ coolant start condition.
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references
BRAISHER M, STONE R, PRICE P. Particle number emissions from a range of European vehicles: SAE 2010-01-0786 [R]. Washington, DC, USA: SAE, 2010.
GAUDERMAN W J, URMAN R. Association of improved air quality with lung development in children [J]. England Journal of Medicine, 2015, 372(10): 905-913.
RAVINDRA K, SOKHI R, van GRIEKEN R. Atmospheric polycyclic aromatic hydrocarbons: source attribution, emission factors and regulation [J]. Atmos Environ, 2008, 42(13): 2895-2921.
VOJTISEK-LOM M, PECHOUT M, DITTRICH L, et al. Polycyclic aromatic hydrocarbons(PAH)and their genotoxicity in exhaust emissions from a diesel engine during extended low-load operation on diesel and biodiesel fuels [J]. Atmos Environ, 2015, 109: 9-18.
BAKEAS E, KARAVALAKIS G, FONTARAS G, et al. An experimental study on the impact of biodiesel origin on the regulated and PAH emissions from a Euro 4 light-duty vehicle [J]. Fuel, 2011, 90(11), 3200-3208.
MARK S P, ALEX F. Study of particle number emissions from a turbocharged gasoline direct injection(GDI)engine including data from a fast-response particle size spectrometer: SAE 2011-01-1224 [R]. Washington, DC, USA: SAE, 2011.
WHELAN I, SMITH W. The effect of engine operating conditions on engine-out particulate matter from a gasoline direct-injection engine during cold-star: SAE 2012-01-1711 [R]. Washington, DC, USA: SAE, 2012.
CHEN L F, BRAISHER M. The influence of ethanol blends on particulate matter emissions from gasoline direct injection engines: SAE 2010-01-0793 [R]. Washington, DC, USA: SAE, 2010.
LIANG B, GE Y S. Comparison of PM emissions from a gasoline direct injected(GDI)vehicle and a port fuel injected(PFI)vehicle measured by electrical low pressure impactor(ELPI)with two fuels: gasoline and M15 methanol gasoline [J]. Journal of Aerosol Science, 2013, 57: 22-31.
LI Xiang, PEI Yiqiang, QIN Jing, et al. Investigation on particulate matter emission of GDI engine fueled with methanol and gasoline-methanol blends [J]. Chinese Internal Combustion Engine Engineering, 2015, 36(2): 1-6.
LI Fangcheng, LI Su, BAI Honglin, et al. Formation mechanism of polycyclic aromatic hydrocarbons in gasoline engine [J]. Journal of Combustion Science and Technology, 2010, 16(3): 210-214.
ZHAO Changpu, CHEN Shengqi, SONG Chonglin, et al. PAHs formation mechanism in n-heptane premixed flame [J]. Journal of Combustion Science and Technology, 2008, 14(5): 400-405.
HU Qixiu, ZHAO Jijun, JIANG Jinfeng, et al. Study on the formation mechanism of polycyclic aromatic hydrocarbons based on free radical reaction [J]. Journal of Sichuan Continuing Education College of Medical Sciences, 2009, 28(1): 33-35.
ZHENG Dong, ZHONG Beijing. Characteristics and kinetic analysis of soot formation for representative species of gasoline in premixed flame [J]. Journal of Combustion Science and Technology, 2015, 21(2): 131-134.
WANG Chao, DAO Xu, ZHANG Linlin, et al. Characteristics and toxicity assessment of airborne particulate polycyclic aromatic hydrocarbons of four background sites in China [J]. China Environmental Science, 2015, 35(12): 3543-3549.
ROBERT E, BRIAN G B, JOSEPHY P D, et al. Comparison of the Ames salmonella assay and Mutatox genotoxicity assay for assessing the mutagenicity of polycyclic aromatic compounds in porewater from Athabasca oil sands mature fine tailings [J]. Environ Sci Technol, 1999, 33(15): 2510-2516.
NISBET C, LAGOY P. Toxic equivalency factor(TEFs)for polycyclic aromatic hydrocarbons(PAHs)[J]. Regulatory Toxicology and Pharmacology, 1992, 16(3): 290-300.
TAN Piqiang, RUAN Shuaishuai, HU Zhiyuan, et al. Particle-bound PAHs emission from a heavy duty diesel engine with biodiesel fuel: SAE 2013-01-2573 [R]. Washington, DC, USA: SAE, 2013.