Experimental Study on ETSS Coupling Mechanism and Identification of Key Parameter for Lithium-Ion Batteries[J]. 2017, 51(8): 142-148.
DOI:
Experimental Study on ETSS Coupling Mechanism and Identification of Key Parameter for Lithium-Ion Batteries[J]. 2017, 51(8): 142-148.DOI: 10.7652/xjtuxb201708023.
Experimental Study on ETSS Coupling Mechanism and Identification of Key Parameter for Lithium-Ion Batteries
The coupling mechanism of ETSS fields(electro-chemical field
temperature field and strain-stress field)is a hot spot in the lithium-ion battery design and management researches. A novel instrument is designed to simultaneously obtain the thermal
electric and mechanical behaviors of the battery under charge and discharge operations and to further ascertain the characteristics in both spatial and temporal domains. Conclusion is drawn that the battery deformation curve has an obvious piecewise characteristic related to SOC(state of charge)
and can be used to aid in the modification of the SOC estimation method for LiFePO
4
battery. Based on the test results
the mechanism of battery deformation under charge and discharge is further investigate
d and the key parameter of thermal expansion coefficient is identified. The result shows that when discharge is at a high rate
the battery expands during the initial and middle stages
then shrinks during the final stage in the edge area
while battery shrinks during the initial and middle stages and expands during the final stage in the center area
and that when discharge is at a low rate
the battery shrinks during the initial and middle stages but expands in the final stage in both the edge and the center areas. These results may provide a basis for theoretical analysis
testing and management of battery ETSS fields.
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references
RAMADESIGAN V. Modeling and simulation of lithium-ion batteries from a systems engineering perspective [J]. Journal of the Electrochemical Society, 2012, 159(3): 31-37.
KIM U S, KIM C, SHIN C B. Effect of electrode configuration on the thermal behavior of a lithium-polymer battery [J]. Journal of Power Sources, 2008, 180(2): 909-916.
NORTHROP P W. Efficient simulation and reformulation of lithium-ion battery models for enabling electric transportation [J]. Journal of the Electrochemical Society, 2014, 161(8): 3149-3157.
ZHANG Xiangchun, SHYY W, SASTRY A M. Numerical simulation of intercalation-induced stress in li-ion battery electrode particles [J]. Journal of the Electrochemical Society, 2007, 154(12): A910-A916.
SALVADORI A, BOSCO E, GRAZIOLI D. A computational homogenization approach for Li-ion battery cells: part 1 Formulation [J]. Journal of the Mechanics and Physics of Solids, 2014, 65(4): 114-137.
CHRISTENSEN J, NEWMAN J. Stress generation and fracture in lithium insertion materials [J]. Journal of Solid State Electrochemistry, 2006, 10(5): 293-319.
GOLMON S, MAUTE K, DUNN M L. Numerical modeling of electrochemical-mechanical interactions in lithium polymer batteries [J]. Computers and Structures, 2009, 87(23): 1567-1579.
RENGANATHAN S. Theoretical analysis of stresses in a lithium ion cell [J]. Journal of the Electrochemical Society, 2010, 157(2): A155.
WU Wei, XIAO Xinran, SHI Danghe. Heat transfer and thermal stress in a lithium-ion battery [C]∥ Proceedings of the ASME 2010 International Mechanical Engineering Congress and Exposition. New York, USA: ASME, 2010: 343-351.
FU Rujian, XIAO Meng, CHOE S Y. Modeling, validation and analysis of mechanical stress generation and dimension changes of a pouch type high power Li-ion battery [J]. Journal of Power Sources, 2013, 224(4): 211-224.
CANNARELLA J, ARNOLD C B. Stress evolution and capacity fade in constrained lithium-ion pouch cells [J]. Journal of Power Sources, 2014, 245(1): 745-751.
CANNARELLA J, ARNOLD C B. State of health and charge measurements in lithium-ion batteries using mechanical stress [J]. Journal of Power Sources, 2014, 269(2): 7-14.
CHEN Chaoyang, WANG Yexi, ZHANG Jinjing. Graphite structure change in Li-ion battery processes [J]. Chinese Journal of Power Sources, 2010(6): 549-551.
ANDERSSON A S, KALSKA B, HAGGSTROM L, et al. Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mössbauer spectroscopy study [J]. Solid State Ionics, 2000, 130(1/2): 41-52.
PRUSSIN S. Generation and distribution of dislocations by solute diffusion [J]. Journal of Applied Physics, 1961, 32(10): 1876-1881.
GAO Jian, LV Yingchun, LI Hong. Fundamental scientific aspects of lithium batteries: IV Phase transition and phase diagram: 2 [J]. Energy Storage Science and Technology, 2013(4): 383-401.
DAHN J R. Phase diagram of LixC6 [J]. Physical Review: B, 1991, 44(17): 9170-9177.
SRINIVASAN V, NEWMAN J. Discharge model for the lithium iron-phosphate electrode [J]. Journal of the Electrochemical Society, 2004, 151(10): A1517-A1529.