Surface Analysis of Ti/Sb-SnO<sub>2</sub> Electrode after Electrolysis

doi:10.7652/xjtuxb201402016

您当前的位置：

首页 >

文章列表页 >

Surface Analysis of Ti/Sb-SnO₂ Electrode after Electrolysis

更新时间：2025-07-09

- Surface Analysis of Ti/Sb-SnO₂ Electrode after Electrolysis
- Vol. 48, Issue 2, Pages: 93-98(2014)
- 作者机构：
  
  西安交通大学环境科学与工程系,西安,710049
- 作者简介：
- 基金信息：
- DOI：10.7652/xjtuxb201402016
  CLC： TQ150
- Online First：10 February 2014，
  
  Published：2014
- 稿件说明：
移动端阅览
Surface Analysis of Ti/Sb-SnO₂ Electrode after Electrolysis[J]. 2014, 48(2): 93-98. DOI: 10.7652/xjtuxb201402016.
DOI：

Surface Analysis of Ti/Sb-SnO₂ Electrode after Electrolysis[J]. 2014, 48(2): 93-98. DOI: 10.7652/xjtuxb201402016. DOI：

摘要

针对电极表面发生电化学反应而影响电极稳定性的问题

研究了0.1 mol·L

-1

的Na

溶液中以5×10

-3

A·cm

-2

恒电流电解300 h后Ti/Sb-SnO

电极表面状态的变化

同时采用扫描电镜、元素分析和X射线衍射检测了该表面的状态

用电感耦合等离子体发射光谱仪检测了电解后溶液中的金属含量。结果表明:经长时间电解后的Ti/Sb-SnO

电极表面出现了氧化物层局部溶解及脱落的情况; 电解完成后的溶液中检测到Sn元素; 电极表层的物质仍为Sb-SnO

但衍射峰强度有所降低

Ti峰强度大幅度升高。由此推测

表层氧化物层的溶解、局部区域的脱落以及基底与表面层之间的钝化可能是造成Ti/Sb-SnO

电极在长时间使用后失稳的主要原因。该结果可为改善Ti/Sb-SnO

电极表面形貌、提高表层氧化物负载量和电极稳定性研究提供参考。

Abstract

The change in the surface morphology in electrochemical processes can directly affect the stability of the electrode. Ti/Sb-SnO

the target electrode

was electrolyzed in the Na

solution(0.1 mol·L

-1

)under constant current density condition(5×10

-3

A·cm

-2

)for 300 h. scanning electron microscope

energy dispersive spectrometer and X-ray diffraction(XRD)were used to determine the change in the surface morphology. Inductively coupled plasma optical emission spectrometry was used to determine the metal content in the electrolyte. Then the possible reason for the deactivat

ion of the Ti/Sb-SnO

electrode after long time running was proposed. The SEM results show that the surface layer of the Ti/Sb-SnO

electrode was partially dissolved and some parts were even detached from the titanium base after electrolysis. The Sn element was detected in the electrolyte after electrolysis

suggesting that Sb-SnO

was indeed dissolved in the electrolyte. The XRD analysis indicates that the surface layer was still Sb-SnO

but the diffraction peak intensity decreased. It appears that the anode deactivation may result from the dissolution and detachment of the oxide layer and the passivation of substrate. The result can be useful for the enhancement of the electrode stability.

关键词

Keywords

references

RAJESHWAR K, IBANEZ J G, SWAIN G M. Electrochemistry and the environment[J]. Journal of Applied Electrochemistry, 1994, 24(11): 1077-1091.

MARTINEZ-HUITLE C A, FERRO S. Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect process[J]. Chemistry Society Reviews, 2006, 35(12): 1324-1340.

MARTINEZ-HUITLE C A, BRILLAS E. Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: a general review[J]. Applied Catalysis: B Environmental, 2009, 87(3/4): 105-145.

MARCO P, GIACOMO C. Direct and mediated anodic oxidation of organic pollutants[J]. Chemical Review, 2009, 109(12): 6541-6569.

孔德生, 吕文华, 冯媛媛, 等. DSA电极电催化性能研究及尚待深入探究的几个问题[J]. 化学进展, 2009, 21(6): 1107-1117.

KONG Desheng, LU Wwenhua, FENG Yuanyuan, et al. Advances and some problems in electrocatalysis of DSA electrodes[J]. Progress in Chemistry, 2009, 21(6): 1107-1117.

LI Xiaohong, PLETCHER D, WALSH F C. Electrodeposited lead dioxide coatings[J]. Chemical Society Reviews, 2011, 40(7): 3879-3894.

张招贤. 钛电极工学[M]. 第2版. 北京: 冶金工业出版社, 2003.

SO Y Y, YEON S C, KIM S, et al. Boosting the electrocatlytic activities of SnO2 electrodes for remediation of aqueous pollutants by doping with various metals[J]. Applied Catalysis: B Environmental, 2012, 111/112(12): 317-325.

LI Peiqiang, ZHAO Guohua, CUI Xiao, et al. Constructing stake structured TiO2-NTs/Sb-doped SnO2 electrode simultaneously with high electrocatalytic and photocatalytic performance for complete mineralization of refractory aromatic acid[J]. Journal of Physic and Chemistry: C, 2009, 113(6): 2375-2383.

ADAMS B, TIAN M, CHEN A C. Design and electrochemical study of SnO2-based mixed oxide electrodes[J]. Electrochimica Acta, 2009, 54(5): 1491-1498.

FENG Yujie, CUI Yuhong, LIU Junfeng, et al. Factors affecting the electro-catalytic characteristics of Eu doped SnO2/Sb electrode[J]. Journal of Hazardous Materials, 2010, 178(1/2/3): 29-34.

SHAHRAM G, MIR F M, MOITABA S. Electrochemical deposition of lead dioxide in the presence of polyvinylpyrrolidone: a morphological study[J]. Electrochimica Acta, 2007, 53(2): 459-467.

徐浩, 延卫, 游莉. 不同酸处理对钛基体性能的影响研究[J]. 稀有金属材料与工程, 2011, 40(9): 1550-1554.

XU Hao, YAN Wei, YOU Li. Effects of various acids treatment on the properties of titanium substrate[J]. Rare Metal Materials and Engineering, 2011, 40(9): 1550-1554.

KONG Haishen, LU Haiyan ZHANG Wenli, et al. Performance characterization of Ti substrate lead dioxide electrode with different solid solution interlayers[J]. Journal of Material Science, 2012, 47(18): 6709-6715.

DING Haiyang, FENG Yujie, LIU Junfeng. Preparation and properties of Ti/SnO2-Sb2O5 electrodes by electrodeposition[J]. Materials Letters, 2007, 61(27): 4920-4923.

YAO Peidong, JIN Qiannan, CHEN Xueming, et al. Ti/SnO2-Sb electrodes for pollutant degradation prepared using ultrasonic spray pyrolysis[J]. Electrochemical and Solid-State Letters, 2008, 11(5): J37-J39.

HUANG Aisheng, ZHAO Guohua, LI Hongxu. High quality Sb-doped SnO2 electrodes with high oxygen evolution potential prepared by in situ hydrothermal synthesis method[J]. Chinese Chemical Letters, 2007, 18(8): 997-1000.

邹忠, 李杰, 丁凤其,等. 梯度功能型金属氧化物涂层阳极(DSA)的制备[J]. 功能材料, 2001, 32(4): 431-433.

ZOU Zhong, LI Jie, DING Fengqi, et al. Preparation of the functionally gradient metal oxide anode coating(DSA)[J]. Journal of Functional Materials, 2001, 32(4): 431-433.

XU Hao, YAN Wei, TANG Chengli. A novel method to prepare metal oxide electrode: spin-coating with thermal decomposition[J]. Chinese Chemical Letters, 2011, 22(3): 354-357.[20] XU Hao, TANG Chengli, ZHANG Qian, et al. A microwave approach to the preparation of Sb-doped SnO2electrode[J]. Journal of Inorganic Materials, 2012, 27(6): 667-672.

BERENGUER R, QUIJADA C, MORALLON E. Electrochemical characterization of SnO2 electrodes doped with Ru and Pt[J]. Electrochimica Acta, 2009, 54(22): 5230-5238.

CUI Yuhong, FENG Yujie, LIU Zhengqian. Influence of rare earths doping on the structure and electro-catalytic performance of Ti/Sb-SnO2 electrodes[J]. Electrochimica Acta, 2009, 54(21): 4903-4909.

崔玉虹, 冯玉杰, 刘峻峰. 含Mn中间层钛基二氧化锡电催化电极的性能[J]. 材料研究学报, 2005, 19(1): 47-53.

CUI Yuhong, FENG Yujie, LIU Junfeng. Performance of Ti-base SnO2 electrode with an inter layer containing Mn element[J]. Chinese Journal of Materials Research, 2005, 19(1): 47-53.

ZHAO Guohua, CUI Xiao, LIU Meichuan, et al. Electrochemical degradation of refractory pollutant using a novel microstructured TiO2 nanotubes/Sb-doped SnO2 electrode[J]. Environmental Science and Technology, 2009, 43(5): 1480-1486.

吴春,陈刚,彭勃.中温固体氧化物燃料电池LaNiO2.5-Ba(Zr0.1Ce0.7Y0.2)O3-δ阴极的制备和表征.2013,47(2):92-96.[doi:10.7652/xjtuxb201302016]

马扬洲,徐友龙,肖芳,等.影响脉冲电流法制备MnO2超级电容器电极性能的因素.2011,45(9):114-118.[doi:10.7652/xjtuxb201109021]

燕子鹏,蔡舒,武卫兵.电化学法制备p型Cu2O半导体薄膜及其性能的表征.2011,45(3):121-124.[doi:10.7652/xjtuxb201103023]

连芩,刘红忠,丁玉成,等.TiO2光阳极有序微结构的纳米压印工艺.2009,43(11):90-94.[doi:10.7652/xjtuxb2009110 19]

钞书哲,丁玉成,叶向东,等.电子束直写模版电沉积制备图案化磁记录介质.2009,43(3):27-30.[doi:10.7652/xjtuxb 200903006]

Liang F U,卢天健,J.K.LUO.一种微型锌/空气电池的开发.2008,42(7):791-754.[doi:10.7652/xjtuxb200807001]

苗鹤,刘永锋,高明霞,等.Co替代Ni对钛钒基储氢电极合金循环稳定性的影响.2008,42(5):630-633.[doi:10.7652/xjtuxb200805026]

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A Hybrid-Topology Overlay Network for Supporting Large-Scale Application-Level Multicast

Dynamics in the Evolution of Spherical Micro-Bubble in Water and Its Control

Effect of Control Delay on Dynamic Characteristics of Negative Stiffness Duffing System

Model for Cable-in-Conduit Conductor(CICC) Design Considering Strain Effect

Dynamic Backup Multipath Routing for Improving Route Stability in Mobile Ad Hoc Networks

Related Author

2 董巍 1

刘晓 1

郑庆华 1

姜山 1

任晟 1

张家忠 1

Related Institution

Ministry of Education Key Lab for Intelligent Networks and Network Security, Xi'an Jiaotong University

Department of Computer Science and Technology, Xi'an Jiaotong University

School of Energy and Power Engineering, Xi'an Jiaotong University

Institute of Mechatronics and Information System, Xi'an Jiaotong University

School of Information Science and Engineering, Henan University of Technology

⁰

Surface Analysis of Ti/Sb-SnO2 Electrode after Electrolysis

DOI：10.7652/xjtuxb201402016

摘要

Abstract

关键词

Keywords

references

Surface Analysis of Ti/Sb-SnO₂ Electrode after Electrolysis