Experimental Investigation on Span20 Promoting Effect on Methane Hydrate Formation

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Experimental Investigation on Span20 Promoting Effect on Methane Hydrate Formation

更新时间：2025-07-09

- Experimental Investigation on Span20 Promoting Effect on Methane Hydrate Formation
- Vol. 42, Issue 9, Pages: 1165-1168(2008)
- 作者机构：
  
  1. 中国科学院广州能源研究所,广州,510640
  2. 中国科学院可再生能源与天然气水合物重点实验室,广州,510640
  3. 中国科学院研究生院,北京,100039
- 作者简介：
- 基金信息：
- DOI：
  CLC： TQ517.1
- Online First：10 September 2008，
  
  Published：2008
- 稿件说明：
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Experimental Investigation on Span20 Promoting Effect on Methane Hydrate Formation[J]. 2008, 42(9): 1165-1168.
DOI：

Experimental Investigation on Span20 Promoting Effect on Methane Hydrate Formation[J]. 2008, 42(9): 1165-1168. DOI：

摘要

在已有的天然气水合物储气实验台上

利用带磁力搅拌的141 mL高压反应釜

采用定压法

在温度为(274.15±0.10)K、压力为(8.30±0.10)MPa的条件下

从诱导时间、生成速率和储气密度等方面研究了非离子表面活性剂失水山梨醇单月桂酸酯(Span20)的质量分数为0～3%范围内对甲烷水合物生成的影响.结果发现:Span20的质量分数为0.2%时诱导时间最短

为53～167 min; 在0.4%时的生成速率最大

是纯水的10倍以上

同时其储气密度V/V

最大

达到145.2.通过分析Span20的分子结构

对表面活性剂促进甲烷水合物形成机理进行了研究

认为可能是Span20分子中带有2个羟基的类四氢呋喃结构的诱导作用以及假六元环的模板作用共同促进了甲烷水合物的形成.

Abstract

Experiments on the effect of non-ionic surfactant sorbitan monododecanoate(Span 20)on induction time

formation rate and gas storage density were conducted during methane hydrate formation in a high pressure reactor with a magnetic stir at(274.15±0.10)K

(8.30±0.10)MPa and 0-3%. The results show that the induction time with 0.2% Span 20 was shortest

53-167 minutes and a maximum formation rate was obtained with 0.4% Span 20

about 10 times the rate of pure water. Moreover

at 0.4% Span 20 also had the largest gas storage density of 145.2. On the basis of analysis on the Span 20 structure

the mechanism of surfactants promoting methane hydrate formation was investigated. It appears that the induction effect of tetrahydrofuranoid with two hydroxyls together with the template effect of the false hexahydroxy cycle may promote methane hydrate formation.

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Keywords

references

SLOAN E D. Clathrate hydrates of natural gases [M].2nd ed. New York,USA: Marcel Dekker Inc., 1998:24-110.

樊栓狮.天然气水合物储存与运输技术 [M].北京:化学工业出版社,2005.

孙志高,马荣生,郭开华,等.表面活性剂对甲烷水合物储气特性影响的实验研究 [J].西安交通大学学报,2003,37(7):723-725.

SUN Zhigao, MA Rongsheng, GUO Kaihua, et al.Experimental investigation of the effect of surfactants on storage properties of methane hydrates [J]. Journal of Xi'an Jiaotong University, 2003,37(7):723-725.

陈孝彦,何小社,何晓霞,等.天然气水合物生成动力学机理的研究 [J].西安交通大学学报,2004,38(1):85-88.

CHEN Xiaoyan, HE Xiaoshe, HE Xiaoxia, et al. Study on kinetics of natural gas hydrate formation [J]. Journal of Xi'an Jiaotong University, 2004,38(1):85-88.

KALOGERAKIS N, JAMALUDDIN A K M, DHOLABHAI P D, et al. Effect of surfactants on hydrate formation kinetic:SPE paper,25188 [R]. New Orleans, LA, USA: Society of Petroleum Engineers,1993: 375-383.

ZHONG Yu, ROGERS R E. Surfactant effects on gas hydrate formation [J]. Chemical Engineering Science, 2000, 55(19): 4174-4187.

KARAASLAN U,ULUNEYE E,PARLAKTUNA M. Effect of an anionic surfactant on different type of hydrate structures [J]. Journal of Petroleum Science and Engineering, 2002, 35(1/2):49-57.

ZHANG Chunsun, FAN Shuanshi, LIANG Deqing, et al. Effect of additives on formation of natural gas hydrate [J]. Fuel, 2004, 83(16):2115-2121.

GANJI H, MANTEGHIAN M, SADAGHIANI ZADEH K,et al. Effect of different surfactants on methane hydrate formation rate, stability and storage capacity [J]. Fuel, 2007, 86(3):434-441.

林微.水合物储存气体技术的相关基础研究 [D].北京:石油大学化工学院,2005.

HUO Zhongxin, FREER E, LAMAR M, et al. Hydrate plug prevention by anti-agglomeration [J]. Chemical Engineering Science, 2001, 56(13):4979-4991.

CHRISTIANSEN R L, SLOAN E D. Mechanisms and kinetics of hydrate formation [C]∥International Conference on Natural Gas Hydrates.New York,USA: Annals of New York Academy of Sciences,1994,715:283-305.

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