Study of Fixed Bed Reactor for Removing H<sub>2</sub>S by Ferric Oxide

您当前的位置：

首页 >

文章列表页 >

Study of Fixed Bed Reactor for Removing H₂S by Ferric Oxide

更新时间：2025-07-09

- Study of Fixed Bed Reactor for Removing H₂S by Ferric Oxide
- Vol. 44, Issue 5, Pages: 91-96(2010)
- 作者机构：
  
  1. 西安交通大学动力工程多相流国家重点实验室,西安,710049
  2. 西安交通大学能源与动力工程学院,西安,710049
- 作者简介：
- 基金信息：
- DOI：
  CLC： TQ051.5
- Online First：10 May 2010，
  
  Published：2010
- 稿件说明：
移动端阅览
Study of Fixed Bed Reactor for Removing H₂S by Ferric Oxide[J]. 2010, 44(5): 91-96.
DOI：

Study of Fixed Bed Reactor for Removing H₂S by Ferric Oxide[J]. 2010, 44(5): 91-96. DOI：

摘要

原油在储存、输运过程中会产生油气挥发和H

S气体逸出

对周围环境影响严重

为此提出了采用氧化铁吸附脱除原油挥发气中H

S的工艺.针对氧化铁吸附脱除原油挥发气中H

S的固定床脱硫反应器建立了数学模型

利用COMSOL软件进行了求解

模拟计算出不同条件下固定床脱硫反应器的穿透曲线

并与实验值进行了对照

同时进一步探讨了吸附容量的影响因素.研究结果表明:采用的氧化铁脱硫剂在空速为1 500 h

-1

至4 200 h

-1

的范围内

穿透硫容随着空速的降低而增加; 空速再度下降会导致穿透硫容减小; 穿透时间和穿透硫容随温度的升高而增大.另外

在相同空速下

进料H

S浓度的变化只改变穿透时间

不影响硫容的变化.

Abstract

Hydrogen sulfide gas could escape from storage tank area in the process of crude oil storage and transportation

which can pollute the surrounding environment. According to the characteristics of crude oil tank area

a process with fixed bed reactors for removing volatile gas H

S from the crude oil by ferric oxide was proposed in this study. In order to understand the desulfurization process

a mathematical model of the fixed bed desulfurization reactor was established and the simulation was performed by using the COMSOL software. The simulation result shows that the breakthrough curves under different conditions are in reasonable agreement with the experimental data. Moreover

the investigation into the effect on the adsorption capacity indicates that the breakthrough capacity of the ferric oxide desulfuriz

ing agent increases with the decrease of the space velocity in the range from 1 500 h

-1

to 4 200 h

-1

. If the space velocity decreases further

the breakthrough capacity decreases. The breakthrough time and capacity increase with the increase of the temperature. In addition

the variation of the input H

S concentration changes the breakthrough time

but it has no influence on the variation of sulfur capacity under the same space velocity condition.

关键词

Keywords

references

XIAO Yonghou, WANG Shudong, WU Diyong, et al. Catalytic oxidation of hydrogen sulfide over unmodified and impregnated activated carbon [J]. Separation and Purification Technology, 2008, 59(3): 326-332.

MEEYOO V, TRIMM D L. Adsorption-reaction processes for the removal of hydrogen sulphide from gas streams [J]. J Chem Tech Biotechnol,1997, 68(4): 411-416.

钟立梅.变压过程脱除气体中微量硫化氢的研究[D].天津: 天津大学化工学院, 2006.

李芬, 张杰, 姜安玺,等.低温脱硫剂的研究进展 [J]. 化工进展, 2007, 26(4): 519-525.

LI Fen, ZHANG Jie, JIANG Anyu, et al. Research progress of desulfurizer at a low temperature [J]. Chemical Industry and Engineering Process, 2007, 26(4): 519-525.

谢巍, 常丽萍, 余江龙,等.煤气净化中H2S干法脱除的研究进展 [J]. 化工学报, 2006, 57(9): 2012-2020.

XIE Wei, CHANG Liping, YU Jianglong, et al. Research progress of removal of H2S from coal gas by dry method [J]. Journal of Chemical Industry and Engineering, 2006, 57(9): 2012-2020.

LEE Y S, KIM H T, KYONG O. Effect of ferric oxide on the high temperature removal of hydrogen sulfide over ZnO-Fe2O3 mixed metal oxide sorbent [J]. Ind Eng Chem Res, 1995, 34(4): 1181-1188.

DAVYDOV A, CHUANG K T, SANGER A R. Mechanism of H2S oxidation by ferric oxide and hydroxide surfaces [J]. Phys Chem: B, 1998, 102(24):4745-4752.

胡典明, 王国兴, 魏华,等. EF-2 型特种氧化铁常温精脱硫剂的研制 [J]. 天然气化工, 1999, 24(2): 31-36.

HU Dianming, WANG Guoxing, WEI Hua, et al. Research and development of EF special oxide fine desulfurizer [J]. Natural Gas Chemical Engineering, 1999, 24(2): 31-36.

朱志敏, 姚虎卿, 李承涛. NF 型脱硫剂的吸附与常温空气再生特性 [J]. 南京化工大学学报, 2000, 22(2): 66-69.

ZHU Zhimin, YAO Huqing, LI Chengtao. Adsorption and regeneration characteristics of NF-desulfurizing agent [J]. Journal of Nanjing University of Chemical Technology, 2000, 22(2): 66-69.

李彦旭, 宋靖, 李春虎,等. 铁钙混合氧化物脱硫剂的硫化与再生过程研究 [J]. 高校化学工程学报, 2001, 15(2): 133-137.

LI Yanxu, SONG Jing, LI Chunhu, et al. A study of high temperature desulfurization and regeneration using iron-calcium oxides in a fixed-bed reactor [J]. Journal of Chemical Engineering of Chinese Universities, 2001, 15(2): 133-137.

沈芳, 李春虎, 上官炬, 等. 高温煤气铁系脱硫剂的研究 [J]. 煤炭转化, 2004, 27(2): 54-56.

SHEN Fang, LI Chunhu, SHANG Guanju, et al. Study on iron oxide desulfurizer of hot gas desulfurization [J]. Coal Conversion, 2004, 27(2): 54-56.

TSENG T K, CHANG H C, CHUA H. Hydrogen sulfide removal from coal gas by the metal-ferrite sorbents made from the heavy metal wastewater sludge [J]. Journal of Hazardous Materials, 2008, 160(2/3), 482-488.

WANG Li, CAO Bin, WANG Shudong, et al. H2S catalytic oxidation on impregnated activated carbon: experiment and modeling [J]. Chemical Engineering Journal, 2006, 118(3): 133-139.

一种有限容积法中极点奇异单元的处理方法. 西安交通大学学报, 2010,44(3):95-99.

变负荷条件下的大型合成氨装置特性研究. 西安交通大学学报, 2009,43(10): 114-118.

中空纤维膜换热器传热传质特性的实验和理论研究. 西安交通大学学报, 2009,43(5):40-45.

水垢的电化学去除工艺与机理研究. 西安交通大学学报, 2009,43(5): 104-108.

在涂层催化剂上甲烷蒸汽重整的本征动力学研究. 西安交通大学学报, 2009,43(5):109-114.

中空纤维膜溶液热交换器的传热传质模拟研究. 西安交通大学学报, 2009,43(3): 36-41.

一种改进的二氧化碳吸收减排法. 西安交通大学学报, 2008,42(11): 1413-1417.

溶胶-凝胶法制备La3+、碳纳米管掺杂纳米TiO2及光催化性能. 西安交通大学学报, 2008,42(10):1304-1308.

Span20促进甲烷水合物生成的实验研究. 西安交通大学学报, 2008,42(9):1165-1168.

Eosin敏化不同晶体结构TiO2的产氢性能研究. 西安交通大学学报, 2008,42(7):900-903.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Factors on Generation of Reducing Volatiles from Coal

Bi-Level Multi-Obj ective Optimization of a Wind-Solar Coupled Hydrogen Production System Based on the Synergy of Hybrid Electrolyzer Arrays

Numerical Simulation of the Energy Conversion Process in Thermoacoustic Engines with Different Stack Materials

Diffusion Characteristics and Influencing Factors in Case of Hydrogen Leakage from Fuel Cell Vehicles Running in Tunnels

Research on the Electrohydrodynamic Effects of Ionic Liquid-Modified Fuels

Related Author

刘艳华

张晓燕

刘银河

车得福

Related Institution

School of Energy and Power Engineering, Xi'an Jiaotong University

⁰

Study of Fixed Bed Reactor for Removing H2S by Ferric Oxide

DOI：

摘要

Abstract

关键词

Keywords

references

Study of Fixed Bed Reactor for Removing H₂S by Ferric Oxide