composite powders are synthesized by the liquid-solid hybrid method through mixing BaTiO
3
sol and Ni
0.5
Zn
0.5
Fe
2
O
4
powder together
in which the BaTiO
3
sol is prepared by sol-gel method and the Ni
0.5
Zn
0.5
Fe
2
O
4
powder is synthesized by self-combustion method. The Ni
0.5
Zn
0.5
Fe
2
O
4
/BaTiO
3
composite ceramics are succ
essfully prepared by pressing powder into green pellets and rings
and then sintering at different temperatures. The influences of ferrite phase on both the dielectric and magnetic properties of the composite are studied. The results show that
similar to the percolation behavior
the dielectric constant increases exponentially with increasing ferrite phase when its mole fraction is below 50% in the composite; while it remains almost a constant of about 10 000 F/m when the ferrite phase is more than 50%. The permeability of the composite increases from 5 to 18 H/m as ferrite phase increases from about 50% to 90%. It is clear that the composite ceramics with high dielectric constant and acceptable permeability can be obtained via the liquid-solid hybrid method.
关键词
Keywords
references
SPALDIN N A, FIEBIG M. The renaissance of magnetoelectric multiferroics[J]. Science, 2005, 309(5733): 391-392.
QI Xiwei,ZHOU Ji,YUE Zhenxing, et al. Study on magnetic and dielectric properties of ferroelectric/ferromagnetic composites[J]. Electronic components Materials,2003, 22(4):3-5.
DONG Yanling, DU Piyi, WENG Wenjian. Effect of phase formation on magnetism of sol-gel derived PbTiO3/(Ni, Pb)ferrite composite powders[J]. Key Eng Mater, 2007, 336: 706.
GAO Qiuling,LI Ping. Study on magnetoelectric effect of ferromagnetic alloy/piezoelectric composite material[J]. Transducer and Microsystem Technologies. 2010, 29(1): 62-64.
ZHENG H, WANG J, LOFLAND S E. et al. Multiferroic BiFeO3-CoFe2O4 nanostructures [J]. Science, 2004, 303(5658): 661-663.
TOSHIMITSU K, SHIN-ICHI O, NAKAJI A, et al. A ferroelectric ferromagnet composed of(PLZT)x(BiFeO3)1±x solid solution [J]. Adv Mater, 2001, 13(7): 487-490.
HUANG Jiquan, DU Piyi, HONG Lanxiu, et al. A percolative ferroelectric-metal composite with significant dielectric and magnetic properties [J]. Adv Mater, 2007, 19(3): 437-440.
ZHENG Hui, DONG Yanling, WANG Xin, et al. Super high threshold percolative ferroelectric/ferrimagnetic composite ceramics with outstanding permittivity and initial permeability [J].Angew Chem, 2009, 48(47):8927-8930.
HWANG Chyiching, WU Tsungyung, WAN Jun, et al. Development of a novel combustion synthesis method for synthesizing of ceramic oxide powders [J]. Materials Science and Engineering: B, 2004,111(1): 49-56.
CHEN Zuhuang, HUANG Jiquan, CHEN Qian, et al. A percolative ferroelectric-metal composite with hybrid dielectric dependence [J]. Scripta Materialia, 2007, 57(10):921-924.