

浏览全部资源
扫码关注微信
1.西安交通大学能源与动力工程学院,710049,西安
2.西安交通大学化学工程与技术学院,710049,西安
Received:30 December 2025,
Revised:2026-03-27,
Accepted:13 April 2026,
移动端阅览
ZHU Shun, WEN Jian, XU Pan, et al. Experimental and Numerical Investigation of Flow and Heat Transfer and Ortho-Para Hydrogen Conversion Performance in a Catalyst-Filled Plate-Fin Heat Exchanger[J/OL]. JOURNAL OF XI’AN JIAOTONG UNIVERSITY, 2026.
为实现氢液化过程中,正仲氢的连续高效转化,针对正仲氢催化剂填充板翅式换热器(CFPFHE),采用实验测试与数值模拟相结合的方法,系统研究了其流动阻力、换热性能及正仲氢催化转化特性。基于搭建的CFPFHE低温实验测试平台,在良好绝热条件下开展了不同雷诺数工况的流动换热与正仲转化实验,并采用热平衡法计算了填料通道(热侧)出口仲氢的体积分数。此外,建立了CFPFHE的三维数值模型,对CFPFHE流动换热与正仲氢转化过程进行了模拟,并通过实验结果对模型进行了验证。研究结果表明:随着雷诺数的增加,热侧与冷侧摩擦阻力因子均逐渐降低;热侧换热因子先增大后减小,在热侧雷诺数约为213时达到峰值,而冷侧换热因子随冷侧雷诺数单调下降;出口仲氢体积分数随热侧雷诺数先升高后略有下降。数值模拟结果与实验数据吻合良好,摩擦阻力因子、换热因子及出口仲氢体积分数的平均相对偏差均小于7.15%。该研究结果验证了所建数值模型的可靠性,可为CFPFHE在大型氢液化装置中的工程应用提供参考。
To achieve continuous and efficient ortho-para hydrogen conversion during hydrogen liquefaction
a catalyst-filled plate-fin heat exchanger (CFPFHE) was investigated using a combined experimental and numerical approach. The flow resistance
heat transfer performance
and ortho-para hydrogen catalytic conversion characteristics of the CFPFHE were systematically studied. Based on a cryogenic experimental test platform developed for the CFPFHE
experiments on flow and heat transfer coupled with ortho-para hydrogen conversion were carried out under different Reynolds number conditions with good thermal insulation
and the para-hydrogen volume fraction at the outlet of the filled channel (hot-side) was determined using the heat balance method. In addition
a three-dimensional numerical model of the CFPFHE was established to simulate the coupled flow
heat transfer
and ortho-para hydrogen conversion processes
and the model was validated against experimental data. The results indicate that
with in
creasing Reynolds number
the friction factors of both the hot and cold sides decrease gradually; the hot-side heat transfer factor first increases and then decreases reaching a peak at a hot-side Reynolds number of about213
while the cold-side heat transfer factor decreases monotonically with cold-side Reynolds number; the outlet para-hydrogen volume fraction first increases and then slightly decreases with increasing hot-side Reynolds number. The numerical results show good agreement with the experimental data
with the average relative deviations of the friction
factors
heat transfer factors
and outlet para-hydrogen volume fraction all within 7.15%. These results confirm the reliability of the proposed numerical model and provide a reference for the engineering application of CFPFHEs in large-scale hydrogen liquefaction systems.
俞和胜 , 祁海鹰 , 谭忠超 . “双碳”背景下传统化石能源脱碳制氢增值化利用技术 [J/OL ] . 清华大学学报(自然科学版) , 2023 , 63 ( 8 ): 1226 - 1235 .
YU H , QI H , TAN Z . Decarbonization, hydrogen production, and value-added utilization of conventional fossil fuels under the background of “double-carbon ”. Journal of Tsinghua University (Science and Technology) , 2023 , 63 ( 8 ): 1226 - 1235 .
蒲亮 , 余海帅 , 代明昊 , 等 . 氢的高压与液化储运研究及应用进展 [J ] . 科学通报 , 2022 , 67 ( 19 ): 2172 - 2191 .
PU L , YU H , DAI M , et al . Research progress and application of high-pressure hydrogen and liquid hydrogen in storage and transportation [J ] . Chinese Science Bulletin , 2022 , 67 ( 19 ): 2172 - 2191 .
KRASAE-IN S , STANG J H , NEKSA P . Development of large-scale hydrogen liquefaction processes from 1898 to 2009 [J ] . International Journal of Hydrogen Energy , 2010 , 35 ( 10 ): 4524 - 4533 .
卓红英 , 赵忠正 , 沈铮 , 等 . 正-仲氢催化转化研究进展 [J ] . 化工学报 , 2024 , 75 ( 11 ): 3883 - 3895 .
ZHUO H , ZHAO Z , SHEN Z , et al . Research progress on the catalytic conversion of ortho- to para-hydrogen [J ] . CIESC Journal , 2024 , 75 ( 11 ): 3883 - 3895 .
陈晓露 , 刘小敏 , 王娟 , 等 . 液氢储运技术及标准化 [J ] . 化工进展 , 2021 , 40 ( 9 ): 4806 - 4814 .
CHEN X , LIU X , WANG J , et al . Technology and standardization of liquid hydrogen storage and transportation [J ] . Chemical Industry and Engineering Progress , 2021 , 40 ( 9 ): 4806 - 4814 .
SADAGHIANI M S , MEHRPOOYA M . Introducing and energy analysis of a novel cryogenic hydrogen liquefaction process configuration [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 9 ): 6033 - 6050 .
魏欣宇 , 方松 , 滕钧杰 , 等 . 连续转化式低温氢气换热器换热与催化匹配特性研究 [J ] . 工程热物理学报 , 2025 , 46 ( 3 ): 703 - 713 .
WEI X , FANG S , TENG J , et al . Investigation into the heat exchange and catalytic matching characteristics in continuous conversion cryogenic hydrogen gas heat exchangers [J ] . Journal of Engineering Thermophysics , 2025 , 46 ( 3 ): 703 - 713 .
XU P , WEN J , LI K , et al . Structural improvement of catalyst filled channel of continuous ortho-para hydrogen conversion technology [J ] . Thermal Science and Engineering Progress , 2023 , 43 : 101974 .
李科 , 朱顺 , 文键 , 等 . 入口流动不均对耦合氢正仲催化转化板翅式换热器性能的影响 [J ] . 化工进展 , 2025 , 44 ( 10 ): 5640 - 5651 .
LI K , ZHU S , WEN J , et al . Effect of inlet flow maldistribution on performance of plate fin heat exchanger coupled with hydrogen ortho-para catalytic conversion [J ] . Chemical Industry and Engineering Progress , 2025 , 44 ( 10 ): 5640 - 5651 .
ASADNIA M , MEHRPOOYA M . A novel hydrogen liquefaction process configuration with combined mixed refrigerant systems [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 23 ): 15564 - 15585 .
KIM J H , KANG S W , NAH I W , et al . Synthesis and characterization of fe-modified zeolite for spin conversion of hydrogen at cryogenic temperature [J ] . International Journal of Hydrogen Energy , 2015 , 40 ( 45 ): 15529 - 15533 .
孙崇正 , 樊欣 , 李玉星 , 等 . 海上多孔介质通道内氢气换热与正仲氢转化的耦合特性 [J ] . 化工进展 , 2023 , 42 ( 3 ): 1281 - 1290 .
SUN C , FAN X , LI Y , et al . Coupling characteristics of hydrogen heat transfer and normal-parahydrogen conversion in offshore porous media channels [J ] . Chemical Industry and Engineering Progress , 2023 , 42 ( 3 ): 1281 - 1290 .
ZHOU H , LI Z , LI M , et al . Study of activation methods for ortho-para hydrogen catalysts in a small isothermal converter based on gas chromatography at LN 2 temperature [J ] . International Journal of Hydrogen Energy , 2024 , 55 : 55 - 64 .
范质 , 吴俊哲 , 杨昌乐 , 等 . 正仲氢转化催化剂性能实验研究 [J ] . 低温工程 , 2025 , ( 1 ): 65 - 69 .
FAN Z , WU J , YANG C , et al . Experimental study of performance of ortho-parahydrogen conversion catalyst [J ] . Cryogenics , 2025 , ( 1 ): 65 - 69 .
刁希文 , 滕越 , 赵骞 , 等 . 正仲氢催化转化性能低温测试装置设计 [J ] . 低温与超导 , 2022 , 50 ( 2 ): 84 - 88 .
DIAO X , TENG Y , ZHAO Q , et al . Design of cryogenic test device for catalytic conversion performance of ortho-parahydrogen [J ] . Cryogenics & Superconductivity , 2022 , 50 ( 2 ): 84 - 88 .
WEITZEL D H , VALIN C C , DRAPER J W . Design data for ortho-parahydrogen converters [M ] . New York : Springer US , 1960 : 73 - 84 .
HUTCHINSON H L . Analysis of catalytic ortho-parahydrogen reaction mechanisms [D ] . Boulder, Colorado, USA : University of Colorado , 1966 : 58 - 122 .
WAKAO N , SELWOOD P , SMITH J . Low temperature ortho-para hydrogen conversion-kinetic studies [J ] . Aiche Journal , 1962 , 8 ( 4 ): 478 - 481 .
PARK J , LIM H , RHEE G H , et al . Catalyst filled heat exchanger for hydrogen liquefaction [J ] . International Journal of Heat and Mass Transfer , 2021 , 170 : 121007 .
李启铭 , 张磊 , 徐攀 , 等 . 氢液化流程中催化换热一体化可行性研究 [J ] . 化学工程 , 2021 , 49 ( 7 ): 26 - 30 .
LI Q , ZHANG L , XU P , et al . Feasibility on integration of catalysis and heat transfer in hydrogen liquefaction process [J ] . Chemical Engineering , 2021 , 49 ( 7 ): 26 - 30 .
徐攀 , 文键 , 厉彦忠 , 等 . 氢正仲转化耦合流动换热板翅式换热器研究 [J ] . 西安交通大学学报 , 2021 , 55 ( 12 ): 16 - 24 .
XU P , WEN J , LI Y , et al . Study on hydrogen ortho-para conversion coupled with flow and heat transfer of the plate fin heat exchanger [J ] . Journal of Xi'an Jiaotong University , 2021 , 55 ( 12 ): 16 - 24 .
WILHELMSEN O , BERSTAD D , AASEN A , et al . Reducing the exergy destruction in the cryogenic heat exchangers of hydrogen liquefaction processes [J ] . International Journal of Hydrogen Energy , 2018 , 43 ( 10 ): 5033 - 5047 .
DONAUBAUER P J , CARDELLA U , DECKER L , et al . Kinetics and heat exchanger design for catalytic ortho-para hydrogen conversion during liquefaction [J ] . Chemical Engineering & Technology , 2019 , 42 ( 3 ): 669 - 679 .
ZHU S , TENG J , ZHI X , et al . Numerical study on comprehensive performance of flow and heat transfer coupled with ortho-para hydrogen conversion [J ] . International Journal of Heat and Mass Transfer , 2023 , 201 : 123653 .
TENG J , ZHU S , WEI X , et al . Roles of catalysts’ porous media feature and catalytic conversion effect on the performance of plate-fin heat exchangers in hydrogen liquefaction [J ] . International Journal of Heat and Mass Transfer , 2024 , 218 : 124761 .
李科 , 朱顺 , 文键 . 集成氢仲正催化转化的蒸气冷却屏对液氢储罐自增压的影响 [J ] . 西安交通大学学报 , 2025 , 59 ( 7 ): 170 - 181 .
LI K , ZHU S , WEN J . Effects of vapor-cooled shields integrated with para-ortho hydrogen catalytic conversion on self-pressurization of liquid hydrogen storage tanks [J ] . Journal of Xi'an Jiaotong University , 2025 , 59 ( 7 ): 170 - 181 .
LI K , ZHU S , WEN J , et al . Study on self-pressurization liquid hydrogen tank with multi-layer insulation considering effect of thermodynamic vent system integrated with vapor-cooled shield based on transient-state modeling [J ] . Energy , 2025 , 332 : 137250 .
LI K , WEN J , XIN B , et al . Multi-parameter optimization of multiple vapor-cooled shields integrated with para-to-ortho catalytic conversion based on self-pressurization model of liquid hydrogen tank and MOGA [J ] . Applied Thermal Engineering , 2025 , 263 : 125348 .
0
Views
1
下载量
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution
京公网安备11010802024621