Study on Bending Properties of Graphene Oxide-Modified Woven Carbon Fiber Composites

MA Yuqin; YAO Yinshu; LV Jinshu; GAO Yongchang; LI Shuo; HAN Yupeng

doi:null

您当前的位置：

首页 >

文章列表页 >

Study on Bending Properties of Graphene Oxide-Modified Woven Carbon Fiber Composites

更新时间：2025-12-11

- Study on Bending Properties of Graphene Oxide-Modified Woven Carbon Fiber Composites
- JOURNAL OF XI’AN JIAOTONG UNIVERSITY (2025)
- 作者机构：
  
  道路施工技术与装备教育部重点实验室，长安大学工程机械学院，西安 710064
- 作者简介：
- 基金信息：
- DOI：
  CLC： TB332
- Received：28 August 2025，
  
  Revised：2025-10-24，
  
  Accepted：29 October 2025，
- 稿件说明：
移动端阅览
MA Yuqin, YAO Yinshu, LV Jinshu, et al. Study on Bending Properties of Graphene Oxide-Modified Woven Carbon Fiber Composites[J/OL]. JOURNAL OF XI’AN JIAOTONG UNIVERSITY, 2025.
DOI：

MA Yuqin, YAO Yinshu, LV Jinshu, et al. Study on Bending Properties of Graphene Oxide-Modified Woven Carbon Fiber Composites[J/OL]. JOURNAL OF XI’AN JIAOTONG UNIVERSITY, 2025. DOI：

摘要

为了提高编织碳纤维复合材料的力学性能及其在实际工程中的应用，提出通过引进氧化石墨烯（GO）并调整其质量分数来优化复合材料力学性能。采用真空浸渗热压工艺制备GO质量分数为0.0%~0.5%的编织碳纤维复合材料，对其进行三点弯曲试验并借助扫描电子显微镜表征微观断口形貌；同时构建代表性体积单元模型，导入仿真软件中进行三点弯曲仿真分析。结果表明：随着GO质量分数从0.0%增至0.5%，材料极限弯曲载荷从150 N提升至292 N，增幅近95%；弯曲强度和模量在其质量分数为0.5%时达最优，分别为164.71 MPa和9.97 GPa，较未添加GO的样品分别提升93.02%和49.47%。试验与仿真结果变化趋势一致且吻合良好，说明GO的添加对碳纤维复合材料微观组织和力学性能影响显著，且在其质量分数为0.5%时作用最突出。研究为高性能碳纤维复合材料的设计与制备提供了数据支撑和理论参考。

Abstract

To improve the mechanical properties of woven carbon fiber composites and their application in practical engineering

it was proposed to optimize the mechanical properties of the composites by introducing graphene oxide (GO) and adjusting its mass fraction. Woven carbon fiber composites with GO mass fractions ranging from 0.0% to 0.5% were fabricated via vacuum impregnation hot pressing system. Three-point bending tests were conducted on the composites

and the microfracture morphology was characterized using a scanning electron microscope. Meanwhile

a representative volume element model was established and imported into simulation software for three-point bending simulation analysis.The results indicated that as the GO mass fraction increased from 0.0% to 0.5%

the ultimate bending load of the material increased from 150 N to 292 N

with an increase of nearly 95%. When the GO mass fraction was 0.5%

the bending strength and modulus reached the optimal values

which were 164.71 MPa and 9.97 GPa

respectively—representing increases of 93.02% and 49.47% compared with the samples without GO addition. The variation trends of the experimental and simulation results were consistent and in good agreement

which indicated that the addition of GO had a significant impact on the microstructure and mechanical properties of woven carbon fiber composites

and the most prominent effect was observed when the GO mass fraction was 0.5%. This study provides data support and theoretical reference for the design and preparation of high-performance woven carbon fiber composites.

关键词

Keywords

references

Sayam A , Rahman A N M M , Rahman M S , et al . A review on carbon fiber-reinforced hierarchical composites: mechanical performance, manufacturing process, structural applications and allied challenges [J ] . Carbon Letters , 2022 , 32 ( 5 ): 1173 - 1205 .

Karataş M A , Gökkaya H . A review on machinability of carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) composite materials [J ] . Defence Technology , 2018 , 14 ( 4 ): 318 - 326 .

Zhang Z , Tie Y , Fan C , et al . Multiscale Analysis of Impact-Resistance in Self-Healing Poly (ethylene-co-methacrylic acid)(EMAA) Plain Woven Composites [J ] . Polymers , 2024 , 16 ( 19 ): 2740 .

Kwon D J , Park S M , Kwon I J , et al . Improvement of interlaminar properties of carbon fiber-reinforced epoxy composites using aluminum trihydroxide [J ] . Carbon Letters , 2019 , 29 : 183 - 191 .

刘玉婷 , 姚婷婷 , 宋红艳 , 等 . 氧化石墨烯/炭纤维复合增强体的制备及对环氧树脂复合材料界面性能影响 [J ] . 新型炭材料 , 2018 , 33 ( 06 ): 595 - 604 .

LIU Yuting , YAO Tingting , SONG Hongyan , et al . Preparation of carbon fibers grafted to graphene oxide as a reinforcement for epoxy matrix composites [J ] . New Carbon Materials , 2018 , 33 ( 06 ): 595 - 604 .

叶国锐 , 晏义伍 , 曹海琳 . 氧化石墨烯改性玄武岩纤维及其增强环氧树脂复合材料性能 [J ] . 复合材料学报 , 2014 , 31 ( 06 ): 1402 - 1408 .

YE Guorui , YAN Yiwu , CAO Hailin . Basalt fiber modified with graphene oxide and properties of its reinforced epoxy composites [J ] . Acta Materiae Compositae Sinica , 2014 , 31 ( 06 ): 1402 - 1408 .

Altin Y , Yilmaz H , Unsal O F , et al . Graphene oxide modified carbon fiber reinforced epoxy composites [J ] . Journal of Polymer Engineering , 2020 , 40 ( 5 ): 415 - 420 .

Acar V , Erden S , Sarıkanat M , et al . Graphene oxide modified carbon fiber prepregs: a mechanical comparison of the effects of oxidation methods [J ] . Express Polymer Letters , 2020 , 14 ( 12 ): 1106 - 1115 .

许欢 , 叶蓓 , 陆晶晶 , 等 . 硅聚物-氧化石墨烯增强玻璃纤维/环氧树脂复合材料的制备与性能 [J ] . 复合材料学报 , 2024 , 41 ( 11 ): 5976 - 5984 .

XU Huan , YE Bei , LU Jingjing , et al . Preparation and properties of silicone polymer-graphene oxide reinforcedglass fiber/epoxy resin composites [J ] . Acta Materiae Compositae Sinica , 2024 , 41 ( 11 ): 5976 - 5984 .

侯永刚 , 吕生华 , 张佳 , 等 . 氧化石墨烯的制备及形成机理 [J ] . 精细化工 , 2019 , 36 ( 04 ): 559 - 567 .

HOU Yonggang , LV Shenghua , ZHANG Jia , et al . Preparation and Formation Mechanism of Graphene Oxide [J ] . Fine Chemicals , 2019 , 36 ( 04 ): 559 - 567 .

Jiang J , Yao X , Xu C , et al . Influence of electrochemical oxidation of carbon fiber on the mechanical properties of carbon fiber/graphene oxide/epoxy composites [J ] . Composites Part A: Applied Science and Manufacturing , 2017 , 95 : 248 - 256 .

芦武刚 , 葛曷一 . 碳纤维-氧化石墨烯/环氧树脂复合材料界面性能研究 [J/OL ] . 化工新型材料 , 1 - 8 [ 2025-09-16 ] . https://doi.org/10.19817/j.cnki.issn1006-3536.2025.11.032 https://doi.org/10.19817/j.cnki.issn1006-3536.2025.11.032 .

LU Wugang , GE Heyi . Study on the interface properties of carbon fiber graphene oxide/epoxy resincomposites [J/OL ] . New Chemical Materials . 1 - 8 [ 2025-09-16 ] . https://doi.org/10.19817/j.cnki.issn1006-3536.2025.11.032 https://doi.org/10.19817/j.cnki.issn1006-3536.2025.11.032 .

Zhang R L , Gao B , Ma Q H , et al . Directly grafting graphene oxide onto carbon fiber and the effect on the mechanical properties of carbon fiber composites [J ] . Materials and Design , 2016 , 93 : 364 - 369 .

Zhang J , Kim D , Lee D , et al . Optimized dispersion and multidimensional mechanical property enhancement mechanisms in reduced graphene oxide nanosheet reinforced epoxy composite coatings [J ] . Diamond and Related Materials , 2025 , 154 : 112194 .

王杰 . 真空浸渗热压形状记忆复合材料及其性能研究 [D ] . 西安：西安电子科技大学 , 2021 .

WANG Jie . Research on Vacuum Infiltration and Hot-Pressed Shape Memory Composite Materialand Its Performance [D ] . Xi’an : Xidian University , 2021 .

水丽 , 张凯 , 于宏 . 石墨烯含量对石墨烯/Al-15Si-4Cu-Mg复合材料微观组织和力学性能的影响 [J ] . 工程科学学报 , 2019 , 41 ( 09 ): 1162 - 1167 .

SHUI Li , ZHANG Kai , YU Hong . Effect of graphene content on the microstructure and mechanical properties of graphene-reinforced Al-15Si-4Cu-Mg matrix composites [J ] . Chinese Journal of Engineering , 2019 , 41 ( 09 ): 1162 - 1167 .

Shin S E , Bae D H . Deformation behavior of aluminum alloy matrix composites reinforced with few-layer graphene [J ] . Composites Part A: Applied Science and Manufacturing , 2015 , 78 : 42 - 47 .

全国纤维增强塑料标准化技术委员会 . 纤维增强塑料弯曲性能试验方法 : GB/T 1449-2005 [S ] . 中国标准出版社 , 2005 .

National Technical Committee on Fiber Reinforced Plastics of Standardization Administration of China . Test method for flexural properties of fiber reinforced plastics : GB/T 1449-2005 [S ] . China Standards Press , 2005 .

左殿军 . DIGIMAT非线性复合材料多尺度模拟平台应用基础 [M ] . 北京 : 中国建筑工业出版社 , 2021 .

ZUO Dianjun . Fundamentals of Application for DIGIMAT Nonlinear Composite Materials Multiscale Simulation Platform [M ] . Beijing : China Architecture and Building Press , 2021 .

王帅 . 粉末冶金层状TiBw/TC4复合材料组织与力学性能研究 [D ] . 哈尔滨：哈尔滨工业大学 , 2017 .

WANG Shuai . Microstructure and mechanical properties of TiBw/TC4 composites with laminate structure fabricated by powder metallurgy [D ] . Harbin : Harbin Institute of Technology , 2017 .

张松俊 . 基于多尺度模型的二维三轴编织复合材料的损伤破坏机理研究 [D ] . 长沙 : 湖南大学 , 2018 .

ZHANG Songjun . Research on the damage mechanism of triaxial braided composites based on multi-scale model [D ] . Changsha : Hunan University , 2018 .

王成聘 . 石墨烯和陶瓷复合材料力学性能的多尺度模拟 [D ] . 南京 : 东南大学 , 2021 .

WANG Chengdan . Multiscale simulation of the mechanical properties of graphene and ceramic composites [D ] . Nanjing : Southeast University , 2021 .

刘延超 . 短柱增强体金属基复合材料的剪切滞后分析 [D ] . 沈阳工业大学 , 2014 .

LIU Yanchao . The Shear Lag Theory Analysis of Stress Distribution of The Short Column Reinforced Metal Matrix Composite [D ] . Shenyang : Shenyang University of Technology , 2014 .

陈宇飞 , 赵辉 , 滕成君 . MAH-GO/MBMI-E51复合材料的微观结构及力学性能 [J ] . 复合材料学报 , 2022 , 39 ( 2 ): 601 - 607 .

CHEN Yufei , ZHAO Hui , TENG Chengjun . Microstructure and mechanical properties of MAH-GO/MBMI-E51 composites [J ] . Acta Materiae Compositae Sinica , 2022 , 39 ( 2 ): 601 - 607 .

胡涛 , 赵东林 , 程兴旺 , 等 . 氧化石墨烯增强环氧树脂复合材料的制备及其力学性能研究 [J ] . 北京化工大学学报(自然科学版) , 2018 , 45 ( 06 ): 29 - 33 .

HU Tao , ZHAO Donglin , CHENG Xingwang . et al . Preparation and mechanical properties of graphene oxidereinforced epoxy composites [J ] . Journal of Beijing University of Chemical Technology(Natural Science Edition) , 2018 , 45 ( 06 ): 29 - 33 .

ACOCELLA M R , CORCIONE C E , GIURI A , et al . Graphene oxide as a catalyst for ring opening reactions in amine crosslinking of epoxy resins [J/OL ] . RSC Advances , 2016 , 6 (Compendex): 23858 - 23865 .

Pathak A K , Borah M , Gupta A , et al . Improved mechanical properties of carbon fiber/grapheneoxide-epoxy hybrid composites [J ] . Composites Science and Technology , 2016 , 135 : 28 - 38 .

Liu L , Yan F , Li M , et al . Improving interfacial properties of hierarchical reinforcement carbon fibers modified by graphene oxide with different bonding types [J ] . Composites Part A:Applied Science and Manufacturing , 2018 , 107 : 616 - 625 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study on Bending Performance of Graphene Oxide-Modified Woven Carbon Fiber Composites

Stir Friction Brazing and Interlayer Optimization for AZ31B Magnesium Alloy and 316L Stainless Steel

Effects of Ti3SiC2 Content on the Microstructure and Properties of Heat Treated(Ti5Si3+TiC)/TC4 Composites

Mechanism and Optimal Control Strategy for Hysteresis in Rapid Dehumidification Response of Indirect Thermal Systems in Electric Vehicles

Effects of Steam Addition on the Swirl Combustion and Emission Characteristics of Cracked Ammonia

Related Author

MA Yuqin

YAO Yinshu

LÜ Jinshu

GAO Yongchang

LI Shuo

HAN Yupeng

ZHAO Qihong

ZHANG Guifeng

Related Institution

Key Laboratory of Road Construction Technology and Equipment of Ministry of Education, Chang'an University

College of Engineering Machinery, Chang'an University

State Key Laboratory for Mechanical Behavior Materials, Xi'an Jiaotong University

State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University

Institute of Foundry Technology and Wear Resistant Materials, Xi’an Jiaotong University

⁰