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为探究固空形成过程中枝晶微结构演化和氧溶质非均匀分布规律,建立了描述固空枝晶生长凝固过程中枝晶形态演化和氧溶质分布的定量相场模型(QPFM)
应用该模型对连续冷却条件下的固空单枝晶和多枝晶生长行为特性进行了研究,选择了两条特殊位置曲线定量表述氧溶质分布规律。结果表明:枝晶形态随初始过冷度增大而变得复杂,二次枝晶臂更为发达;氧溶质质量分数呈现枝晶内部贫氧外部富氧的分布特征,沿一次枝晶臂和二次枝晶臂的轴线形成了氧溶质质量分数较低的脊柱;多枝晶的相互作用破环了枝晶的对称形态;连续冷却条件下,固空枝晶二次枝晶臂随时间增长逐渐粗化、融合,固相率和最大氧溶质质量分数分别持续增长到最大值0.911 1和0.840 6;枝晶之间的间隙阻碍了氧溶质的扩散,使得氧溶质质量分数由单枝晶时的0.402升至多枝晶时的0.668。研究可为液氢系统的安全使用提供理论指导。
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