[1]生森森,刘佳祥,李卓.金属有机框架材料UiO-66-(COOH)2吸附去除染料废水中的亚甲基蓝和罗丹明B[J].西安交通大学学报,2020,54(09):180-188.[doi:10.7652/xjtuxb202009021]
 SHENG Sensen,LIU Jiaxiang,LI Zhuo.Adsorption and Removal of Methylene Blue and Rhodamine B from Dye Wastewater by Metal-Organic FrameworkUiO-66-(COOH)2[J].Journal of Xi'an Jiaotong University,2020,54(09):180-188.[doi:10.7652/xjtuxb202009021]
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金属有机框架材料UiO-66-(COOH)2吸附去除染料废水中的亚甲基蓝和罗丹明B
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《西安交通大学学报》[ISSN:0253-987X/CN:61-1069/T]

卷:
54
期数:
2020年第09期
页码:
180-188
栏目:
出版日期:
2020-09-10

文章信息/Info

Title:
Adsorption and Removal of Methylene Blue and Rhodamine B from Dye Wastewater by Metal-Organic FrameworkUiO-66-(COOH)2
文章编号:
0253-987X(2020)09-0180-09
作者:
生森森 刘佳祥 李卓
同济大学环境科学与工程学院, 200092, 上海
Author(s):
SHENG Sensen LIU Jiaxiang LI Zhuo
School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
关键词:
金属有机框架材料 UiO-66-(COOH)2 亚甲基蓝 罗丹明B 吸附
Keywords:
metal-organic framework material UiO-66-(COOH)2 methylene blue rhodamine B adsorption
分类号:
X522; X791
DOI:
10.7652/xjtuxb202009021
文献标志码:
A
摘要:
为提高对废水中阳离子染料亚甲基蓝(MB)和罗丹明B(RhB)的吸附性能,引入羧基基团,制备了表面带负电的金属有机框架材料UiO-66-(COOH)2。对所得样品进行了X射线衍射图谱分析、扫描电镜形貌分析、N2吸附脱附等温线分析、热重分析、傅里叶红外光谱分析。深入研究了UiO-66-(COOH)2对废水中MB和RhB两种染料的吸附性能和吸附机理。结果表明:由于静电作用的影响,引入羧基基团后的UiO-66-(COOH)2对MB和RhB的吸附性能均优于UiO-66的,分别超出32.4%和51.8%,且远高于活性炭吸附剂及其他羧基修饰材料的吸附量; UiO-66-(COOH)2在pH为3~10的范围内均具有较好的吸附性能,具有较强的pH适应性; 吸附等温线拟合分析表明,UiO-66-(COOH)2对MB和RhB的吸附过程与Langmuir等温吸附模型吻合; 吸附动力学拟合分析表明,UiO-66-(COOH)2对MB和RhB的吸附过程与准二级动力学方程吻合; 经3次吸脱附循环后,UiO-66-(COOH)2对MB和RhB的吸附量分别减少了15.6%和22.5%,表明UiO-66-(COOH)2具有可再生循环使用潜力。
Abstract:
To improve the adsorption capacity of cationic dyes methylene blue(MB)and rhodamine B(RhB)in wastewater, the negatively charged metal-organic framework(MOFs)materialUiO-66-(COOH)2 was prepared by introducing carboxyl groups. The MOFs samples were carefully characterized by X-ray diffraction, scanning electron microscopy, N2 absorption-desorption isotherm, thermogravimetric analyzer and Fourier transform infrared spectroscopy. The adsorption properties and mechanisms ofUiO-66-(COOH)2 to MB and RhB in wastewater were deeply investigated. The results show that the effect of static electricity lead the adsorption properties ofUiO-66-(COOH)2 improved by 32.4% and 51.8% respectively compared with UiO-66, and the adsorption properties are much higher than that of activated carbon and other carboxyl modified materials. In the pH range of 3 - 10,UiO-66-(COOH)2 exhibits better adsorption properties and stronger pH adaptability. Analyzing the fitted adsorption isotherms, the adsorption processes ofUiO-66-(COOH)2 to MB and RhB are found to coincide with Langmuir isotherms as well as pseudo-second-order kinetic model. After three adsorption and desorption cycles, the adsorption ofUiO-66-(COOH)2 to MB and RhB decreases by 15.6% and 22.5% respectively to indicate its potential for recycling and regeneration.

参考文献/References:

[1] 何舒敏, 张颖欣, 麦裔强, 等. 纺织品禁用偶氮染料假阳性分析方法的研究进展 [J]. 上海纺织科技, 2019, 47(6): 57-59.
HE Shumin, ZHANG Yingxin, MAI Yiqiang, et al. Research progress of false positive analysis method for the banned azo dyes in textiles [J]. Shanghai Textile Science & Technology, 2019, 47(6): 57-59.
[2] KADIRVELU K, KAVIPRIYA M, KARTHIKA C, et al. Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions [J]. Bioresource Technology, 2003, 87(1): 129-132.
[3] CRINI G. Non-conventional low-cost adsorbents for dye removal: a review [J]. Bioresource Technology, 2006, 97(9): 1061-1085.
[4] 曾玉彬, 周静颖, 谭观成, 等. 一种生物质活性炭的制备及其对亚甲基蓝的吸附性能 [J]. 应用化工, 2019, 48(10): 2271-2275, 2279.
ZENG Yubin, ZHOU Jingying, TAN Guancheng, et al. Preparation of bio-activated carbon and adsorption properties to methylene blue dye [J]. Applied Chemical Industry, 2019, 48(10): 2271-2275, 2279.
[5] 常国华, 党雅馨, 岳斌, 等. 人造沸石/活性炭对甲基绿的吸附及再生研究 [J]. 环境科学与技术, 2017, 40(S1): 71-76.
CHANG Guohua, DANG Yaxin, YUE Bin, et al. Adsorption of methyl green on synthetic zeolite & activated carbon and their regeneration [J]. Environmental Science & Technology, 2017, 40(S1): 71-76.
[6] 连丽丽, 吕进义, 修超, 等. 磁性硅藻土的制备及其对刚果红的吸附 [J]. 吉林化工学院学报, 2018, 35(7): 82-85.
LIAN Lili, Lü Jinyi, XIU Chao, et al. Preparation of the functional magnetic diatomite and its application in Congo red adsorption [J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 82-85.
[7] 温丙奎, 刘珊珊, 杨鸿凯, 等. 改性粉煤灰对酸性大红染料模拟废水的脱色研究 [J]. 山东化工, 2019, 48(21): 238-240.
WEN Bingkui, LIU Shanshan, YANG Hongkai, et al. Study on decolorization of acid red dye simulated wastewater by modified fly ash [J]. Shandong Chemical Industry, 2019, 48(21): 238-240.
[8] 冯丽, 葛小鹏, 晏晓敏, 等. 载钯树脂对偶氮类染料的吸附降解及其产物对发光菌的毒性暴露试验 [J]. 生态毒理学报, 2011, 6(3): 265-271.
FENG Li, GE Xiaopeng, YAN Xiaomin, et al. Adsorption and degradation of azo dyes and acute toxicity of the degradation products to luminescent bacteria in the reaction process by Pd loaded chelating resin [J]. Asian Journal of Ecotoxicology, 2011, 6(3): 265-271.
[9] LIAN X, YAN B. A lanthanide metal-organic framework(MOF-76)for adsorbing dyes and fluorescence detecting aromatic pollutants [J]. RSC Advances, 2016, 6(14): 11570-11576.
[10] ROSI N L, ECKERT J, EDDAOUDI M, et al. Hydrogen storage in microporous metal-organic frameworks [J]. Science, 2003, 300(5622): 1127-1129.
[11] AZHAR M R, VIJAY P, TADé M O, et al. Submicron sized water-stable metal organic framework(bio-MOF-11)for catalytic degradation of pharmaceuticals and personal care products [J]. Chemosphere, 2018, 196: 105-114.
[12] ZHANG Y Q, WU X H, MAO S, et al. Highly luminescent sensing for nitrofurans and tetracyclines in water based on zeolitic imidazolate framework-8 incorporated with dyes [J]. Talanta, 2019, 204: 344-352.
[13] KATZ M J, BROWN Z J, COLóN Y J, et al. A facile synthesis of UiO-66, UiO-67 and their derivatives [J]. Chemical Communications, 2013, 49(82): 9449-9451.
[14] YANG Q Y, VAESEN S, RAGON F, et al. A water stable metal-organic framework with optimal features for CO2 capture [J]. Angewandte Chemie, 2013, 52(39): 10316-10320.
[15] 袁立永, 罗百丞, 石伟群, 等. UiO-66及其羧基衍生物对U(Ⅵ)的吸附与机理研究 [C/OL]∥中国化学会第九届全国无机化学学术会议论文集: L 能源材料化学. 北京, 中国: 中国化学会, 2015. [2019-11-10]. http:∥ir.ihep.ac.cn/handle/311005/229250.
[16] ZHAO X D, LIU D H, HUANG H L, et al. Highly selective and sensitive metal-organic framework fluorescent probe for Cu2+ through rational design of binding sites [J]. Microporous and Mesoporous Materials, 2016, 224: 149-154.
[17] HAO J N, YAN B. A water-stable lanthanide-functionalized MOF as a highly selective and sensitive fluorescent probe for Cd2+ [J]. Chemical Communications, 2015, 51(36): 7737-7740.
[18] 吴文炳. UiO-66及UiO-66/再生纤维素复合膜的制备与吸附降解研究 [J]. 闽南师范大学学报(自然科学版), 2017, 30(4): 59-65.
WU Wenbing. Preparation and study adsorption-photocatalytic degradation property of UiO-66 and UiO-66/regenerated cellulose composite membrane [J]. Journal of Minnan Normal University(Natural Science), 2017, 30(4): 59-65.
[19] COOK T R, ZHENG Y R, STANG P J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials [J]. Chemical Reviews, 2013, 113(1): 734-777.
[20] 蔡之望, 刘峙嵘, 裘阳, 等. 竣基纤维介孔硅对Th(Ⅵ)的高效去除 [J]. 有色金属工程, 2018, 8(3): 22-28.
CAI Zhiwang, LIU Zhirong, QIU Yang, et al. Efficient removal of Th(Ⅵ)by carboxyl fiber mesoporous [J]. Nonferrous Metals Engineering, 2018, 8(3): 22-28.
[21] HAQUE E, JUN J W, JHUNG S H. Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate(MOF-235)[J]. Journal of Hazardous Materials, 2011, 185(1): 507-511.
[22] 王丰昶, 余彩莉, 许建本, 等. 含松香的羧基化聚合物微球对亚甲基蓝吸附研究 [J]. 化学研究与应用, 2016, 28(6): 777-782.
WANG Fengchang, YU Caili, XU Jianben, et al. Study on adsorption of methylene blue by rosin-based carboxylated polymer microspheres [J]. Chemical Research and Application, 2016, 28(6): 777-782.
[23] KADIRVELU K, KARTHIKA C, VENNILAMANI N, et al. Activated carbon from industrial solid waste as an adsorbent for the removal of rhodamine-B from aqueous solution: kinetic and equilibrium studies [J]. Chemosphere, 2005, 60(8): 1009-1017.
[24] OYETADE O A, NYAMORI V O, MARTINCIGH B S, et al. Effectiveness of carbon nanotube/cobalt ferrite nanocomposites for the adsorption of rhodamine B from aqueous solutions [J]. RSC Advances, 2015, 5(29): 22724-22739.
[25] LIU J, SHI J H, QIAN C X, et al. Decolorization of rhodamine-B from aqueous solutions by spent mushroom substrate [J]. BioResources, 2017, 12(4): 8612 -8628.
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备注/Memo

备注/Memo:
收稿日期: 2019-12-27。作者简介: 生森森(1994—),女,硕士生; 李卓(通信作者),女,副教授。基金项目: 国家自然科学基金资助项目(51676141); 国家水体污染控制与治理科技重大专项资助项目(2017ZX07201001); 中央高校基本科研业务费专项资金资助项目。
更新日期/Last Update: 2020-09-10